Process-Induced Nanostructures on Anatase Single Crystals via Pulsed-Pressure MOCVD
Abstract
:1. Introduction
Nanostructured Materials for Coating Applications
2. Experimental Details
2.1. Pulsed-Pressure MOCVD Technology
2.2. Materials and Chemicals
2.3. Characterization Methods
2.4. Nanostructure Dimension Measurement
3. Results
3.1. Phase and Composition of TiO2 Coatings Prepared by pp-MOCVD
3.2. Plan-View Surface Morphologies of TiO2 Coatings
3.3. Analysis of Growth and Nanoscale Dimensions
3.4. Fracture Surface Morphologies
3.5. Nanostructure Dimensions along Column Length
4. Discussion
5. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample ID | Substrate | Number of Pulses |
---|---|---|
A | Fused Silica | 150 |
B | Fused Silica | 200 |
C | Fused Silica | 350 |
D | Fused Silica | 500 |
E | Fused Silica | 750 |
F | Fused Silica | 1000 |
G | Stainless Steel | 600 |
SA | Stainless Steel | 400 |
SB | Stainless Steel | 735 |
SC | Stainless Steel | 909 |
ID | Number of Pulses | Column Diameter (nm) | Plate Thickness (nm) |
---|---|---|---|
A | 150 | 157 ± 35 | 17.85 ± 3.5 |
B | 200 | 257 ± 5 | 27.98 ± 5.3 |
C | 350 | 277 ± 5 | 27.53 ± 2.3 |
D | 500 | 469 ± 30 | 36.23 ± 2.7 |
E | 750 | 553 ± 10 | 43.25 ± 3.5 |
F | 1000 | 600 ± 18 | 43.74 ± 3.0 |
ID | Number of Pulses | Film Thickness (μm) | Growth-Rate (nm/pulse) |
---|---|---|---|
A | 150 | 1.33 ± 0.03 | 8.87 ± 0.2 |
B | 200 | 3.07 ± 0.05 | 15.35 ± 0.25 |
C | 350 | 3.30 ± 0.04 | 10 ± 0.11 |
D | 500 | 4.00 ± 0.03 | 8.4 ± 0.06 |
E | 750 | 11.50 ± 0.10 | 15.33 ± 0.13 |
F | 1000 | 16.03 ± 0.50 | 16.03 ± 0.5 |
ROI | Anatase Column Width (nm) | |||
---|---|---|---|---|
G1 | G2 | G3 | G4 | |
1 | 80.7 ± 18 | 101.7 ± 17 | 221.6 ± 54 | 136.0 ± 30 |
2 | 92.4 ± 8 | 126.7 ± 31 | 332.3 ± 3 | 215.9 ± 20 |
3 | 142.4 ± 26 | 269.8 ± 59 | 418.3 ± 21 | 325.5 ± 49 |
4 | 315.5 ± 60 | 397.2 ± 53 | 419.7 ± 28 | 511.4 ± 19 |
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Gorthy, R.; Krumdieck, S.; Bishop, C. Process-Induced Nanostructures on Anatase Single Crystals via Pulsed-Pressure MOCVD. Materials 2020, 13, 1668. https://doi.org/10.3390/ma13071668
Gorthy R, Krumdieck S, Bishop C. Process-Induced Nanostructures on Anatase Single Crystals via Pulsed-Pressure MOCVD. Materials. 2020; 13(7):1668. https://doi.org/10.3390/ma13071668
Chicago/Turabian StyleGorthy, Rukmini, Susan Krumdieck, and Catherine Bishop. 2020. "Process-Induced Nanostructures on Anatase Single Crystals via Pulsed-Pressure MOCVD" Materials 13, no. 7: 1668. https://doi.org/10.3390/ma13071668