Zeolite NaP1 Functionalization for the Sorption of Metal Complexes with Biodegradable N-(1,2-dicarboxyethyl)-D,L-aspartic Acid
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Instruments
2.3. Methods—Kinetic and Adsorption Experiments
2.4. Calculations
3. Results
3.1. NaP1CS Preparation and Characterization
3.2. Sorption Properties of NaP1CS
3.2.1. Effect of pH and pHZPC
3.2.2. Effect of Time—Kinetic Studies
3.2.3. Effect of Accompanied Ions
3.2.4. Effect of Concentration—Adsorption Isotherms
3.2.5. Comparison of Efficiency of Different Sorbents
3.2.6. Effect of Temperature
3.3. Desorption Process
3.4. Mechanizm of Sorption of [M(idha)](n−m)− Complexes
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Adsorbent | Al6Si2O13 (%) | Fe2O3 (%) | CaO (%) | TiO2 (%) | SiO2 (%) |
---|---|---|---|---|---|
FA | 75.80 | 3.50 | 0.00 | 1.80 | 20.00 |
Element | CS | NaP1CS |
---|---|---|
C (%) | 40.72 | 10.59 |
N (%) | 7.25 | 1.19 |
H (%] | 3.91 | 1.46 |
Parameter | Value | |
---|---|---|
NaP1CS before Adsorption | NaP1CS after Adsorption | |
SBET (m2/g) | 53.5 | 53.4 |
Vmic (a) (cm3/g) | 0.004 | 0.004 |
Smic (a) (m2/g) | 10.68 | 10.47 |
Vtot (b) (cm3/g) | 0.13 | 0.11 |
Dav (c) (Å) | 111 | 95 |
Adsorbate | C0 (mg/dm3) | qeq,exp (mg/g) | Kinetic Parameters | ||
---|---|---|---|---|---|
Pseudo-First Order | |||||
qeq (mg/g) | k1 (1/min) | R2 | |||
Cu(II)–IDHA = 1:1 | 5 | 0.49 | 57.07 | 0.046 | 0.54 |
10 | 0.94 | 7.87 | 0.044 | 0.91 | |
15 | 1.48 | 2.81 | 0.026 | 0.84 | |
20 | 2.47 | 1.25 | 0.023 | 0.95 | |
Fe(III)–IDHA = 1:1 | 10 | 1.28 | 1.59 | 0.025 | 0.98 |
20 | 2.06 | 1.01 | 0.081 | 0.98 | |
30 | 3.11 | 1.56 | 0.035 | 0.97 | |
40 | 4.87 | 2.15 | 0.030 | 0.98 | |
Mn(II)–IDHA = 1:1 | 20 | 4.61 | 2.85 | 0.088 | 0.97 |
40 | 8.76 | 1.84 | 0.042 | 0.87 | |
60 | 11.55 | 4.07 | 0.035 | 0.97 | |
80 | 13.74 | 5.05 | 0.026 | 0.96 | |
Zn(II)–IDHA = 1:1 | 10 | 2.20 | 3.68 | 0.027 | 0.99 |
20 | 2.53 | 1.79 | 0.037 | 0.92 | |
30 | 5.17 | 4.10 | 0.056 | 0.93 | |
40 | 8.78 | 1.03 | 0.072 | 0.99 | |
Pseudo-second order | |||||
qeq (mg/g) | k2 (g/mg·min) | R2 | |||
Cu(II)–IDHA = 1:1 | 5 | 0.49 | 0.49 | 13.609 | 1.00 |
10 | 0.94 | 0.94 | 1.683 | 1.00 | |
15 | 1.48 | 1.48 | 0.421 | 0.99 | |
20 | 2.47 | 2.48 | 0.149 | 0.99 | |
Fe(III)–IDHA = 1:1 | 10 | 1.28 | 1.30 | 0.166 | 0.99 |
20 | 2.06 | 2.10 | 0.221 | 0.99 | |
30 | 3.11 | 3.18 | 0.080 | 0.99 | |
40 | 4.87 | 4.94 | 0.056 | 0.99 | |
Mn(II)–IDHA = 1:1 | 20 | 4.61 | 4.62 | 0.999 | 1.00 |
40 | 8.76 | 8.80 | 0.109 | 0.99 | |
60 | 11.55 | 11.67 | 0.037 | 0.99 | |
80 | 13.74 | 13.84 | 0.024 | 0.99 | |
Zn(II)–IDHA = 1:1 | 10 | 2.20 | 2.20 | 0.560 | 0.99 |
20 | 2.53 | 2.55 | 0.316 | 0.99 | |
30 | 5.17 | 5.60 | 0.020 | 0.99 | |
40 | 8.78 | 8.80 | 0.295 | 1.00 | |
Intraparticle diffusion | |||||
ki (mg/g min1/2) | |||||
k1 | k2 | k3 | |||
Cu(II)–IDHA = 1:1 | 5 | 0.49 | 0.038 | 0.029 | 0.001 |
10 | 0.94 | 0.046 | 0.019 | 0.004 | |
15 | 1.48 | 0.203 | 0.062 | 0.028 | |
20 | 2.47 | 0.236 | 0.064 | 0.079 | |
Fe(III)–IDHA = 1:1 | 10 | 1.28 | 0.090 | 0.076 | 0.062 |
20 | 2.06 | 0.312 | 0.158 | 0.009 | |
30 | 3.11 | 0.445 | 0.173 | 0.062 | |
40 | 4.87 | 0.431 | 0.221 | 0.115 | |
Mn(II)–IDHA = 1:1 | 20 | 4.61 | 0.221 | 0.180 | 0.010 |
40 | 8.76 | 0.990 | 0.250 | 0.062 | |
60 | 11.55 | 1.161 | 0.480 | 0.163 | |
80 | 13.74 | 0.877 | 0.800 | 0.338 | |
Zn(II)–IDHA = 1:1 | 10 | 2.20 | 0.005 | 0.070 | 0.025 |
20 | 2.53 | 0.215 | 0.039 | 0.020 | |
30 | 5.17 | 0.128 | 1.058 | 0.071 | |
40 | 8.78 | 0.270 | 0.158 | 0.022 |
Adsorbate | Isotherm | Parameters | |||
---|---|---|---|---|---|
Langmuir | qm (mg/g) | KL (L/mg) | R2 | RL (-) | |
Cu(II)–IDHA | - | 3.93 | 0.074 | 0.94 | 0.725 |
Fe(III)–IDHA | 17.26 | 0.032 | 0.93 | 0.802 | |
Mn(II)–IDHA | 11.59 | 0.314 | 0.99 | 0.135 | |
Zn(II)–IDHA | 6.14 | 0.069 | 0.96 | 0.545 | |
Freundlich | KF (mg/g) | n (-) | R2 | - | |
Cu(II)–IDHA | - | 3.53 | 1.46 | 0.85 | - |
Fe(III)–IDHA | 1.06 | 1.57 | 0.97 | ||
Mn(II)–IDHA | 5.87 | 5.78 | 0.72 | ||
Zn(II)–IDHA | 1.11 | 2.37 | 0.80 | ||
Dubinin-Radushkevich | Xm (mg/g) | β (mol2/kJ2) | R2 | E (kJ/mol) | |
Cu(II)–IDHA | - | 2014.4 | 0.0066 | 0.87 | 8.69 |
Fe(III)–IDHA | 964.2 | 0.0058 | 0.97 | 9.28 | |
Mn(II)–IDHA | 3109.9 | 0.0017 | 0.81 | 17.01 | |
Zn(II)–IDHA | 3476.7 | 0.0043 | 0.82 | 10.77 | |
Temkin | A (L/g) | b (kJ/mol) | R2 | B (J/mol) | |
Cu(II)–IDHA | - | 1.805 | 2.530 | 0.93 | 0.979 |
Fe(III)–IDHA | - | 1.569 | 0.895 | 0.90 | 2.767 |
Mn(II)–IDHA | - | 127.41 | 1.836 | 0.70 | 1.349 |
Zn(II)–IDHA | - | 1.268 | 1.923 | 0.86 | 1.288 |
Adsorbent | Adsorbate | (ΔH°) (kJ/mol) | (ΔS°) (J/mol K) | (ΔG°) (kJ/mol) | ||
---|---|---|---|---|---|---|
293 K | 313 K | 333 K | ||||
NaP1CS | Cu(II)–IDHA | 5.94 | 16.6 | −10.33 | −11.74 | −12.53 |
Fe(III)–IDHA | 16.80 | 49.1 | −14.41 | −16.55 | −18.67 | |
Mn(II)–IDHA | 19.70 | 44.4 | −10.02 | −12.42 | −14.05 | |
Zn(II)–IDHA | 3.91 | 3.8 | −11.82 | −12.87 | −13.97 |
Solution | Percentage Desorption (%) | |||
---|---|---|---|---|
Cu(II)–IDHA | Fe(III)–IDHA | Mn(II)–IDHA | Zn(II)–IDHA | |
0.5 M NaCl | 25.1 | 0 | 37.5 | 35.2 |
0.5 M NaOH | 1.3 | 0 | 0.3 | 25.7 |
0.5 M KCl | 24.6 | 0 | 26.9 | 0.6 |
0.5 M CH3OH | 4.4 | 0 | 2.7 | 14.2 |
0.5 M HCl | 74.1 | 91.4 | 65.4 | 79.7 |
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Kołodyńska, D.; Ju, Y.; Franus, M.; Franus, W. Zeolite NaP1 Functionalization for the Sorption of Metal Complexes with Biodegradable N-(1,2-dicarboxyethyl)-D,L-aspartic Acid. Materials 2021, 14, 2518. https://doi.org/10.3390/ma14102518
Kołodyńska D, Ju Y, Franus M, Franus W. Zeolite NaP1 Functionalization for the Sorption of Metal Complexes with Biodegradable N-(1,2-dicarboxyethyl)-D,L-aspartic Acid. Materials. 2021; 14(10):2518. https://doi.org/10.3390/ma14102518
Chicago/Turabian StyleKołodyńska, Dorota, Yongming Ju, Małgorzata Franus, and Wojciech Franus. 2021. "Zeolite NaP1 Functionalization for the Sorption of Metal Complexes with Biodegradable N-(1,2-dicarboxyethyl)-D,L-aspartic Acid" Materials 14, no. 10: 2518. https://doi.org/10.3390/ma14102518