Preparation and Characterization of a Hybrid Complex of Cyclodextrin-Based Metal—Organic Frameworks-1 and Ascorbic Acid Derivatives
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of CD-MOF-1
2.3. Preparation of ASCP or ASCDP Physical Mixture and Evaporated Samples
2.4. Powder X-ray Diffraction (PXRD) Measurement
2.5. Differential Scanning Calorimetry (DSC) Measurement
2.6. Near-Infrared Absorption Spectroscopy (NIR) Measurement
2.7. Scanning Electron Microscopy (SEM) Measurement
2.8. 1H-1H Nuclear Overhauser Effect Spectroscopy (NOESY) NMR Spectra Measurement
3. Results and Discussion
3.1. Evaluation of the Crystalline State
3.2. Evaluation of Thermal Behavior
3.3. Evaluation of Intermolecular Interaction
3.4. Evaluation of Morphological Properties
3.5. Evaluation of Relative Positional Relationship
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
Abbreviations
MOFs | Metal–organic frameworks |
γ-CD | γ-Cyclodextrin |
CD-MOF-1 | Cyclodextrin-based metal–organic frameworks-1 |
ROS | Reactive oxygen species |
ASC | L(+)-ascorbic Acid |
ASCP | L-ascorbyl 6-palmitate |
ASCDP | L-ascorbyl 2, 6-palmitate |
CoQ10 | Coenzyme Q10 |
FaSSIF | Fasted state simulated intestinal fluid |
PM | Physical mixture |
EVP | Evaporated sample |
PXRD | Powder X-ray diffraction |
DSC | Differential scanning calorimetry |
NIR | Near-infrared absorption spectroscopy |
SEM | Scanning electron microscopy |
NOESY | Nuclear Overhauser effect spectroscopy |
IR | Infrared absorption spectroscopy |
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Nanri, A.; Yoshida, M.; Ishida, Y.; Nakata, D.; Terao, K.; Arce, F.J.; See, G.L.; Tanikawa, T.; Inoue, Y. Preparation and Characterization of a Hybrid Complex of Cyclodextrin-Based Metal—Organic Frameworks-1 and Ascorbic Acid Derivatives. Materials 2021, 14, 7309. https://doi.org/10.3390/ma14237309
Nanri A, Yoshida M, Ishida Y, Nakata D, Terao K, Arce FJ, See GL, Tanikawa T, Inoue Y. Preparation and Characterization of a Hybrid Complex of Cyclodextrin-Based Metal—Organic Frameworks-1 and Ascorbic Acid Derivatives. Materials. 2021; 14(23):7309. https://doi.org/10.3390/ma14237309
Chicago/Turabian StyleNanri, Ayumi, Masaaki Yoshida, Yoshiyuki Ishida, Daisuke Nakata, Keiji Terao, Florencio Jr Arce, Gerard Lee See, Takashi Tanikawa, and Yutaka Inoue. 2021. "Preparation and Characterization of a Hybrid Complex of Cyclodextrin-Based Metal—Organic Frameworks-1 and Ascorbic Acid Derivatives" Materials 14, no. 23: 7309. https://doi.org/10.3390/ma14237309