Next Article in Journal
Bonding of Clear Aligner Composite Attachments to Ceramic Materials: An In Vitro Study
Previous Article in Journal
Comparative Study on the Generation and Characteristics of Debris Induced by Fretting and Sliding
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Effects of Admixtures on Energy Consumption in the Process of Ready-Mixed Concrete Mixing

by
Veerabadrasamy Arularasi
1,*,
Thamilselvi Pachiappan
1,
Siva Avudaiappan
2,3,
Sudharshan Naidu Raman
4,
Pablo Guindos
3,
Mugahed Amran
5,6,*,
Roman Fediuk
7,8 and
Nikolai Ivanovich Vatin
8
1
Department of Civil Engineering, College of Engineering Guindy, Anna University, Chennai 600025, India
2
Departamento de Ingeniería Civil, Universidad de Concepción, Concepción 4070386, Chile
3
Centro Nacional de Excelencia para la Industria de la Madera (CENAMAD), Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago 8331150, Chile
4
School of Engineering, Monash University Malaysia, Jalan Lagoon Selatan, Bandar Sunway 47500, Malaysia
5
Department of Civil Engineering, College of Engineering, Prince Sattam Bin Abdulaziz University, Alkharj 16273, Saudi Arabia
6
Department of Civil Engineering, Faculty of Engineering and IT, Amran University, Amran 9677, Yemen
7
Polytechnic Institute, Far Eastern Federal University, 690922 Vladivostok, Russia
8
Peter the Great St. Petersburg Polytechnic University, 195251 St. Petersburg, Russia
*
Authors to whom correspondence should be addressed.
Materials 2022, 15(12), 4143; https://doi.org/10.3390/ma15124143
Submission received: 25 April 2022 / Revised: 21 May 2022 / Accepted: 8 June 2022 / Published: 10 June 2022

Abstract

:
The production and utilization of concrete and concrete-based products have drastically increased with the surge of construction activities over the last decade, especially in countries such as China and India. Consequently, this has resulted in a corresponding increase in the energy used for the production of ready-mixed concrete. One approach to reduce the cost of concrete manufacturing is to reduce the energy required for the manufacturing process. The main hypothesis of this study is that the power required for mixing the concrete can be reduced through the use of mineral admixtures in the mix design. Optimization of energy consumption during mixing using admixtures in concrete manufacturing is the predominant focus of this article. To achieve this objective, power consumption data were measured and analyzed throughout the concrete mixing process. The power consumption curve is the only source to distinguish the behavior of the different materials used in the concrete in a closed chamber. In the current research, fly ash and ground granulated blast-furnace slag (GGBS) were used as mineral admixtures to produce ready-mixed concrete. The experimental study focused on the influence of GGBS and fly ash on power consumption during concrete mixing. The results indicated that the use of a higher content of GGBS is more beneficial in comparison to the use of fly ash in the mix due to the lower mixing time required to achieve homogeneity in the mixing process. It was found that the amount of energy required for mixing is directly related to the mixing time for the mix to achieve homogeneity.

1. Introduction

Energy consumption is a major issue that is faced globally in the current scenario. In all manufacturing industries, identifying and controlling the processes that consume more energy is a key element in optimizing energy consumption, which will save energy and increase cost-efficiency. Before applying all cost-saving methods to a single factory, all cost-saving methods should be carefully analyzed, because all manufacturing processes require different potential energy, resulting in different energy consumption and material savings [1,2,3]. Through the use of efficient materials and effective energy improvement technologies, the production cost of concrete can be reduced, thereby making the concrete manufacturing industry more successful [4]. An excellent energy-saving plan will reduce annual energy costs by 3 to 10% [1]. The use of energy-saving methods in the manufacturing industry can also reduce waste generated in the production process [3,5,6]. Energy guidelines are provided to identify technical deficiencies that consume more energy. These guidelines provide cost-effective practices that reduce the energy consumption of any product in the manufacturing process [7]. In addition, the task of all concrete manufacturers is to reduce energy costs without compromising product quality [8,9].
Cazacliu [10] explained the new method of concrete mixing and related energy consumption. This method explains the changes in the concrete mixture during the successive stages of concrete mixing. According to him, when concrete mixing is conducted in a closed chamber, power consumption is the only tool to identify the transition phase of the concrete mixture. The author has pointed out that the power consumption value has not been compared with the flow characteristics. Three mixer measurement methods were developed: mixing power, Orbiter (rotating microwave sensor), and Viscoprobe TM (the measurement of resistance on a spherical probe passing through the mixture) [11]. The research was based on on the relationship between the evolution of the microstructure of concrete components and the mixing time. Juez et al. [12] applied image analysis technology to monitor the mixing of concrete and observe the texture of the concrete. At the same time, the power consumption during the concrete mixing process was also recorded and correlated with the texture of the concrete with the captured images [13,14,15,16]. Chopin et al. [17] explained the increase in the homogenization time of superplasticizer concrete and its impact on concrete production. The mixing time for the SCC and HPC is increased due to the homogeneity factor. This article discusses the ability to control uniformity through power consumption measurements. Daumann et al. reported concrete mixing in single-shaft and double-shaft mixers on a laboratory scale [18,19]. The author explains the energy required for the homogenization of concrete in the mixer that can be used for different applications, including 3D-printing [20,21]. Certain characteristics of concrete mixtures will change in relation to one other, such as w/c ratio, mixing time, flow characteristics, aggregate particle size distribution curve, and compressive strength [18]. The application of energy to achieve the homogenization of different mixtures is variable. Only when all the mixtures are of the same homogeneity can the energy required for different concretes be compared. The author uses imaging measurements to determine the homogeneity of the concrete mixture. It can be seen from the above references that the influence of admixtures on concrete mixing and power consumption has not been explored. With this in mind, this article will focus on the impact of admixtures on power consumption during concrete mixing, thereby reducing energy consumption in concrete production in ready-mixed concrete plants. The workability test is also conducted for comparison with the power consumption curve. The power consumption during the mixing process also depends on the flow of the concrete; that is, the rheology of the concrete [22]. Tattersall [23] stated that increasing the water content is the final decision of workers to improve the workability of concrete. To date, the relationship between the power consumption curve and the workability of the concrete has not been concentrated on. From the above literature, it is observed that the power consumption required for the mixing of the concrete has not been studied for the ready-mix concrete. The impact of the admixtures, slump value, and water/powder ratio (w/p) on power consumption during mixing has also not been explored.

1.1. Importance of Mixing

Mixing is the most important stage in concrete manufacturing and is one that consumes the most energy. A ready-mixed concrete factory produces different types of concrete. Mixing plays a vital role in distinguishing different types of concrete. Nowadays, the manufacturing of SCC and HPC has increased due to emerging high-rise buildings and large structures. The power consumption curve obtained during the mixing of concrete gives a better understanding of the microstructural evolution in the concrete mixture [10]. Mixing consists of the evolution of a wet granular state to a granular microstructure suspension [11]. The mixing process is a key element in achieving good quality concrete [18,24,25]. In the current scenario, adequate mixing is not carried out by the concrete manufacturer. There is a lack of knowledge concerning the new materials used in concrete manufacturing. The increase in HPC and SCC productivity provides an opportunity to use new materials in the concrete production industry [12,26,27]. Concrete manufacturers should pay attention to the characteristics and performance of new materials and use appropriate mixing times to obtain high-quality concrete. A longer mixing time is applied in order to properly homogenize the concrete mixture, which affects the mixing efficiency. The elimination of inhomogeneity in the concrete mixture is a result of the mixing efficiency, and thus the mixing of concrete is the important phase for obtaining a quality outcome. Improper mixing leads to weak concrete and structural failure, and it has been common in the construction industry since HPC and SCC came into existence [28,29]. The production of HPC and SCC has given a higher priority to introducing new material into manufacturing concrete; hence, increasing the mixing time should be avoided in order to ensure the quality of the concrete. In the manufacturing of HPC and SCC, concrete manufactures are asked to respect the mixing time of concrete [30,31].

1.2. Mixing Mechanism

Mixing is an important operation that eliminates the inhomogeneity in a mixture. ASTM 305 is commonly used all around the world for mixing procedures [32]. Two important factors that can occur during the mixing operation are intensive mixing and extensive mixing [33]. Intensive mixing reduces agglomeration of the particles held by surface tension. The agglomeration can be reduced when the strength of the inter-particle bond is subject to higher hydrodynamic stresses [34]. During intensive mixing, fine powder is converted into a viscous fluid. In extensive mixing, deformation of the fluid takes place, which increases the interface area between the particles, and hence the inhomogeneity is reduced. Shear history is important for all fresh concrete because the binder-rich SCC exhibits thixotropic and structural breakdown characteristics. In the mixing of fresh concrete, the mixing energy is closely related to the shear rate [35].

1.3. Production and Energy Consumption of Ready-Mixed Concrete

In high-speed construction, concrete production requires more attention because there is no optimal time for concrete mixing [36]. In the past 20 years, ready-mixed concrete plants have produced a large quantity of SCC and HPC. The problems encountered in concrete mixing are mainly concentrated in ready-mixed concrete plants [37]. Measuring power consumption during mixing is important because more than 200 m3 of concrete can be manufactured per day in one ready-mixed concrete plant. In the future, this may increase due to the development of urbanization. In the manufacture of ready-mixed concrete, ingredients are added at specific intervals. Cement, fine aggregate, coarse aggregate, fly ash, GGBS, and water are added one by one into the mixing chamber. As the ingredients are loaded into the mixing chamber, power consumption will increase. The maximum power consumption is obtained when all components are loaded. The first peak is obtained when the mixture of dry ingredients reaches homogeneity in the dry state. After adding water, when a homogeneous mixture is obtained in a wet state, the second peak is reached [10,11]. After the homogenization is obtained, the power consumption is gradually reduced, and then the concrete is discharged.

1.4. The Relation between Power Consumption and the Mixing of Concrete

Power consumption is an important factor in determining the different stages of concrete mixing in the mixing chamber [10]. The power consumption curve is the only tool to determine whether homogeneity is achieved. The homogeneity of concrete varies from one mixture to another [21]. This leads to differences in concrete energy consumption. The power consumption during mixing is divided into different stages. The first stage starts from an empty condition and proceeds to the loading condition. The power consumption will gradually increase during the subsequent loading. In the second stage, the ingredients will mix thoroughly in a dry state, followed by the addition of water, where the moisture is absorbed by the powder particles [10]. At first, the power consumption does not increase because it does not form any liquid bridge. In the third stage, because a liquid bridge is formed between the powder particles, the saturation rate increases, and the gradual mixing will cause a sudden increase in power consumption. Further mixing disintegrates the granular particles to form a paste. At this stage, power consumption will reach its peak. In the fourth stage, homogeneity of the mixture can be achieved by continuously mixing the ingredients, and the concrete can reach full saturation. The starting point of the fourth stage will show higher power consumption, which will gradually decrease once a homogenous mixture is obtained [21,22,23,24].
The gaps identified from the above literatures are as follows: The power consumption required for the mixing of the concrete has not been studied for the ready-mix concrete. The impact of the admixtures, workability, and density of concrete on power consumption during mixing has not been explored.

2. Materials and Methods

In this experimental investigation, energy consumption was measured during the mixing of concrete manufactured in a ready-mixed concrete plant. The mixing motor was connected to the power meter, where the voltage and current consumed during mixing were recorded. The power was calculated by the formula P = V × I. In the ready-mixed concrete plant, 1 m3 of concrete was manufactured for each batch. The total quantity of concrete required for one truck may vary from 6 to 8 m3, and it takes approximately 1 min to mix 1 m3 of concrete in the mixing unit. Three grades of concrete, M25, M30, and M40 were studied. From each grade, four to five mixes were produced by replacing fly ash and GGBS in different percentage, and its energy consumption during mixing was measured and the energy curve plotted. The raw materials used were cement, fine aggregate, coarse aggregate, fly ash, GGBS, and water. All raw materials were stored in different storage locations in the RMC plant, as shown in Figure 1 and Figure 2, and when the mixing operation began, they were transported to the mixing chamber by a conveyor. Two types of high-efficiency water-reducing agents were used: PCE-based (Polycarboxylic ethers), a medium-range water-reducing agent, and SNF-based (Sulfonated naphthalene formaldehyde), a high-range water-reducing agent [37,38,39,40].

2.1. Composition of the Concrete Ingredients

Grade 53 ordinary Portland cement meeting IS 269-2015 (Indian Standard) was used to produce concrete in the RMC plant. Fly ash, conforming to IS 3812-2003, was obtained from the Ennore thermal power plant in India, and was used as a mineral admixture. Another mineral admixture, GGBS, conforming to IS 16714:2018, was also used. Table 1 lists the chemical composition of the binding material and Table 2 gives the physical properties of the binding materials.
M-sand and C-sand were used as fine aggregate and coarse aggregate of size 12 mm and 20 mm, respectively, both the aggregates conforming to IS 383-2016. They were obtained from the locally available market. Both types satisfy the requirements of the Indian standard that complies with grading zone II. Crushed granite stone was used as coarse aggregate with sizes of 12 mm and 20 mm. This was obtained from the local dealers of Chennai, and it satisfies the Indian standard requirement. Table 3 shows the physical properties of the aggregates.
The two chemical admixtures used were Polycarboxylate ether (PCE) and Sulphonate naphthalene formaldehyde (SNF), obtained from CBS Chemicals, and these were used as retarding Superplasticizers. Table 4 shows the chemical properties of the aggregates.
The mix design was calculated according to the Indian standard method by adopting mix code IS 10262-2019. The batching and mixing of the concrete were carried out according to the code IS 4925-2004. The entire manufacturing was carried out in a ready-mixed concrete plant. The Mix compositions and specifications are shown in Table 5 and Table 6.

2.2. Power Meter Reading

The entire power meter readings during the mixing process were recorded, as shown in Figure 3 and Figure 4. A 100 amp watt-meter was connected to the mixer machine. Power consumption was noted down for every second to plot the power curve for the concrete manufactured.
The curve was plotted against time versus power consumption. Each peak represents the mixing of 1 m3 of concrete, i.e., one batch. The total number of peaks represents the total quantity of the concrete manufactured. It can be seen from the curve that the initial reading starts at zero, and as the material is loaded, the power consumption will increase [41]. Energy consumption is calculated by the average method based on the readings obtained during concrete mixing. Figure 5, Figure 6 and Figure 7 show the power consumption curves of M25, M30, and M40.

2.3. Measurement of Slump Value

The slump test is used to measure the workability of concrete. Workability tests are usually performed on all batches of concrete in the ready-mixed concrete plant to check the uniformity of the different batches of concrete manufactured. The slump test will show different values for the same concrete manufactured in the morning and afternoon. The amount of a chemical admixture depends on the slump value of the first batch of concrete produced. After the concrete is discharged from the mixer, the freshly cast concrete is directly composed from the outlet of the truck mixer to perform a slump test. The entire test is carried out in the ready-mixed concrete plant. Furthermore, this research has been extended to correlate power consumption with a slump value, which has not been carried out previously for ready-mixed concrete. The measurement of the slump value is shown in Figure 8.

3. Results and Discussion

The power consumption for the various grades of concrete and the slump value for the corresponding mixes are shown in Table 7. The reason for the increase or decrease in the power consumption for the various mixes is explained in Figure 9, Figure 10, Figure 11 and Figure 12. The slump value obtained for the various mixes is compared to the power consumption to find the workability of the concrete and its impact on power consumption.
It can be seen from Figure 9 that the power consumed by the high-density concrete A1 is almost the same as that of the lower density mixtures A2 and A3. The lower density mixture A4 consumes the least power. In M30 concrete, the density of the mixture of B2, B3, and B4 does not increase or decrease much, even though the density of B2 is very high. In B1, for the minimum density concrete, power consumption is significantly reduced. In the M40 low-density concrete, C1 and C5 indicate higher energy consumption, while higher-density concrete C6 indicates the minimum energy consumption.
From the above observation, we can clearly understand that density is an important factor in power consumption, but it is not the only factor that controls power consumption. The M25- and M30-grade concrete shows similar characteristics in power consumption, i.e., lower density mix consumes minimum power and higher mix consumes maximum power. In higher-grade concrete (M40), the results show the opposite characteristics, namely, high-density concrete consumes the least power, while low-density concrete consumes the most power [42,43], though this does depends on the material used for the concrete mix [44,45,46]. In high-grade concrete, the powder content is usually higher than that of low-grade concrete, as shown in Figure 11. The dosage of the chemical mixture and water content is another important factor in increasing or reducing power consumption. The powder (cement + fly ash + GGBS) in the concrete and the water and chemical admixtures used are important factors that can increase or decrease power consumption during the concrete mixing process, as shown in Figure 10, Figure 11 and Figure 12.
In Figure 10a, it can be seen that the power consumption decreases with the increase of the slump value, which is obvious in A1, A3, and A4. Mix A2 has a lower slump value and consumes more power during mixing, while A1, A3, and A4 have a higher slump value and consume the least power.
In Figure 10b, similar to the previous one, the mix B2 obtains the lower slump value and consumes the maximum power. In contrast, the slump of the mixtures B1, B3, B4, and B5 is higher, and the power consumed during the mixing process is minimal. Similarly, in Figure 10c, C5 reduces slump and consumes maximum power during mixing. The other mixes, C1, C2, C3, and C6, have a higher slump and consume the least power.
The mixtures C1 and C2 have similar compositions and slump values, but the power consumption of C2 is abridged. This reduction may be due to the use of SNF superplasticizer. The composition of the mixtures B4, B5, A2, and A3 are similar, but the purpose of the water-reducing agent is different. SNF is used as a chemical mixture in A3 and B5, which is further explained in Figure 12 below. Certain mixtures (such as A4, B1, and C6) are unique and show very low power consumption. This may be due to the availability of the powder content in the mixture, and therefore requires further inspection, which is explained in the comparison between the w/p ratio and the power consumption.
Figure 11 explains the effect of powder content on power consumption. In M25 concrete, the power consumed by A2 is very high, and it consists of the powder content in the combination of cement and GGBS. Mixture A4 consumes the least power and contains a higher content of cement, fly ash, and GGBS. In M30 concrete, the minimum power is consumed by B1, which is composed of cement and GGBS. Mixture B2, which is a combination of cement, fly ash, and GGBS, consumes the maximum power. In M40 concrete, the minimum power is consumed by mixture C6, which includes cement and GGBS. Mixture C5 consumes the maximum power, and is composed of the powder content of cement and fly ash.
The amalgamation of powder content for each concrete has a different effect on power consumption. In most cases, the combination of cement and fly ash consumes more power during the mixing process, while the combination of cement and GGBS consumes the least power [21,26,47,48]. When observing these three grades of concrete, it can be seen that the combination of powder content is another factor that affects power consumption. The molecular structure of the powder enhances the smooth mixing of the concrete in the fresh state [49]. Smooth mixing and rough mixing will cause differences in power consumption [50]. The powder is mixed with water and superplasticizer to form granules. These pastes will bind fine and coarse aggregates, causing wear on the surface of the mixing drum. The molecular structure of the paste is the main factor in reducing the inter-particle wear between the components and the wear on the sidewall of the mixing drum [51]. Therefore, Figure 12A–C further explains the behavior of powder and water in order to provide a clear understanding of the energy consumption of concrete during mixing.
In Figure 12A, A1 and A4 show the minimum power consumption as the w/p ratio decreases. The power consumption increases as the w/p ratio increases. When comparing these two mixtures, A1 and A4, with similar w/p ratios, it can be seen that the combination of powders is an important criterion for increasing or reducing power consumption. In A1, the combination of cement and fly ash consumes more power than A4 (composed of a combination of cement and GGBS). The composition of the mixtures A2 and A3 is similar, but the dosage and type of the water-reducing agents are different. In A4, SNF superplasticizer is used, which has the lowest power consumption. In Figure 12B, when cement and GGBS are combined, B1 consumes the lowest power and has a very high w/p ratio. The mixture B2 consumes more power for low w/p ratio with a combination of cement, fly ash, and GGBS. In a similar mix of B4 and B5, B5 has a smaller power consumption than B4.
Among C1, C2, and C3, which have similar compositions but differ in the type and dosage of superplasticizer, C2, which contains SNF as a superplasticizer, consumes minimum power during mixing. With the combination of fly ash and cement, the w/p ratio increases and mixture C5 consumes the maximum power. Of the mixtures C4 and C6, mixture C4, consisting of cement and fly ash, consumes the maximum power, while mixture C6, composed of cement and GGBS, consumes the minimum power.
The enlargement of the particle size is called granulation, and it depends on the powder used in the mixing process [49,51,52]. Spherical particles and well-compacted particles reduce the duration of the mixing operation. In the shear mixture, the formation of granules is a very sensitive phenomenon that controls the mixing operation. In high-shear mixtures, the characteristics of the powder content and the formation of granules both have an impact on the power consumption during the mixing operation. The amount of binder also controls the mixing operation and reduces power consumption. The cohesive force involved in the agglomeration also causes an impact on power consumption [53,54]. Cohesive force is caused by the liquid bridge between the solid particles and relies on the surface tension of the granulation liquid. The force required to separate the agglomerates, which are achieved by the coalescence of many primary particles, will always be higher than the force required for the nucleation of the primary particles. The addition of viscous material can reduce the separating force of the liquid bridge [54,55,56,57]. In this study, granules consisting of fly ash and GGBS are responsible for the increase or decrease in power consumption, respectively. The well-defined spherical shape of GGBS forms granules, which can decrease friction during the mixing operation and therefore decrease power consumption.

4. Conclusions

The change in power consumption is primarily a result of the different materials included to the concrete mixture. The mineral admixtures used in concrete have different chemical and physical properties. As a result, all materials act differently. Identifying the materials that can minimize energy consumption and using them in concrete production can reduce the energy required for the manufacturing process.
Energy optimization in all areas is the ultimate goal in the protection of our natural resources. It can be seen from the above results that the maximum use of powder content has an impact on the energy consumption, thereby achieving the homogeneity of the concrete during the mixing process. However, the following conclusions were drawn based on the major findings of this study:
A maximum fly ash content of 22% increases the power consumption by 19.27–20.28%. Inversely, a minimum fly ash content of 16–18% decreases the power consumption by 1.3–9.83%. A GGBS content of 35–44% increases the power consumption by 3.8–20.8%.
For the slump value, 16–18% of fly ash increases the value by 12.5–25%, and hence there is a decrease in the power consumption. A fly ash content of 22% decreases the slump by 11.8 to 15.8%, and there is a corresponding increase in the power consumption by 19.27 to 20.28%. There is an increase in the slump value of 6.7–16.8% for 35–44% GGBS content.
It is obvious from the findings that the maximum use of fly ash will consume more energy to achieve homogeneity and increase the energy required for concrete production.
For concrete containing fly ash, its curve profile, which is visible in the energy consumption curve, rises and falls unevenly due to the formation of granules when fly ash and GGBS are mixed with water.
The quality of the mixing depends upon the degree of homogeneity attained at the end. The homogeneity obtained depends on several factors, such as the properties of single particles, the properties of bulk particles, operating conditions, and mix design.
It was found that an increase or decrease in water content may also lead to an increase or decrease in power consumption. The texture of the aggregate and the mineral admixtures added to the concrete can cause internal abrasion on the surface of the mixing drum.
Aggregate and mineral admixture wear and particle collisions are other factors leading to increased power consumption. The mixer drum has difficulty blending certain materials because hard particles prevent blending and overcome the torque, so the drum consumes excess power in order to rotate. This could be one of the key reasons for the difference in power depletion when using different mineral admixtures.

Author Contributions

Conceptualization, V.A. and T.P.; data curation, V.A., T.P., S.A., S.N.R., P.G., M.A., R.F. and N.I.V.; formal analysis, V.A., T.P., S.A., S.N.R., P.G., M.A., R.F. and N.I.V.; funding acquisition, M.A., R.F. and N.I.V.; investigation, V.A. and T.P.; methodology, V.A. and T.P.; project administration, N.I.V.; resources, S.A., S.N.R., P.G., M.A., R.F. and N.I.V.; software, S.A. and P.G.; supervision, T.P. and N.I.V.; validation, T.P., S.A., S.N.R., P.G., M.A., R.F. and N.I.V.; visualization, S.A., S.N.R., P.G., M.A., R.F. and N.I.V.; writing—original draft, V.A.; writing—review and editing, T.P., S.A., S.N.R., P.G., M.A., R.F. and N.I.V. All authors have read and agreed to the published version of the manuscript.

Funding

The research was partially funded by the Ministry of Science and Higher Education of the Russian Federation under the strategic academic leadership program ‘Priority 2030’ (Agreement 075-15-2021-1333 dated 30 September 2021).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Acknowledgments

The authors acknowledge support from Ayyappan Kalaivanan, the director at SUNX Concrete, Chennai, India, and Arumugasamy Subramaniam, the director of VRMX concrete Pvt Ltd., Chennai, India, who allowed the performance energy measurements during the mixing process in concrete manufacturing. Centro Nacional de Excelencia para la Industria de la Madera (ANID BASAL FB210015 CENAMAD), Pontificia Universidad Católica de Chile, Vicuña Mackenna 7860, Santiago, Chile. The authors also gratefully acknowledge the financial support given by the Deanship of Scientific Research at Prince Sattam bin Abdulaziz University, Alkharj, Saudi Arabia, for this research.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Kermeli, K.; Worrell, E.; Masanet, E. Energy Efficiency Improvement and Cost Saving Opportunities for the Concrete Industry. An ENERGY STAR® Guide for Energy and Plant Managers; The U.S. Environmental Protection Agency: Berkeley, CA, USA, 2011.
  2. Lee, Y.H.; Chua, N.; Amran, M.; Lee, Y.Y.; Kueh, A.H.; Fediuk, R.; Vatin, N.; Vasilev, Y. Thermal Performance of Structural Lightweight Concrete Composites for Potential Energy Saving. Crystals 2021, 11, 461. [Google Scholar] [CrossRef]
  3. Lee, Y.H.; Amran, M.; Lee, Y.Y.; Kueh, A.B.H.; Kiew, S.F.; Fediuk, R.; Vatin, N.; Vasilev, Y. Thermal behavior and energy efficiency of modified concretes in the tropical climate: A systemic review. Sustainability 2021, 13, 11957. [Google Scholar] [CrossRef]
  4. Makul, N.; Fediuk, R.; Amran, M.; Al-Akwaa, M.S.; Pralat, K.; Nemova, D.; Petropavlovskii, K.; Novichenkova, T.; Petropavlovskaya, V.; Sulman, M. Utilization of biomass to ash: An overview of the potential resources for alternative energy. Materials 2021, 14, 6482. [Google Scholar] [CrossRef]
  5. Miryuk, O.; Fediuk, R.; Amran, M. Foam Glass Crystalline Granular Material from a Polymineral Raw Mix. Crystals 2021, 11, 1447. [Google Scholar] [CrossRef]
  6. Kozin, A.; Fediuk, R.; Yarysova, S.; Gordienko, P.; Lesovik, V.; Mosaberpanah, M.A.; Amran, M.; Gunasekaran, M. Improvement of mechanical characteristics of mortar by using of wollastonite. Mag. Civ. Eng. 2021, 7, 10715. [Google Scholar]
  7. Sorensen, C.; Berge, E.; Nikolaisen, E.B. Investigation of Fiber Distribution in Concrete Batches Discharged from Ready-Mix Truck. Int. J. Concr. Struct. Mater. 2014, 8, 279–287. [Google Scholar] [CrossRef] [Green Version]
  8. Avudaiappan, S.; Amran, M.; Aepuru, R.; Fediuk, R.; Vatin, N. Prediction of Pore Volume Dispersion and Microstructural Characteristics of Concrete Using Image Processing Technique. Crystals 2021, 11, 1476. [Google Scholar]
  9. Lesovik, V.S.; Ahmed, A.A.; Fediuk, R.S.; Kozlenko, B.; Amran, Y.H.M.; Alaskhanov, A.K.; Asaad, M.A.; Murali, G.; Uvarov, V.A. Performance investigation of demolition wastes-based concrete composites. Mag. Civ. Eng. 2021, 106, 10608. [Google Scholar] [CrossRef]
  10. Cazacliu, B.; Roquet, N. Concrete mixing kinetics by means of power measurement. Cem. Concr. Res. 2009, 39, 182–194. [Google Scholar] [CrossRef]
  11. Cazacliu, B. In-mixer measurements for describing mixture evolution during concrete mixing. Chem. Eng. Res. Des. 2008, 86, 1423–1433. [Google Scholar] [CrossRef]
  12. Moreno Juez, J.; Artoni, R.; Cazacliu, B. Monitoring of concrete mixing evolution using image analysis. Powder Technol. 2017, 305, 477–487. [Google Scholar] [CrossRef] [Green Version]
  13. Kolesnikov, A.; Fediuk, R.; Amran, M.; Klyuev, S.; Klyuev, A.; Volokitina, I.; Naukenova, A.; Shapalov, S.; Utelbayeva, A.; Kolesnikova, O.; et al. Modeling of Non-Ferrous Metallurgy Waste Disposal with the Production of Iron Silicides and Zinc Distillation. Materials 2022, 15, 2542. [Google Scholar] [CrossRef]
  14. Loganina, V.; Davydova, O.; Fediuk, R.; Amran, M.; Klyuev, S.; Klyuev, A.; Sabitov, L.; Nabiullina, K. Improving the Durability of Lime Finishing Mortars by Modifying Them with Silicic Acid Sol. Materials 2022, 15, 2360. [Google Scholar] [CrossRef]
  15. Raju, S.; Rathinam, J.; Dharmar, B.; Rekha, S.; Avudaiappan, S.; Amran, M.; Ramamoorthy, R.V. Cyclically Loaded Copper Slag Admixed Reinforced Concrete Beams with Cement Partially Replaced with Fly Ash. Materials 2022, 15, 3101. [Google Scholar] [CrossRef]
  16. Subash, N.; Avudaiappan, S.; Adish Kumar, S.; Amran, M.; Vatin, N.; Fediuk, R.; Aepuru, R. Experimental Investigation on Geopolymer Concrete with Various Sustainable Mineral Ashes. Materials 2021, 14, 7596. [Google Scholar] [CrossRef]
  17. Chopin, D.; Cazacliu, B.; de Larrard, F.; Schell, R. Monitoring of concrete homogenisation with the power consumption curve. Mater. Struct. Constr. 2007, 40, 897–907. [Google Scholar] [CrossRef]
  18. Daumann, B.; Anlauf, H.; Nirschl, H. Determination of the energy consumption during the production of various concrete recipes. Cem. Concr. Res. 2009, 39, 590–599. [Google Scholar] [CrossRef]
  19. Avudaiappan, S.; Prakatanoju, S.; Amran, M.; Aepuru, R.; Saavedra Flores, E.I.; Das, R.; Gupta, R.; Fediuk, R.; Vatin, N. Experimental Investigation and Image Processing to Predict the Properties of Concrete with the Addition of Nano Silica and Rice Husk Ash. Crystals 2021, 11, 1230. [Google Scholar] [CrossRef]
  20. Lesovik, V.; Fediuk, R.; Amran, M.; Alaskhanov, A.; Volodchenko, A.; Murali, G.; Uvarov, V.; Elistratkin, M. 3d-printed mortars with combined steel and polypropylene fibers. Fibers 2021, 9, 79. [Google Scholar] [CrossRef]
  21. Arularasi, V.; Thamilselvi, P.; Avudaiappan, S.; Flores, E.I.S.; Amran, M.; Fediuk, R.; Vatin, N.; Karelina, M. Rheological behavior and strength characteristics of cement paste and mortar with fly ash and GGBS admixtures. Sustainability 2021, 13, 9600. [Google Scholar] [CrossRef]
  22. Jang, K.P.; Kwon, S.H.; Choi, M.S.; Kim, Y.J.; Park, C.K.; Shah, S.P. Experimental Observation on Variation of Rheological Properties during Concrete Pumping. Int. J. Concr. Struct. Mater. 2018, 12, 79. [Google Scholar] [CrossRef]
  23. Tattersall, G.H.; Banfill, P.F. The Rheology of Fresh Concrete, 1st ed.; Pitman Books Limited: London, UK, 1983. [Google Scholar]
  24. Amran, M.; Abdelgader, H.S.; Onaizi, A.M.; Fediuk, R.; Ozbakkaloglu, T.; Rashid, R.S.; Murali, G. 3D-printable alkali-activated concretes for building applications: A critical review. Constr. Build. Mater. 2022, 319, 126126. [Google Scholar] [CrossRef]
  25. Klyuev, S.; Klyuev, A.; Fediuk, R.; Ageeva, M.; Fomina, E.; Amran, M.; Murali, G. Fresh and mechanical properties of low-cement mortars for 3D printing. Constr. Build. Mater. 2022, 338, 127644. [Google Scholar] [CrossRef]
  26. Chakrawarthi, V.; Avudaiappan, S.; Amran, M.; Dharmar, B.; Raj Jesuarulraj, L.; Fediuk, R.; Saavedra Flores, E. Impact Resistance of Polypropylene Fibre-Reinforced Alkali–Activated Copper Slag Concrete. Materials 2021, 14, 7735. [Google Scholar] [CrossRef]
  27. Makul, N.; Fediuk, R.; Amran, H.M.M.; Zeyad, A.M.; de Azevedo, A.R.G.; Klyuev, S.; Vatin, N.; Karelina, M. Capacity to develop recycled aggregate concrete in south east asia. Buildings 2021, 11, 234. [Google Scholar] [CrossRef]
  28. Dils, J.; De Schutter, G.; Boel, V. Influence of mixing procedure and mixer type on fresh and hardened properties of concrete: A review. Mater. Struct. 2012, 45, 1673–1683. [Google Scholar] [CrossRef]
  29. Mazanec, O.; Lowke, D.; Schiel, P. Mixing of high performance concrete: Effect of concrete composition and mixing intensity on mixing time. Mater. Struct. Constr. 2010, 43, 357–365. [Google Scholar] [CrossRef]
  30. Beitzel, H. Optimisation of the Mixing Process for Producing SCHP Concrete; RILEM Bookseries; Springer: Berlin/Heidelberg, Germany, 2010; Volume 1, pp. 175–183. [Google Scholar] [CrossRef]
  31. Cazacliu, B.; Legrand, J. Characterization of the granular-to-fluid state process during mixing by power evolution in a planetary concrete mixer. Chem. Eng. Sci. 2008, 63, 4617–4630. [Google Scholar] [CrossRef]
  32. Yang, M.; Jennings, H.M. Influences of mixing methods on the microstructure and rheological behavior of cement paste. Adv. Cem. Based Mater. 1995, 2, 70–78. [Google Scholar] [CrossRef]
  33. Lim, J.L.G.; Raman, S.N.; Lai, F.C.; Zain, M.F.M.; Hamid, R. Synthesis of nano cementitious additives from agricultural wastes for the production of sustainable concrete. J. Clean. Prod. 2018, 171, 1150–1160. [Google Scholar] [CrossRef]
  34. Lim, J.L.G.; Raman, S.N.; Safiuddin, M.; Zain, M.F.M.; Hamid, R. Autogenous Shrinkage, Microstructure, and Strength of Ultra-High Performance Concrete Incorporating Carbon Nanofibers. Materials 2019, 12, 320. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  35. Wallevik, J.E.; Wallevik, O.H. Analysis of shear rate inside a concrete truck mixer. Cem. Concr. Res. 2017, 95, 9–17. [Google Scholar] [CrossRef]
  36. Wang, K.; Hu, J. Use of a moisture sensor for monitoring the effect of mixing procedure on uniformity of concrete mixtures. J. Adv. Concr. Technol. 2005, 3, 371–383. [Google Scholar] [CrossRef] [Green Version]
  37. Chopin, D.; de Larrard, F.; Cazacliu, B. Why do HPC and SCC require a longer mixing time? Cem. Concr. Res. 2004, 34, 2237–2243. [Google Scholar] [CrossRef]
  38. Ngo, H.T.; Kaci, A.; Kadri, E.H.; Ngo, T.T.; Trudel, A.; Lecrux, S. Energy consumption reduction in concrete mixing process by optimizing mixing time. Energy Procedia 2017, 139, 810–816. [Google Scholar] [CrossRef]
  39. Kazaz, A.; Ulubeyli, S.; Er, B.; Arslan, V.; Arslan, A.; Atici, M. Fresh Ready-mixed Concrete Waste in Construction Projects: A Planning Approach. Procedia Eng. 2015, 123, 268–275. [Google Scholar] [CrossRef] [Green Version]
  40. Nelubova, V.; Strokova, V.; Fediuk, R.; Amran, M.; Vatin, N.; Vasilev, Y. Effect of an aluminosilicate disperse additive on behaviors of autoclave silicate materials. Buildings 2021, 11, 239. [Google Scholar] [CrossRef]
  41. Collet, R.; Oulahna, D.; de Ryck, A.; Jezequel, P.H.; Martin, M. Mixing of a wet granular medium: Effect of the particle size, the liquid and the granular compacity on the intensity consumption. Chem. Eng. J. 2010, 164, 299–304. [Google Scholar] [CrossRef]
  42. Lesovik, V.; Volodchenko, A.; Fediuk, R.; Mugahed Amran, Y.H. Improving the Hardened Properties of Nonautoclaved Silicate Materials Using Nanodispersed Mine Waste. J. Mater. Civ. Eng. 2021, 33, 4021214. [Google Scholar] [CrossRef]
  43. Lesovik, V.; Volodchenko, A.; Fediuk, R.; Mugahed Amran, Y.H.; Timokhin, R. Enhancing performances of clay masonry materials based on nanosize mine waste. Constr. Build. Mater. 2021, 269, 121333. [Google Scholar] [CrossRef]
  44. Arularasi, V.; Thamilselvi, P.; Avudaiappan, S.; Flores, E.I.S. Energy Consumption of Self-Compacting Concrete during Mixing and Its Impact on the Yield Stress Measured in the Ready-Mix Concrete Plant. Adv. Civ. Eng. 2021, 2021, 6664577. [Google Scholar] [CrossRef]
  45. Raman, S.N.; Ngo, T.; Mendis, P.; Mahmud, H.B. High-strength rice husk ash concrete incorporating quarry dust as a partial substitute for sand. Constr. Build. Mater. 2011, 25, 3123–3130. [Google Scholar] [CrossRef]
  46. Tamanna, K.; Raman, S.N.; Jamil, M.; Hamid, R. Utilization of wood waste ash in construction technology: A review. Constr. Build. Mater. 2020, 237, 117654. [Google Scholar] [CrossRef]
  47. Tang, Y.X.; Lee, Y.H.; Amran, M.; Fediuk, R.; Vatin, N.; Kueh, A.B.H.; Lee, Y.Y. Artificial Neural Network-Forecasted Compression Strength of Alkaline-Activated Slag Concretes. Sustainability 2022, 14, 5214. [Google Scholar] [CrossRef]
  48. Amran, M.; Murali, G.; Khalid, N.H.A.; Fediuk, R.; Ozbakkaloglu, T.; Lee, Y.H.; Haruna, S.; Lee, Y.Y. Slag uses in making an ecofriendly and sustainable concrete: A review. Constr. Build. Mater. 2021, 272, 121942. [Google Scholar] [CrossRef]
  49. Watano, S. Direct control of wet granulation processes by image processing system. Powder Technol. 2001, 117, 163–172. [Google Scholar] [CrossRef]
  50. Leuenberger, H.; Betz, G. Chapter 15 Granulation process control—Production of pharmaceutical granules: The classical batch concept and the problem of scale-up. Handb. Powder Technol. 2007, 11, 705–733. [Google Scholar] [CrossRef]
  51. Kristensen, H.G. Particle agglomeration in high shear mixers. Powder Technol. 1996, 88, 197–202. [Google Scholar] [CrossRef]
  52. Watano, S. Chapter 10 Online monitoring. Handb. Powder Technol. 2007, 11, 477–498. [Google Scholar] [CrossRef]
  53. Kazaz, A.; Ulubeyli, S. Current Methods for the Utilization of the Fresh Concrete Waste Returned to Batching Plants. Procedia Eng. 2016, 161, 42–46. [Google Scholar] [CrossRef] [Green Version]
  54. Leuenberger, H. Granulation, new techniques. Pharm. Acta Helv. 1982, 57, 72–82. [Google Scholar]
  55. Daumann, B.; Fath, A.; Anlauf, H.; Nirschl, H. Determination of the mixing time in a discontinuous powder mixer by using image analysis. Chem. Eng. Sci. 2009, 64, 2320–2331. [Google Scholar] [CrossRef] [Green Version]
  56. Daumann, B.; Nirschl, H. Assessment of the mixing efficiency of solid mixtures by means of image analysis. Powder Technol. 2008, 182, 415–423. [Google Scholar] [CrossRef] [Green Version]
  57. Wang, Y.; Huang, J.; Wang, D.; Liu, Y.; Zhao, Z.; Liu, J. Experimental investigation on thermal conductivity of aerogel-incorporated concrete under various hygrothermal environment. Energy 2019, 188, 115999. [Google Scholar] [CrossRef]
Figure 1. Storage of coarse aggregate and fine aggregate in the RMC plant.
Figure 1. Storage of coarse aggregate and fine aggregate in the RMC plant.
Materials 15 04143 g001
Figure 2. Storage of cement, fly ash, and GGBS in silos.
Figure 2. Storage of cement, fly ash, and GGBS in silos.
Materials 15 04143 g002
Figure 3. Power meter shows the reading of voltage and current during the mixing operation.
Figure 3. Power meter shows the reading of voltage and current during the mixing operation.
Materials 15 04143 g003
Figure 4. Recording the power meter reading during the mixing operation.
Figure 4. Recording the power meter reading during the mixing operation.
Materials 15 04143 g004
Figure 5. Energy consumption curve for M25 grade concrete for Mix A1, A2, A3, and A4. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer, (expressed in %).
Figure 5. Energy consumption curve for M25 grade concrete for Mix A1, A2, A3, and A4. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer, (expressed in %).
Materials 15 04143 g005
Figure 6. Energy consumption curve for M30 grade concrete for Mix B1, B2, B3, B4, and B5. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer (expressed in %).
Figure 6. Energy consumption curve for M30 grade concrete for Mix B1, B2, B3, B4, and B5. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer (expressed in %).
Materials 15 04143 g006aMaterials 15 04143 g006b
Figure 7. Energy consumption curve for M40 grade concrete for Mix C1, C2, C3, C4, C5, and C6. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer (expressed in %).
Figure 7. Energy consumption curve for M40 grade concrete for Mix C1, C2, C3, C4, C5, and C6. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer (expressed in %).
Materials 15 04143 g007
Figure 8. Measuring the slump value.
Figure 8. Measuring the slump value.
Materials 15 04143 g008
Figure 9. Power consumption versus density of concrete.
Figure 9. Power consumption versus density of concrete.
Materials 15 04143 g009
Figure 10. Power consumption versus slump value for (a) M25 grade concrete, (b) M30 grade concrete, (c) M40 grade concrete.
Figure 10. Power consumption versus slump value for (a) M25 grade concrete, (b) M30 grade concrete, (c) M40 grade concrete.
Materials 15 04143 g010
Figure 11. Power consumption versus total powder content (GGBS + fly ash + cement), GGBS, cement content, and fly ash.
Figure 11. Power consumption versus total powder content (GGBS + fly ash + cement), GGBS, cement content, and fly ash.
Materials 15 04143 g011
Figure 12. Power consumption versus w/p ratio for (A) M25 grade concrete, (B) M30 grade, (C) M40 grade concrete. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer. A3, B5, and C5, Materials 15 04143 i001—SNF is used and for other mixes, Materials 15 04143 i002—PCE is used.
Figure 12. Power consumption versus w/p ratio for (A) M25 grade concrete, (B) M30 grade, (C) M40 grade concrete. C—Cement, F—Fly ash, G—GGBS, SP—Superplasticizer. A3, B5, and C5, Materials 15 04143 i001—SNF is used and for other mixes, Materials 15 04143 i002—PCE is used.
Materials 15 04143 g012aMaterials 15 04143 g012b
Table 1. Chemical composition of the used materials (expressed in %).
Table 1. Chemical composition of the used materials (expressed in %).
ComponentsSiO2Al2O3CaOMgOFe2O3SO3SClNa2OK2OTiO2Mn2O3
Cement23.66.262.32.53.11.9-0.03----
Fly ash51.518.85.71.917.12.50.5-0.40.60.750.12
GGBS32.511.241.310.62.10.5---0.320.60.35
Table 2. Physical properties of the used materials.
Table 2. Physical properties of the used materials.
PropertiesCementGGBSFly Ash
Initial setting time (min)309080
Specific gravity3.152.92.7
Normal consistency (%)29--
Final setting time (min)510550580
Specific surface area, m2/kg300375390
Table 3. Properties of aggregates.
Table 3. Properties of aggregates.
PropertiesSand #1
(Sand-C)
Sand #2
(Sand-M)
Gravel #1
(12 mm)
Gravel #2
(20 mm)
Specific gravity2.62.72.62.6
Water absorption0.91.711
Fineness modulus3.33.45.26.5
Table 4. Chemical admixture properties.
Table 4. Chemical admixture properties.
ParameterSNFPCE
Chemical nameSulphonated naphthalene formaldehydePolycarboxylic Ether
AppearanceReddish-brown liquidLight-brown liquid
pH66
Relative density1.111.07
Chloride content0.2%0.1%
TypeRetarding SuperplasticizerRetarding Superplasticizer
Table 5. Concrete Mix Compositions.
Table 5. Concrete Mix Compositions.
ComponentsCementC-SandM-SandFly AshGGBSWaterSuperplasticizer
MixGrade kg/m3 Quantity (kg)Type
A1M253304323227001672.6PCE
A2M2520040040001501682.1PCE
A3M2520045830501501652.8SNF
A4M25200438292501501652.4PCE
B1M3024036036001401672.28PCE
B2M30200444290501701652.52PCE
B3M3026038238201401652.6PCE
B4M3026038238201401652.8PCE
B5M3026038238201401652.8SNF
C1M4025035035002001642.25PCE
C2M4025035035002001642.25SNF
C3M4025035035002001642.25PCE
C4M404103633638001652.45PCE
C5M4036034934910001682.76PCE
C6M4028035035002001652.88PCE
Table 6. Concrete Mix specifications.
Table 6. Concrete Mix specifications.
MixWater/PowderTotal Quantity (m3)Batch Quantity (m3)Duration of Mixing (Min)
A10.413617.48
A20.48618.15
A30.471618.25
A40.413615.25
B10.439418.55
B20.393618.4
B30.413619.23
B40.4136110.4
B50.413618.15
C10.364516.34
C20.364719.53
C30.364415.15
C40.337617.42
C50.365516.08
C60.344618.27
Table 7. The power consumption and slump value measured for different mixes.
Table 7. The power consumption and slump value measured for different mixes.
MixPower Consumption (kW)Slump (mm)
A13.547200
A23.595160
A33.568190
A43.436160
B13.042170
B23.659150
B33.638160
B43.675170
B53.568170
C13.744180
C23.477180
C33.536170
C43.685190
C54.086160
C63.426180
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Share and Cite

MDPI and ACS Style

Arularasi, V.; Pachiappan, T.; Avudaiappan, S.; Raman, S.N.; Guindos, P.; Amran, M.; Fediuk, R.; Vatin, N.I. Effects of Admixtures on Energy Consumption in the Process of Ready-Mixed Concrete Mixing. Materials 2022, 15, 4143. https://doi.org/10.3390/ma15124143

AMA Style

Arularasi V, Pachiappan T, Avudaiappan S, Raman SN, Guindos P, Amran M, Fediuk R, Vatin NI. Effects of Admixtures on Energy Consumption in the Process of Ready-Mixed Concrete Mixing. Materials. 2022; 15(12):4143. https://doi.org/10.3390/ma15124143

Chicago/Turabian Style

Arularasi, Veerabadrasamy, Thamilselvi Pachiappan, Siva Avudaiappan, Sudharshan Naidu Raman, Pablo Guindos, Mugahed Amran, Roman Fediuk, and Nikolai Ivanovich Vatin. 2022. "Effects of Admixtures on Energy Consumption in the Process of Ready-Mixed Concrete Mixing" Materials 15, no. 12: 4143. https://doi.org/10.3390/ma15124143

APA Style

Arularasi, V., Pachiappan, T., Avudaiappan, S., Raman, S. N., Guindos, P., Amran, M., Fediuk, R., & Vatin, N. I. (2022). Effects of Admixtures on Energy Consumption in the Process of Ready-Mixed Concrete Mixing. Materials, 15(12), 4143. https://doi.org/10.3390/ma15124143

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop