The Effect of Potential on Surface Characteristic and Corrosion Resistance of Anodic Oxide Film Formed on Commercial Pure Titanium at the Potentiodynamic-Aging Mode
Abstract
:1. Introduction
2. Experimental
2.1. Specimen Preparation
2.2. Surface Characterization
2.3. Corrosion Behavior
3. Results and Discussion
3.1. Surface Properties
3.2. Electrochemical Tests
3.3. Discussion
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Ti 2p3/2 (eV) | O 1s (eV) | |||||
---|---|---|---|---|---|---|
Ti | Ti2+ | Ti3+ | Ti4+ | O2− | OH− | H2O |
453.6 | 455.9 | 457.3 | 458.7 | 530.2 | 532.5 | 533.4 |
Samples | The Contribution of O 1s Components (%) | ||
---|---|---|---|
O2− | OH− | H2O | |
Ti10 | 73.65 | 21.88 | 4.47 |
Ti30 | 78.03 | 17.59 | 4.38 |
Ti50 | 84.09 | 12.99 | 2.92 |
Sample | Ecorr/VSCE | jcorr (μA cm−2) |
---|---|---|
CP-Ti | −1.352 | 1.258 × 10−4 |
Ti10 | −1.297 | 5.623 × 10−5 |
Ti30 | −1.252 | 1.995 × 10−5 |
Ti50 | −1.181 | 5.623 × 10−6 |
Samples | Rs (kΩ·cm2) | Q1/10−5 (Ω−1·cm−2sα) | α1 | Q2/10−5 (Ω−1·cm−2sα) | α2 | R1 (kΩ·cm2) | R2 (kΩ·cm2) | χ2 (10−4) |
---|---|---|---|---|---|---|---|---|
Ti10 | 1.02 | 8.5501 | 0.92 | 2.5680 | 0.67 | 1.79 | 489.53 | 3.47 |
Ti30 | 1.12 | 2.5727 | 0.89 | 1.7535 | 0.64 | 43.78 | 502.56 | 2.87 |
Ti50 | 1.08 | 1.9826 | 0.93 | 1.3068 | 0.59 | 89.45 | 512.48 | 2.67 |
Samples | C1 (μF·cm−2) | C2 (μF·cm−2) | L1 (nm) | L2 (nm) |
---|---|---|---|---|
Ti10 | 0.08121 | 0.08935 | 52.33 | 32.68 |
Ti30 | 0.02611 | 0.05964 | 162.75 | 49.86 |
Ti50 | 0.02078 | 0.04896 | 204.48 | 59.64 |
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Zhang, L.; Duan, Y.; Gao, R.; Yang, J.; Wei, K.; Tang, D.; Fu, T. The Effect of Potential on Surface Characteristic and Corrosion Resistance of Anodic Oxide Film Formed on Commercial Pure Titanium at the Potentiodynamic-Aging Mode. Materials 2019, 12, 370. https://doi.org/10.3390/ma12030370
Zhang L, Duan Y, Gao R, Yang J, Wei K, Tang D, Fu T. The Effect of Potential on Surface Characteristic and Corrosion Resistance of Anodic Oxide Film Formed on Commercial Pure Titanium at the Potentiodynamic-Aging Mode. Materials. 2019; 12(3):370. https://doi.org/10.3390/ma12030370
Chicago/Turabian StyleZhang, Ling, Yanqing Duan, Rui Gao, Jianyun Yang, Keyi Wei, Danyu Tang, and Tianlin Fu. 2019. "The Effect of Potential on Surface Characteristic and Corrosion Resistance of Anodic Oxide Film Formed on Commercial Pure Titanium at the Potentiodynamic-Aging Mode" Materials 12, no. 3: 370. https://doi.org/10.3390/ma12030370