Adsorption of Pb(II) from Aqueous Solution by Mussel Shell-Based Adsorbent: Preparation, Characterization, and Adsorption Performance
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemical Reagents
2.2. Preparation of Calcined Shell Powder
2.3. Characterization of the Calcined Shell Powder
2.4. Adsorption of Pb(II)
2.5. Desorption Studies
2.6. Standard Deviation Calculations
3. Results and Discussion
3.1. Characterization
3.1.1. FTIR Analysis
3.1.2. DSC Analysis
3.1.3. XRD Analysis
3.1.4. SEM Analysis
3.1.5. XPS Analysis
3.1.6. BET Analysis
3.2. Adsorption Testing
3.2.1. pH
3.2.2. Adsorbent Dosage
3.2.3. Comparison of the Adsorption Performance before and after Calcination
3.2.4. Adsorbent Action Time and Kinetics
3.2.5. Temperature and Thermodynamics
3.2.6. Initial Pb(II) Concentration and Isothermal Models
3.2.7. Desorption Studies
3.2.8. Comparison with Other Adsorbents
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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qe,exp | Pseudo First-Order (PFO) | Pseudo Second-Order (PSO) | ||||
---|---|---|---|---|---|---|
qe,cal | k1 | R2 | qe,cal | k2 | R2 | |
62.48 | 48.51 | 0.0054 | 0.9780 | 59.52 | 0.0168 | 0.9895 |
Concentration (mg/L) | ΔG (kJ/mol) | ΔH (kJ/mol) | ΔS (J/mol) | |||
---|---|---|---|---|---|---|
T (K) | ||||||
293.2 | 298.2 | 303.2 | 308.2 | |||
100 | −0.36 | −0.81 | −1.26 | −1.70 | 25.73 | 89.06 |
T (K) | Langmuir | Freundlich | ||||
---|---|---|---|---|---|---|
qmaxa | B | R2 | KF | N | R2 | |
298.2 | 102.04 | 0.028 | 0.9519 | 5.07 | 1.55 | 0.9992 |
C0 | RL |
---|---|
20 | 0.64 |
40 | 0.47 |
60 | 0.37 |
80 | 0.31 |
100 | 0.26 |
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Wang, Q.; Jiang, F.; Ouyang, X.-K.; Yang, L.-Y.; Wang, Y. Adsorption of Pb(II) from Aqueous Solution by Mussel Shell-Based Adsorbent: Preparation, Characterization, and Adsorption Performance. Materials 2021, 14, 741. https://doi.org/10.3390/ma14040741
Wang Q, Jiang F, Ouyang X-K, Yang L-Y, Wang Y. Adsorption of Pb(II) from Aqueous Solution by Mussel Shell-Based Adsorbent: Preparation, Characterization, and Adsorption Performance. Materials. 2021; 14(4):741. https://doi.org/10.3390/ma14040741
Chicago/Turabian StyleWang, Quan, Fangyuan Jiang, Xiao-Kun Ouyang, Li-Ye Yang, and Yangguang Wang. 2021. "Adsorption of Pb(II) from Aqueous Solution by Mussel Shell-Based Adsorbent: Preparation, Characterization, and Adsorption Performance" Materials 14, no. 4: 741. https://doi.org/10.3390/ma14040741