A Sustainable Technique to Prepare High-Purity Vanadium Pentoxide via Purification with Low Ammonium Consumption
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Experimental Steps
2.2.1. Hydrolyzed Vanadium Precipitation
2.2.2. Ammonium Salt Purification
3. Characterizations and Analysis
4. Results and Discussion
4.1. Effects of Hydrolyzed Vanadium Precipitation Conditions on Precipitation Efficiency
4.2. Ammonium Salt Purification
4.2.1. Effect of Detergent on Ammonium Salt Purification
4.2.2. Effect of Ammonium Addition Coefficient on Product Purity
4.2.3. Effect of Purification Time on Product Purity
4.2.4. Effect of Purification Frequency on Product Purity
4.2.5. Effect of Purification Temperature on Product Purity
4.3. Characterization of V2O5 Product
4.4. Comparison of Vanadium Preparation Processes
4.5. Composition and Structure of Purified Products
Crystal Purification Mechanism
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Element | V | K | Ca | Na | Mg | Al | Si | P | As | Fe |
---|---|---|---|---|---|---|---|---|---|---|
Content | 42.27 | 0.37 | 0.44 | 0.42 | 0.08 | 8.80 | 0.26 | 0.48 | 0.37 | 0.12 |
Item | V2O5 | Si | Fe | P | S | As | Na2O + K2O |
---|---|---|---|---|---|---|---|
V2O5 sample | 99.05 | <0.01 | 0.075 | 0.026 | 0.01 | <0.01 | 0.74 |
Standard sample | ≥99.00 | ≤0.08 | ≤0.08 | ≤0.03 | ≤0.08 | ≤0.01 | ≤0.8 |
Item | Precipitation by NH3·H2O | Precipitation by NH4Cl | Purification by NH4Cl |
---|---|---|---|
K | 9.9 | 10 | 2.0 |
efficiency | 99.41% | 99.12% | 99.23% |
purity | 98.35% | 98.04% | 99.05% |
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Lin, G.; Huang, J.; Zhang, Y.; Hu, P. A Sustainable Technique to Prepare High-Purity Vanadium Pentoxide via Purification with Low Ammonium Consumption. Materials 2022, 15, 1945. https://doi.org/10.3390/ma15051945
Lin G, Huang J, Zhang Y, Hu P. A Sustainable Technique to Prepare High-Purity Vanadium Pentoxide via Purification with Low Ammonium Consumption. Materials. 2022; 15(5):1945. https://doi.org/10.3390/ma15051945
Chicago/Turabian StyleLin, Guoce, Jing Huang, Yimin Zhang, and Pengcheng Hu. 2022. "A Sustainable Technique to Prepare High-Purity Vanadium Pentoxide via Purification with Low Ammonium Consumption" Materials 15, no. 5: 1945. https://doi.org/10.3390/ma15051945