1. Introduction
The use of combustion machines began in the 18th century. The need to expel water from mines led to the steam engine’s development, which used wood, coal, or oil as fuel [
1]. Inconveniences such as extreme working conditions, excessive fuel demand, and low efficiency motivated several engineers to apply modifications to improve the steam engine [
2]. These machines’ use in human activities was not common because it was considered expensive, with high maintenance costs and low efficiency [
3]. The initiative to improve the machine began with searching for new fuels that would offer increased power to the pistons [
4]. The use of hydrogen with oxygen in François Isaac de Rivaz’s internal combustion engine was among the first research conducted in this field [
5]. This machine’s development led to research in 1851 on pistons fabricated out of cast iron by Barsanti and Felice Matteucci, in an engine where valves were already used to intake and expel gases. This type of engine started combustion using an electric spark. In 1859 and 1860, engineer Jean Joseph Étienne Lenoir built an engine fitted to the Hippomobile. This engine used benzene as fuel [
4]. The development of various engines, such as George Brayton’s engine in 1872 [
4] or Nikolaus August Otto’s engine in 1877 [
6], formed the basis for the implementation of internal combustion engines in cars used as means of transport [
7]. However, the engineer Rudolf Diesel, based on Nicolas Léonard Sadi Carnot’s machine, built a combustion engine in 1880 that worked from air and fuel explosion when a certain pressure was applied [
8]. In 1897, the engine was fully developed, producing an efficiency of 27%; in comparison, the efficiency of the steam engine was only 10% [
9]. Although this engine had high efficiency, it had drawbacks, such as its noise, heavy weight, and problems with the injection system, which presented obstacles to developing the engine in vehicles [
10]. The implementation of a rotary pump in 1950 by Vernon Roosa in diesel engines boosted diesel engines’ use in transportation, construction machinery, power plants, and water pumps [
11]. The diesel engine development gained in popularity due to its high torque, higher efficiency, resilience to environmental conditions, and reduced pollutant gases [
12].
Henry Ford built the first car in 1896, which used ethanol as fuel. Later, it was replaced by gasoline due to its high energy content [
13]. However, biofuels were used until the end of the 19th century in Europe. Peanut oil was the first biofuel used in Rudolf Diesel’s engine in 1897. The presence of various processes to transform coal into fuel, the laws to use ethanol as a fuel, and/or the end of World War II in several European countries displaced the use and development of biofuels in internal combustion engines [
14]. Regardless, research was conducted by Walton in 1938 on different biofuels fabricated from palm oil, soybean oil, and cottonseed in a diesel engine, showing a fuel economy of 90–91% compared with diesel, although there were problems with the flow of the biofuel and carbon deposits were formed [
15]. By 1944, Martinez de Vedia conducted tests using blends of 20% and 40% linseed oil with fossil diesel. The oil’s lubrication properties, ash, and acidity showed increases over pure diesel, and he also found higher amounts of carbon deposits in the combustion chamber when using blends. Therefore, Martinez proposed decanting the fuel before using injectors and filters to reduce plugging [
16]. Later, Fort and Blumberg used cottonseed oil as fuel in an experimental test, obtaining performance similar to that of fossil diesel, with no variation in power output in a test lasting 200 h [
17]. In 1991, Hemmerlein conducted studies on rapeseed oil and found that the oil’s physical and chemical properties were similar to those of diesel [
18]. Finally, European governments in 1997 modified their plans for the introduction of renewable fuels in their energy market [
14].
In general, different experimental investigations [
19,
20] have shown higher values presented by diesel than by biodiesel when comparing the engine’s thermal efficiency, which increase when the load is raised, whereas the specific fuel consumption of the engine is higher when using biodiesel.
Recently, research carried out in 2015 using blends of 20% Adelfa biodiesel and 80% fossil diesel in a diesel engine produced negative results on performance, combustion characteristics, and emissions due to inadequate air/fuel mixing, and the biofuel had a high viscosity. The solution was to create grooves in the piston head, resulting in higher thermal efficiency and lower specific energy consumption due to better air/fuel mixing. Although carbon monoxide (CO) and hydrocarbon emissions decreased, nitrogen oxide (NOx) emissions increased [
21]. Some researchers applied variations in piston head geometry. The toroidal-shaped piston stands out from the other designs, showing higher performance, better combustion, and decreased pollutant emissions [
22]. This type of piston (toroidal) has been characterized in several experimental tests by increased thermal efficiency, reduction in certain pollutant gases (hydrocarbons (HC) and carbon dioxide (CO
2), reduction in specific fuel consumption [
23], an appropriate air/fuel mixture [
22], and reduction in soot [
24]. The piston design is intended to properly mix the air with the fuel at the injection time to cause complete combustion inside the combustion chamber [
11].
Thermal machines transform thermal energy (heat) into mechanical energy through temperature variation. Heat is obtained from the combustion process (converting fuel into chemical compounds due to an oxidation process) [
25]. The energy in transition is called heat [
26], and this can be released from a substance called fuel. The main fuels are hydrocarbons, hydrogen, carbon, oxygen, nitrogen, sulfur, ash, and moisture [
26,
27]. However, biodiesel is also considered fuel and can be obtained from animal fats, vegetable fats, or waste cooking oils. They are produced through a transesterification process, where they are converted into methyl or ethyl esters derived from fatty acids. This fuel is used either blended or in pure form [
28]. Currently, the problems of oil extraction and the generation of large amounts of pollutant emissions from this fuel have led to the search for new methods of production [
29]. The increase in fuel consumption by the transport sector has led to the use of biofuels from vegetable oils, waste oils, sugars, and animal fats, which are generally mixed with fossil fuels. This type of fuel, called biodiesel, is one option to replace fossil fuels as it has low toxicity and is biodegradable. It is envisaged that by 2050, 27% of energy requirements will be met by biofuels [
30].
In Mexico City, there are Official Mexican Environmental Health Standards that regulate air quality to improve the quality of life of its inhabitants. In 2017, there was a reduction in the admissible suspended particulate matter to preserve health [
31], so the government has implemented laws to incorporate renewable and clean energy into the energy sector [
32]. Means of transport are responsible for 60% of the total consumption of fossil fuels, being large generators of nitrogen oxides (NOx), suspended particles, and carbon dioxide (CO
2) [
33]. The use of biofuels in the energy sector was shown to be an alternative for energy generation and to offer favorable results for the environment [
34]. Mexico is considered to be one of the countries with the resources to generate biofuels from animal fat or used oil [
35].
In this study, we aim to redesign the geometry of the piston head of a diesel engine to improve the combustion process and reduce the generation of polluting gases using biodiesel mixtures as fuel. The properties of the fuels used in this research are based on the ASTM D 975 and ASTM PS 121 standards. The base piston is a four-cylinder pickup truck engine that generates 131 hp at 3600 rpm. The research is oriented to biodiesel as means of transport in large cities, such as Mexico City.
The remainder of this paper is structured as follows:
Section 2 describes the methodology of the analytical calculations of the thermodynamic characteristics of fossil diesel, biofuel, and their mixtures. The new piston design methodology is also provided.
Section 2 describes the process of numerical finite element simulation in the reference piston and the new model. Numerical simulations of pressure and temperature on the piston surface are outlined.
Section 3 provides the results obtained from the analytical calculations and from the numerical simulations of the pistons that allowed the evaluation and comparison of both models. An analysis of the mechanical and thermal behavior of the two models is provided by numerical simulation when temperature and pressure are applied to the upper surface. The results are compared with other investigations on biofuels and piston models.
Section 4 provides our conclusions and future work.
2. Methodology
The mechanical engineering design process (
Figure 1) was used in this research. This methodology starts from identifying the need; in this case, this was the generation of gases during the combustion process of a diesel engine when using biodiesel as a fuel. Subsequently, a preliminary investigation process was initiated. Some proposals to reduce polluting gases were preheating chambers in the combustion chamber, the use of mixtures of fossil fuel with biodiesel, and the change in geometry of the piston head of the diesel engine.
For this research, the change in the geometry of the piston head was chosen, which has shown positive effects towards reduce polluting gases in the combustion process according to various scientific articles. The thermodynamic characteristics of both fuels were determined to obtain the operating temperature. This parameter served as the basis for the numerical simulation (see
Supplementary Material) for the redesign of the piston geometry.
The commercial piston (base piston) of the analyzed diesel engine was taken as a reference. Based on previous studies, specific parameters or characteristics of the geometry of the piston head were obtained that allow the reduction in certain gases. Subsequently, the information obtained from the base piston and from the new design proposal was analyzed. The new design was subjected to mechanical simulations (pressure and temperature) using finite elements to compare the results of both models. The results of the finite element simulations were analyzed and compared with the characteristics of the reference piston.
The results obtained from the volumes, enthalpies, temperatures, and calorific value of the different mixtures are based on the conditions of an adiabatic system, which does not allow the transfer of heat to its surroundings. In addition, it is considered an ideal combustion process, under an ideal diesel cycle, without the intervention of external substances that influence combustion. In the case of fuels (fossil diesel and biodiesel), the calculations are based on properties established by the ASTM D 975 and ASTM PS 121 standards [
28] (See
Supplementary Material: Table S1. Properties of biodiesel and diesel and
Table S2: Chemical composition of fuels). Therefore, for this research, the main objective was to redesign the head geometry of the piston because the design process begins with the modification of the piston geometry and later with the design of other components such as rings, ceramic coatings, heat treatments, and cooling channels.
2.1. Numerical Simulation
2.1.1. Numerical Simulation of the Base Piston
To conduct this simulation, the dimensions of a pickup truck piston were used (
Figure 2a) [
36,
37]. This model served as the basis for comparison and evaluation with the proposed piston head redesign. The finite element method was used because it offers high-quality results and a wide range of results. Symmetry was applied to the model (on the side walls) because only one-quarter of the piston was developed (
Figure 2b). The simulation was performed in Transient Thermal of ANSYS
® 19.2 (Ansys Drive, Canonsburg, PA, USA). In this analysis, an isotropic, linear-elastic, homogeneous, and continuous material was considered. The material used was aluminum 2024.
Table 1 shows the material’s properties.
Figure 3 shows the meshed model after applying high-order elements (intermediate nodes). We considered forced convection to transfer heat between the combustion gases and the valves, cylinder walls, and the piston during the diesel cycle [
40]. The heat transfer was used on the top surface of the piston model with a coefficient of
[
41] for 1 s, assuming an initial temperature of 22 °C.
A compressive pressure of 3.1 MPa [
42] on the piston’s top surface was used to determine the stresses inside the piston. In this simulation, the pin’s area was restricted to 6 degrees of freedom (displacement in x, y, and z directions; rotation in xy, xz, and yz planes).
Figure 3 shows the piston’s meshed model, and the simulation was performed in Static Structural of ANSYS 19.2.
2.1.2. Proposed Redesign for the Piston Head
For the piston redesign process, the information in
Table 2 was considered. In addition, the cone angle must range from 150° to 160° [
43]. In this proposed design, the dimensions of the diameter, the outside diameter of the piston, and the piston rings’ positions were unchanged. Changes were applied to the profile of the piston head to keep the compression ratio constant and confirm that the possible variations that occurred were due to changes in the piston geometry [
19].
Figure 4 shows the dimensions of the modifications to the piston profile geometry and the model used to perform the numerical simulations. Aluminum 2024 was used for this model.
In this simulation, the proper diesel temperature
[
41] with an initial temperature of 22 °C. The simulation was carried out for 1 s.
To determine stresses within the piston head redesign, a compressive pressure of 3.1 MPa [
42] was used on the piston’s top surface. Similarly, the pin’s area was constrained to 6 degrees of freedom (displacement in x, y, and z directions; rotation in xy, xz, and yz planes). The simulation was performed in Static Structural of ANSYS 19.2.
Figure 5 shows a comparison of the base model and the proposed piston geometry.