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Article

Ferromagnetism and Superconductivity in CaRuO3/YBa2Cu3O7-δ Heterostructures

by
Alina Marinela Ionescu
1,*,
Ion Ivan
1,
Claudiu Locovei
1,2,
Melania Onea
1,2,
Adrian Crisan
1,
Soltan Soltan
3,4,
Gisela Schütz
4 and
Joachim Albrecht
5
1
National Institute of Materials Physics, Atomistilor 405A, 077125 Magurele, Romania
2
Faculty of Physics, University of Bucharest, Atomistilor Street 405, 077125 Magurele, Romania
3
Department of Physics, Faculty of Science, Helwan University, Cairo 11792, Egypt
4
Max Planck Institute for Intelligent Systems, Heisenbergstr. 3, D-70569 Stuttgart, Germany
5
Research Institute for Innovative Surfaces FINO, Aalen University, Beethovenstr. 1, D-73430 Aalen, Germany
*
Author to whom correspondence should be addressed.
Materials 2022, 15(7), 2345; https://doi.org/10.3390/ma15072345
Submission received: 22 February 2022 / Revised: 17 March 2022 / Accepted: 19 March 2022 / Published: 22 March 2022
(This article belongs to the Special Issue Synthesis, Design, Characterization of Unconventional Superconducting Materials)
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Abstract

The deposition of a ferromagnetic layer can affect the properties of high-temperature superconductors underneath. We investigated the influence of ferromagnetic CaRuO3 on the properties of YBa2Cu3O7-x (YBCO) superconducting thin films when the layers are either in direct contact or separated by a barrier layer of 5 nm SrTiO3. Detailed measurements of the magnetic moment of the superconductor and ferromagnet as a function of temperature and magnetic field have been performed using SQUID magnetometry. Magnetometry and relaxation measurements show that the modification of the superconducting properties of YBCO strongly depends on the interaction with the ferromagnetic layer on top. The barrier layer has a significant impact on both the supercon-ducting properties of the YBCO film and the ferromagnetic ordering of CaRuO3. The physical properties mentioned above were discussed in correlation with the materials’ structure determined by XRD analysis.

1. Introduction

Since the high-temperature superconductor YBa2Cu3O7-x (YBCO) with a critical temperature Tc of more than 90 K was discovered [1], high-temperature superconductors (HTS) were taken seriously into account for the fabrication of various devices. Some of these large-scale applications where YBCO fits very well are superconducting power cables, magnetic energy-storage devices, motors, fault current limiters, and transformers [2,3,4]. Most of the superconducting properties are significantly influenced by the amount of oxygen in YBCO [5].
For an application-ready superconductor, besides a high transition temperature, high critical currents are needed; in particular, exhibiting small dissipation at high magnetic fields. To fulfil this criterion, vortices in the material have to be strongly pinned. Many possibilities to inhibit vortex motion have been found that led to an increase of the superconducting critical current density, Jc [6]. Some of the methods developed to introduce natural and artificial pinning centers are: microstructural variations [7,8], creation of oxygen vacancies [9], the addition of secondary phases [10,11], magnetic nanoparticles, or nanolayers [12,13,14,15].
Among these methods, the interaction of the superconductor (SC) with a ferromagnet (FM) leads to very interesting results [16,17,18]. If the superconductor and the ferromagnet are in direct contact, coupling phenomena such as proximity [19,20,21,22] and inverse proximity effects [23], spin-orbit [24], or dipolar coupling [25,26] can take place. For power applications, to eliminate the unwanted proximity effects [27] and increase the Jc a thin barrier layer is introduced at the SC/FM interface [28]. On the other hand, SC/FM heterostructures are also of great interest in superconducting electronics [29,30,31,32] where the properties of the ferromagnet are of utmost importance.
CaRuO3 (CRO) is a metal exhibiting interesting properties [33], in particular when deposited as a thin film on various substrates [34,35,36], using several deposition methods [37,38]. In respect to superconducting electronic devices, Josephson junctions have been created using YBCO and non-magnetic CRO [39,40].
Many studies have been performed to fully understand the occurrence of ferromagnetism in CRO [41,42,43,44,45,46], including studies on heterostructures with CRO [47]. Tripathi et al. [36] observed that CRO thin films deposited epitaxially on SrTiO3 (STO) substrates become ferromagnetic due to tensile epitaxial strain. Ferromagnetism in CRO has also been found; for example, when doping it with Ti [48]. Ivan et al. [49] managed to deposit magnetic CRO on YBCO and studied the magnetic and structural properties of the heterostructure.
In this work, we have investigated the influence of an intermediate STO layer on heterostructures composed of YBCO and CRO thin films grown by pulsed laser deposition (PLD). Using XRD measurements and detailed measurements of the magnetic moment as a function of temperature, magnetic field, and time we analyzed the influence of CRO on the superconductor and vice versa, and the role of oxygenation on their properties. We observed that CRO has good ferromagnetic properties only if it is deposited directly on YBCO and without post oxygenation.

2. Materials and Methods

We used pulsed-laser deposition (PLD) (Surface, Hückelhoven, Germany) to epitaxially grow thin films of CRO, YBCO, and STO. In all cases, a 200 nm thick film of optimally doped YBCO was grown on single-crystalline SrTiO3 (001) substrates with a lateral size of 5 mm × 5 mm. Then, for half of the samples, a 5 nm STO buffer layer was deposited on top of the YBCO surface also by PLD. The deposition of both layers was made at 830 °C in a 0.3 mbar O2 atmosphere with a laser energy of 67 mJ, followed by annealing in 1 bar O2. In the next step, 130 nm thick CaRuO3 was deposited at 720 °C and 0.6 mbar O2. The pulse laser energy was 43 mJ and annealing was performed at 0.3 bar O2. The heterostructures were then carefully broken into halves and a half of each was furthermore annealed at 550 °C in O2 atmosphere for 15 h.
A sketch showing the preparation process is depicted in Figure 1. The results in this work were subdivided into three stages of preparation: (I) reference samples YBCO (I-a) and YBCO with 5 nm STO (I-b), (II) YBCO with CaRuO3 in direct contact (II-a), YBCO with CaRuO3 separated by STO (II-b), (III) YBCO with CaRuO3 in direct contact oxygenated (III-a), and YBCO/STO/CRO oxygenated (III-b).
The X-ray diffraction (XRD) characterization was carried out with a Bruker D8 Advance diffractometer (Karlshruhe, Germany) operated at 40 kV and 40 mA (CuKα radiation) in medium resolution parallel beam setup where reciprocal space mappings (RSMs) were recorded. Furthermore, the 2θ-ω scan was performed using a Rigaku SmartLab diffractometer (Tokyo, Japan) using monochromatized radiation Cu-Kα1 (λ = 1.5406 Å). The morphology of the samples was investigated using a Gemini 500 Carl Zeiss field emission scanning electron microscope (FESEM) (Carl Zeiss Microscopy GmbH, Oberkochen, Germany), equipped with LaB6 filament, NanoVP mode, InLens, and SE2 detectors. The FESEM images were taken using the Inlens detector, in high vacuum.
The magnetic properties of all samples were measured with SQUID magnetometry (Quantum Design, San Diego, CA, USA) using a quantum design MPMS. In all measurements, the external magnetic field µ0H was applied perpendicular to the plane of the sample. For the measurement of the superconducting transition temperature Tc, the samples were cooled in zero field (ZFC) to T = 5 K. Then, a magnetic field of µ0H = 1 mT was applied and the temperature was increased to 100 K while measuring the magnetic moment m(T). We extracted Tc at the temperature the diamagnetic signal vanishes. In addition, the critical current density Jc was determined from the magnetization data using the Bean relation [50] modified for a plate-like geometry [51]:
J c = 40 · m V · l ( 1 − l 3 L ) .
where m is the magnetic moment in emu, V—the sample volume in cm3, L is the length and l is the width of YBCO thin film in cm, and the resulting Jc is in A/cm2.
For a more detailed analysis of vortex pinning in the superconducting film, we complemented the Jc data by measurements of the thermally activated relaxation of the magnetization. This allowed a detailed description of thermally activated depinning processes. We studied the corresponding pinning energies by long-time relaxation measurements: the sample is cooled (ZFC) to different temperatures, a magnetic field of 0.2 T is applied and the decay of the magnetic moment in time m(t) is registered for a time window tw of 30 min.
The averaged normalized magnetization relaxation rate S = −Δln(|m|)/Δln(t) and implicitly the normalized vortex-creep activation energy U* = T/S can be extracted in the range where ln(|m|) vs. ln(t) is linear. This is reasonable in regions of the T-H phases diagram that are not too close to the irreversibility line (IL) and for a moderate relaxation time window, tw averaged over tw [52]. Typically, U* increases with temperature in the collective (elastic) vortex creep regime (where the vortex phase is ordered) [53] and decreases for plastic (dislocation mediated) creep (disordered vortex phase) [54].
Figure 1 shows a sketch of the sample preparation process, as well as the surface morphology images obtained by scanning electron microscopy (SEM). The thickness of the YBCO film is 200 nm, the CRO film is 130 nm, and the STO interlayer, where it appears, is 5 nm thick. A major difference compared to ref [49] is that the CRO was deposited after the samples were taken out of the PLD chamber and introduced again.

3. Results and Discussion

Figure 2a presents the m(T) curves for all samples in all three stages of preparation. Initially, YBCO (with and without STO), stage I, is shown in blue; after the deposition of CRO, the results are shown in black/grey (II) and, finally, after oxygenation (III), the measurements are shown in red curves. All measurements were performed in a small applied magnetic field of 1 mT. As expected, the reference samples (YBCO and YBCO/STO) have almost identical properties, exhibiting a Tc of about 86 K. After the deposition of CRO, we observe a drastic decrease of Tc for both samples to around 53 K. We managed to partially recover Tc of the superconducting film by a subsequent oxygenation at 550 °C for 15 h, after which Tc increased to 70 K.
For a better understanding of the properties of the superconductor, we measured the magnetic moment m below Tc to reveal the influence of the STO barrier layer and the post oxygenation on the diamagnetic response of the YBCO film. Figure 2b presents, in logarithmic scale, the temperature-dependent magnetic moment of the initial YBCO films (YBCO I-a and YBCO/STO I-b), of the samples after CRO deposition (YBCO/CRO II-a and YBCO/STO/CRO II-b) and, finally, after the post oxygenation (YBCO/CRO oxy III-a and YBCO/STO/CRO oxy III-b). The magnetic moment has been measured in the remnant state after cooling the sample in zero magnetic field to a temperature T = 5 K and applying an external magnetic field µ0Hex = 0.3 T for several seconds. Then, the external field is reduced to zero and the magnetic moment is measured while continuously heating up until Tc. The behavior of the reference samples is as expected: the high diamagnetic moment (and, implicitly, the resulting Jc) decreases from low temperatures while heating up towards Tc. The deposition of CRO leads to a significant suppression of Jc. Interestingly, after the oxygenation, even though the Tc is partially recovered, Jc at low temperatures is further decreased. A possible reason may be the occurrence of a modification in the site of apical oxygen in YBCO [55].
In the next step, we focus on the ferromagnetism in CaRuO3. As shown in ref [36], CaRuO3 can be ferromagnetic in case of a certain thickness when grown on STO. CaRuO3 can be ferromagnetic as well if it is deposited on YBCO during a one-step process (first deposition of YBCO, then deposition of CRO, without taking the sample out of the PLD chamber) [49].
Our purpose was to try to preserve the good superconducting properties of YBCO while having ferromagnetic CRO on top. For the characterization of the ferromagnetic order, we measured magnetic hysteresis curves at room temperature (300 K). During analysis, the diamagnetic contribution of YBCO and STO substrate has been subtracted (Figure 3). In the case of sample II-a (CRO on YBCO), a characteristic ferromagnetic behavior is found which qualitatively corresponds to results in the literature [49]. After the reoxygenation process (stage III), the magnetic moment of CRO strongly decreases. On the other hand, if CRO is deposited on 5 nm STO on top of YBCO, the sample shows very weak ferromagnetism which is slightly increased after the reoxygenation.
To better emphasize the ferromagnetic behavior for sample YBCO/CRO, we measured the ZFC-FC temperature dependence of the magnetization in 10 mT, above Tc until 300 K. The observed bifurcation is specific for ferromagnetic materials.
As expected, if YBCO is protected by the STO layer or not, the superconducting properties of YBCO are very similar (stage I). Then, after deposition of CRO (stage II), a significant difference appears (as seen from the shape of the m(T) curves) which implies that the STO plays an important role in the YBCO. On the other hand, the only sample with good ferromagnetic properties of CRO is the one in which CRO is deposited directly on YBCO which means that STO has a big impact on the magnetic properties of CRO. The post oxygenation, although helpful for the recovery of Tc of YBCO, is damaging the ferromagnetism of CRO. Another approach should be used to keep the good superconducting properties of YBCO while maintaining ferromagnetic CRO.
Due to the complex behavior of the critical current density and for a better understanding of the role of the decoupling layer on the pinning scenario in YBCO, we performed relaxation measurements in an applied field of 0.2 T.
After each measurement, the field is reduced to 0, the sample is heated above Tc, then cooled down to the next temperature. Subsequently, the field is applied and the measurement is started. Figure 4a depicts magnetic relaxation m(t) curves normalized to t = 100 s for all samples at 20 K which are linear in a log–log plot.
In our analysis, we excluded the early relaxation stages (t < 100 s) where the flux redistribution across the sample or the influence of flux flow at a very short time becomes important [56]. As it can be observed, in a log–log representation, the relaxation curves are almost linear and the normalized vortex-creep activation energy was determined using U* = T/S where S = −Δln(|m|)/Δln(t) (Figure 4b). It is known that the low-T S(T) maximum (in our representation the behavior of U* at temperatures under 35 K for the reference samples) is generated by the occurrence of thermo-magnetic in-stabilities (TMI) at low temperatures [56]. Then, with increasing temperature, U* increases indicating an ordered vortex phase. At higher temperatures, U* decreases, due to plastic creep. At the crossover temperature, U* can be identified with the characteristic pinning energy Uc. The U*(T) dependence was the subject of intensive studies on YBCO films with different pinning centers [57]. However, the crossover collective creep–plastic creep always appears in DC magnetization relaxation measurements in samples with random pinning. For strongly pinned samples, the thermal energy can be neglected when T is significantly below Tc. At low temperatures, J is closer to Jc because the relaxation is smaller, the effective pinning is weak and the intervortex interactions are dominant, giving rise to collective pinning. On the other hand, at high T the energy balance changes, because J relaxes faster and U* increases leading to the apparition of dislocations in the vortex system due to vortex pinning and the creep becomes plastic. Roughly, this dynamic crossover appears when the effective depth of the pinning potential well equals the vortex deformation energy [58].
As expected, the U*(T) dependence and the values for the two reference samples are very similar (Figure 4b). Then, after deposition of CRO, due to a decrease in critical temperature in the samples, U* also shows smaller values. Sample II-a, which exhibits ferromagnetism at room temperature due to CRO, has the smallest pinning energies. Then, after oxygenation, pinning energies increase and the two ‘bumps’ in U*(T) dependence are visible again for both samples. Surprisingly, in all temperature ranges, U* is higher for III-a and b samples than for II-a and b samples. At small temperatures, the differences between the heterostructures with and without STO are small and increase with temperatures.
For a deeper insight into the flux pinning properties of the superconducting film we want to distinguish between the pinning force density that is proportional to the critical current density Jc and the pinning energy U* extracted from the relaxation experiments. A more descriptive picture identifies the pinning force density with the maximum slope and the pinning energy with the depth of the pinning potential. This simplified consideration is reasonably accurate for an individual particle, namely individual vortices at low magnetic fields. This holds quite well for the results in this work.
To extract the role of the decoupling STO layer for flux pinning during three steps of preparation we consider the ratio of Jc and U* for heterostructures with and without the STO layer, respectively. Figure 5 shows the relative change of Jc and U* due to the presence of an additional decoupling STO layer for the three preparations stages I (blue), II (black), and III (red). The filled symbols refer to the pinning energy U*, the open ones describe the Jc data.
The two blue curves describing the influence of an additional STO layer on a bare YBCO film show the expected behavior. Over the whole temperature range, we find a value of about one showing that the pinning in the YBCO film is not influenced by an additional epitaxial STO film with a thickness of 5 nm. After the deposition of the CRO film, the situation changes as described by the black curves. If YBCO and CRO are electronically decoupled by 5 nm of STO, the pinning suppression is drastically reduced. Pinning remains much stronger, apparent in both Jc and U*. This result is quite obvious to explain. First, the presence of the STO layer reduces the magnetic moment in the CRO; second, there is no direct contact between the superconductor and ferromagnet. The black curves describing the effect of the separation layer exhibit values larger than 1. In addition, the observed pinning strongly increases with temperature. This is more prominent in the case of U* (filled black symbols) than in Jc (open black). This evidently shows that the description of pinning by Jc and U* is not equivalent. The more pronounced difference that occurs in U* might be explained by the suppression of superconductivity in a layer of finite thickness due to the adjacent ferromagnet. This reduces the effective length of individual vortices and, thus, the pinning energy. This does not necessarily suppress Jc in the same way, in particular when considering that also magnetic pinning provides a contribution [13].
After annealing in oxygen (stage III, red curves), the situation changes. The introduction of the STO layer leads to a decrease in pinning of about 30% leading to a ratio of about 0.7. The suppression of current transport in the YBCO film by the STO layer proves that the direct contact of both films after oxygenation has beneficial consequences for Jc and U*. The post-oxygenation has recovered the oxygen stoichiometry of YBCO close to the interface by oxygen diffusion through the STO at least partially [59]. The superconducting phase is in direct contact with the ferromagnetically ordered CRO. In this situation, magnetic vortex pinning occurs that leads to an increase of Jc and U*, respectively. A separating STO layer reduces this effect, the red curves show values smaller than 1. In the case of U*, the reduction sets in above about T = 25 K. This shows that thermally activated depinning of vortices is not the dominant process that limits the critical current density at low temperatures. This is consistent with the established descript of temperature-dependent critical currents in YBCO thin films and multilayers in small magnetic fields [60,61].
For a better understanding of the interaction between SC and FM, the final step of our study was the correlation of the physical properties of the heterostructures with the materials´ structure by XRD analysis.
The XRD data in the 2θ-ω scan were recorded after sample alignment for miscut cor-rection of the single crystal substrate, and the results are shown in Figure 6a are the lines corresponding to multiple reflections on the (001) planes of the cubic STO substrate (ICDD # 00-035-0734), of the orthorhombic YBCO structure (ICDD # 01-086-0477), and of the orthorhombic CRO (in pseudocubic indexing, CROpc) (ICDD #04-006-6459) are detected.
To show the epitaxial relationships between YBCO and CRO layers with respect to the STO substrate and to determine the in-plane structural parameters, the RSM measurements were acquired on tilted diffraction planes. The data were collected near the -103 and -013 nodes of STO to determine both a and b in-plane lattice constants of the orthorhombic YBCO. The lattice parameters calculated from RSMs are presented in Table 1. Firstly, sample I-a presents in-plane compressive strain and out-of-plane tensile strain, which is opposite to the values observed for sample I-b even though both have the highest Tc (see Figure 2b). In this reasoning, the differences observed in structural parameters of samples I-a and I-b do not have a high impact on the stoichiometry of the YBCO layer. After the deposition of the CRO layer, for all samples was observed the same value of compressive strain for the b lattice constant of the YBCO layer and a tensile strain in the case of a and c lattice constants. Moreover, the Tc of YBCO is smaller in these samples regardless of the presence of the STO interlayer, which may imply a modification in stoichiometry leading to an under-doped YBCO [62,63]. Differences observed in the strain of the YBCO layer and temperature-dependent magnetic moment curves from Figure 2b of samples II-a, II-b, III-a, and III-b, respectively, may be partly caused by a change in the site of apical oxygen [55]. The CRO layers show an out-of-plane compressive strain and in-plane tensile strain, respectively. Only for sample II-a, the CRO layer has an in-plane compressive strain for the a lattice constant, similar to the situation discussed in [49]. Thus, according to other studies [49], to achieve the ferromagnetism in the epitaxial CRO layer, an induced strain in the CROpc pseudo-cubic structure is required, but a tensile strain in both in-plane directions decreases drastically the saturation magnetization as shown in Figure 3.
However, the interaction between YBCO and CRO is complex and we took into account only some effects which appear at the interface. Probably there are also other effects such as spin diffusion, evidenced in ref [16], which will be further studied.

4. Conclusions

In summary, we investigated the properties of heterostructures of CaRuO3 (CRO) and YBa2Cu3O7-x (YBCO) thin films. It has been of particular interest if the layers are in direct contact or separated by a barrier layer of SrTiO3. The influence of CRO on YBCO and vice versa has been studied by SQUID magnetometry. Detailed measurements of the magnetic moment of the heterostructures as a function of temperature, magnetic field, and relaxation time have been performed. It has been found that a large ferromagnetic signal is found in the case of direct deposition of CRO on YBCO, while in the case of separated layers, the magnetization is reduced. Furthermore, we observed a strong suppression of superconductivity after the direct deposition of the CRO film. A subsequent oxidation process shows that the superconducting properties are partially recovered, most likely due to an efficient oxygen diffusion through the STO barrier. The materials´ structure has been investigated by XRD analysis identifying mechanical strain to be the origin for the formation of a ferromagnetic state in CRO. The highest magnetization has been obtained when the thin layer CRO layer was deposited directly on YBCO, without further oxygenation.

Author Contributions

A.M.I. prepared the samples, performed the magnetic measurements, analyzed the data and prepared the manuscript; I.I. and A.C. developed the concept and prepared the manuscript; C.L. XRD measurements; M.O. SEM analysis; S.S. and G.S. provided conceptual advice; J.A. interpreted the data and prepared the manuscript. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by Romanian Ministry of Research and Innovation through POC (European Regional Development Fund, Operational Fund Competitiveness) Project P-37_697 no 28/01.09.2016 REBMAT, Core Programme PN19-030101, COST Action 19108 Hi-SCALE and COST Action 16218 Nanocohybri. The fee for open access publication was supported from the project 35PFE/2021, funded by the Romanian Ministry of Research, Innovation and Digitization.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The relevant data for the discussion are completely supplied in the results section. Raw data is available upon request.

Acknowledgments

The authors are grateful to G. Cristiani (MPI Stuttgart) for his contribution to the sample fabrication and to I. Pasuk (NIMP Magurele) for fruitful discussion about XRD results.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Wu, M.K.; Ashburn, J.R.; Torng, C.J.; Hor, P.H.; Meng, R.L.; Gao, L.; Huang, Z.J.; Wang, Y.Q.; Chu, C.W. Superconductivity at 93 K in a new mixed-phase Yb-Ba-Cu-O compound system at ambient pressure. Phys. Rev. Lett. 1987, 58, 908–910. [Google Scholar] [CrossRef] [PubMed]
  2. Foltyn, S.R.; Civale, L.; Macmanus-Driscoll, J.L.; Jia, Q.X.; Maiorov, B.; Wang, H.; Maley, M. Materials science challenges for high-temperature superconducting wire. Nat. Mater. 2007, 6, 631–642. [Google Scholar] [CrossRef]
  3. Larbalestier, D.; Gurevich, A.; Feldmann, D.M.; Polyanskii, A. High-Tc superconducting materials for electric power applications. Nature 2001, 414, 368–377. [Google Scholar] [CrossRef] [PubMed]
  4. Seidel, P. Applied Superconductivity: Handbook on Devices and Applications; Seidel, P., Ed.; Wiley: Hoboken, NJ, USA, 2015. [Google Scholar]
  5. Conder, K. Oxygen diffusion in the superconductors of the YBaCuO family: Isotope exchange measurements and models. Mater. Sci. Eng. R Rep. 2001, 32, 41–102. [Google Scholar] [CrossRef]
  6. Jha, A.K.; Matsumoto, K. Superconductive REBCO thin films and their nanocomposites: The role of rare-earth oxides in promoting sustainable energy. Front. Phys. 2019, 7, 82. [Google Scholar] [CrossRef]
  7. Yan, H.; Abdelhadi, M.M.; Jung, J.A.; Willemsen, B.A.; Kihlstrom, K.E. Exponential dependence of the vortex pinning potential on current density in high-Tc superconductors. Phys. Rev. B 2005, 72, 064522. [Google Scholar] [CrossRef]
  8. Jooss, C.; Warthmann, R.; Kronmüller, H.; Haage, T.; Habermeier, H.U.; Zegenhagen, J. Vortex pinning due to strong quasiparticle scattering at antiphase boundaries in YBa2Cu3O7-δ. Phys. Rev. Lett. 1999, 82, 632–635. [Google Scholar] [CrossRef]
  9. Theuss, H.; Kronmüller, H. The influence of a point defect structure on the magnetic properties of YBa2Cu3O7-δ polycrystals. Phys. C 1991, 177, 253–261. [Google Scholar] [CrossRef]
  10. Opherden, L.; Sieger, M.; Pahlke, P.; Hühne, R.; Schultz, L.; Meled, A.; Van Tendeloo, G.; Nast, R.; Holzapfel, B.; Marco, B.; et al. Large pinning forces and matching effects in YBa2Cu3O7-δ thin films with Ba2Y(Nb/Ta)O6 nano-precipitates. Sci. Rep. 2016, 6, 21188. [Google Scholar] [CrossRef]
  11. Crisan, A.; Dang, V.S.; Mikheenko, P.; Ionescu, A.M.; Ivan, I.; Miu, L. Synergetic pinning centres in BaZrO3-doped YBa2Cu3O7-x films induced by SrTiO3 nano-layers. Supercond. Sci. Technol. 2017, 30, 045012. [Google Scholar] [CrossRef]
  12. Rouco, V.; Córdoba, R.; De Teresa, J.M.; Rodríguez, L.A.; Navau, C.; Del-Valle, N.; Via, G.; Sánchez, A.; Monton, C.; Kronast, F.; et al. Competition between Superconductor—Ferromagnetic stray magnetic fields in YBa2Cu3O7-x films pierced with Co nano-rods. Sci. Rep. 2017, 7, 5663. [Google Scholar] [CrossRef] [PubMed]
  13. Stahl, C.; Walker, P.; Treiber, S.; Christiani, G.; Schütz, G.; Albrecht, J. Using magnetic coupling in bilayers of superconducting YBCO and soft-magnetic CoFeB to map supercurrent flow. EPL 2014, 106, 27002. [Google Scholar] [CrossRef]
  14. De Andrés Prada, R.; Gaina, R.; Biškup, N.; Varela, M.; Stahn, J.; Bernhard, C. Controlling the strength of ferromagnetic order in YBa2Cu3O7/La2/3Ca1/3MnO3 multilayers. Phys. Rev. B 2019, 100, 115129. [Google Scholar] [CrossRef]
  15. Huang, S.W.; Wray, L.A.; Jeng, H.T.; Tra, V.T.; Lee, J.M.; Langner, M.C.; Chen, J.M.; Roy, S.; Chu, Y.H.; Schoenlein, R.W.; et al. Selective interlayer ferromagnetic coupling between the Cu spins in YBa2Cu3O7-x grown on top of La0.7Ca0.3MnO3. Sci. Rep. 2015, 5, 16690. [Google Scholar] [CrossRef]
  16. Soltan, S.; Albrecht, J.; Habermeier, H.U. Ferromagnetic/superconducting bilayer structure: A model system for spin diffusion length estimation. Phys. Rev. B 2004, 70, 144517. [Google Scholar] [CrossRef]
  17. Samal, D.; Anil Kumar, P.S. Evidence for decoupled two-dimensional vortex behavior of YBa2Cu3O7-δ in La0.7Sr0.3MnO3/YBa2Cu3O7-δ/La0.7Sr0.3MnO3 trilayer. J. Appl. Phys. 2010, 108, 123909. [Google Scholar] [CrossRef]
  18. Sander, A.; Orfila, G.; Sanchez-Manzano, D.; Reyren, N.; Mawass, M.A.; Gallego, F.; Collin, S.; Bouzehouane, K.; Höflich, K.; Kronast, F.; et al. Superconducting imprint of magnetic textures in ferromagnets with perpendicular magnetic anisotropy. Sci. Rep. 2021, 11, 20788. [Google Scholar] [CrossRef]
  19. Buzdin, A.I.; Ryazanov, V.V. Proximity effect in superconductor-ferromagnet heterostructures. Comptes Rendus Phys. 2006, 7, 107–115. [Google Scholar] [CrossRef]
  20. Paull, O.H.C.; Pan, A.V.; Causer, G.L.; Fedoseev, S.A.; Jones, A.; Liu, X.; Rosenfeld, A.; Klose, F. Field dependence of the ferromagnetic/superconducting proximity effect in a YBCO/STO/LCMO multilayer. Nanoscale 2018, 10, 18995–19003. [Google Scholar] [CrossRef] [PubMed]
  21. Satapathy, D.K.; Uribe-Laverde, M.A.; Marozau, I.; Malik, V.K.; Das, S.; Wagner, T.; Marcelot, C.; Stahn, J.; Brück, S.; Rühm, A.; et al. Magnetic Proximity Effect in YBa2Cu3O7/La2/3Ca1/3MnO3 and YBa2Cu3O7/LaMnO3+δ Superlattices. Phys. Rev. Lett. 2012, 108, 197201. [Google Scholar] [CrossRef]
  22. Frano, A.; Blanco-Canosa, S.; Schierle, E.; Lu, Y.; Wu, M.; Bluschke, M.; Minola, M.; Christiani, G.; Habermeier, H.U.; Logvenov, G.; et al. Long-range charge-density-wave proximity effect at cuprate/manganate interfaces. Nat. Mater. 2016, 15, 831–834. [Google Scholar] [CrossRef]
  23. Kalcheim, Y.; Millo, O.; Di Bernardo, A.; Pal, A.; Robinson, J.W.A. Inverse proximity effect at superconductor-ferromagnet interfaces: Evidence for induced triplet pairing in the superconductor. Phys. Rev. B—Condens. Matter Mater. Phys. 2015, 92, 060504(R). [Google Scholar] [CrossRef]
  24. Banerjee, N.; Ouassou, J.A.; Zhu, Y.; Stelmashenko, N.A.; Linder, J.; Blamire, M.G. Controlling the superconducting transition by spin-orbit coupling. Phys. Rev. B 2018, 97, 184521. [Google Scholar] [CrossRef]
  25. Brisbois, J.; Motta, M.; Avila, J.I.; Shaw, G.; Devillers, T.; Dempsey, N.M.; Veerapandian, S.K.P.; Colson, P.; Vanderheyden, B.; Vanderbemden, P.; et al. Imprinting superconducting vortex footsteps in a magnetic layer. Sci. Rep. 2016, 6, 27159. [Google Scholar] [CrossRef] [PubMed]
  26. Aladyshkin, A.Y.; Silhanek, A.V.; Gillijns, W.; Moshchalkov, V.V. Nucleation of superconductivity and vortex matter in superconductor- ferromagnet hybrids. Supercond. Sci. Technol. 2009, 22, 053001. [Google Scholar] [CrossRef]
  27. Chien, T.Y.; Kourkoutis, L.F.; Chakhalian, J.; Gray, B.; Kareev, M.; Guisinger, N.P.; Muller, D.A.; Freeland, J.W. Visualizing short-range charge transfer at the interfaces between ferromagnetic and superconducting oxides. Nat. Commun. 2013, 4, 1–7. [Google Scholar] [CrossRef] [PubMed]
  28. Albrecht, J.; Soltan, S.; Habermeier, H.U. Magnetic pinning of flux lines in heterostructures of cuprates and manganites. Phys. Rev. B 2005, 72, 092502. [Google Scholar] [CrossRef]
  29. Di Bernardo, A.; Komori, S.; Livanas, G.; Divitini, G.; Gentile, P.; Cuoco, M.; Robinson, J.W.A. Nodal superconducting exchange coupling. Nat. Mater. 2019, 18, 1194–1200. [Google Scholar] [CrossRef]
  30. Soltan, S.; Albrecht, J.; Goering, E.; Schütz, G.; Mustafa, L.; Keimer, B.; Habermeier, H.U. Preparation of a ferromagnetic barrier in YBa2Cu3O7-δ thinner than the coherence length. J. Appl. Phys. 2015, 118, 223902. [Google Scholar] [CrossRef]
  31. Ionescu, A.M.; Simmendinger, J.; Bihler, M.; Miksch, C.; Fischer, P.; Soltan, S.; Schütz, G.; Albrecht, J. Soft-magnetic coatings as possible sensors for magnetic imaging of superconductors. Supercond. Sci. Technol. 2020, 33, 015002. [Google Scholar] [CrossRef]
  32. Alidoust, M.; Halterman, K. Half-metallic superconducting triplet spin multivalves. Phys. Rev. B 2018, 97, 064517. [Google Scholar] [CrossRef]
  33. Schultz, M.; Klein, L.; Reiner, J.W.; Beasley, M.R. Low-temperature magnetoresistance in untwinned CaRuO3 films. Phys. B Condens. Matter 2006, 378–380, 490–491. [Google Scholar] [CrossRef]
  34. Tian, H.Y.; Wang, J.; Wang, Y.; Qi, J.Q.; Wong, K.H.; Chan, H.L.W.; Choy, C.L. Highly c-axis oriented CaRuO3 thin films on LaAlO3 buffered Si(100) substrates by pulsed laser deposition. Phys. Status Solidi Appl. Res. 2004, 201, 101–104. [Google Scholar] [CrossRef]
  35. Ito, A.; Matsumoto, H.; Goto, T. Microstructure and Electrical Conductivity of Epitaxial CaRuO3 Thin Films Prepared on (001), (110) and (111) SrTiO3 Substrates by Laser Ablation. J. Ceram. Soc. Jpn. 2007, 115, 683–687. [Google Scholar] [CrossRef][Green Version]
  36. Tripathi, S.; Rana, R.; Kumar, S.; Pandey, P.; Singh, R.S.; Rana, D.S. Ferromagnetic CaRuO3. Sci. Rep. 2014, 4, 3877. [Google Scholar] [CrossRef]
  37. Nair, H.P.; Liu, Y.; Ruf, J.P.; Schreiber, N.J.; Shang, S.L.; Baek, D.J.; Goodge, B.H.; Kourkoutis, L.F.; Liu, Z.K.; Shen, K.M.; et al. Synthesis science of SrRuO3 and CaRuO3 epitaxial films with high residual resistivity ratios. APL Mater. 2018, 6, 046101. [Google Scholar] [CrossRef]
  38. Geiger, D.; Scheffler, M.; Dressel, M.; Schneider, M.; Gegenwart, P. Broadband microwave study of SrRuO3 and CaRuO3 thin films. J. Phys. Conf. Ser. 2012, 391, 012091. [Google Scholar] [CrossRef]
  39. Myers, K.E.; Char, K.; Colclough, M.S.; Geballe, T.H. Noise characteristics of YBa2Cu3O7-δ/CaRuO3/YBa2Cu3O7-δ Josephson junctions. Appl. Phys. Lett. 1994, 64, 788. [Google Scholar] [CrossRef]
  40. Lee, S.G.; Park, K.; Park, Y.K.; Park, J.C. High Tc superconductor-normal-superconductor step-edge junction dc SQUIDs with CaRuO3 as the normal metal. Appl. Phys. Lett. 1994, 64, 2028. [Google Scholar] [CrossRef]
  41. Shirako, Y.; Satsukawa, H.; Kojitani, H.; Katsumata, T.; Yoshida, M.; Inaguma, Y.; Hiraki, K.; Takahashi, T.; Yamaura, K.; Takayama-Muromachi, E.; et al. Magnetic properties of high-pressure phase of CaRuO3 with post-perovskite structure. J. Phys. Conf. Ser. 2010, 215, 012038. [Google Scholar] [CrossRef]
  42. Shirako, Y.; Satsukawa, H.; Wang, X.X.; Li, J.J.; Guo, Y.F.; Arai, M.; Yamaura, K.; Yoshida, M.; Kojitani, H.; Katsumata, T.; et al. Integer spin-chain antiferromagnetism of the 4d oxide CaRuO3 with post-perovskite structure. Phys. Rev. B 2011, 83, 174411. [Google Scholar] [CrossRef]
  43. Shen, S.; Li, Z.; Tian, Z.; Luo, W.; Okamoto, S.; Yu, P. Emergent Ferromagnetism with Fermi-Liquid Behavior in Proton Intercalated CaRuO3. Phys. Rev. X 2021, 11, 021018. [Google Scholar] [CrossRef]
  44. Bradarić, I.M.; Matić, V.M.; Savić, I.; Rakočević, Z.; Popović, M.; Destraz, D.; Keller, H. Anomalous magnetic properties of CaRuO3 probed by AC and DC magnetic measurements and by low Ti impurity doping. Phys. Rev. B 2018, 98, 134436. [Google Scholar] [CrossRef]
  45. Longo, J.M.; Raccah, P.M.; Goodenough, J.B. Magnetic properties of SrRuO3 and CaRuO3. J. Appl. Phys. 1968, 39, 1327. [Google Scholar] [CrossRef]
  46. Chen, Y.B.; Zhou, J.; Wu, F.X.; Ji, W.J.; Zhang, S.T.; Chen, Y.F.; Zhu, Y.Y. Microstructure and ferromagnetic property in CaRuO3 thin films with pseudoheterostructure. Appl. Phys. Lett. 2010, 96, 182502. [Google Scholar] [CrossRef]
  47. Chen, P.F.; Chen, B.B.; Tan, X.L.; Xu, H.R.; Xuan, X.F.; Guo, Z.; Jin, F.; Wu, W.B. High-Tc ferromagnetic order in CaRuO3/La2/3Ca1/3MnO3 superlattices. Appl. Phys. Lett. 2013, 103, 262402. [Google Scholar] [CrossRef]
  48. He, T.; Cava, R.J. Disorder-induced ferromagnetism in CaRuO3. Phys. Rev. B—Condens. Matter Mater. Phys. 2001, 63, 172403. [Google Scholar] [CrossRef]
  49. Ivan, I.; Pasuk, I.; Crisan, A.; Sandu, V.; Onea, M.; Leca, A.; Cosar, C.; Burdusel, M. New superconductor/ferromagnet heterostructure formed by YBa2Cu3O7-x and CaRuO3. Supercond. Sci. Technol. 2021, 34, 115009. [Google Scholar] [CrossRef]
  50. Bean, C.P. Magnetization of hard superconductors. Phys. Rev. Lett. 1962, 8, 250–253. [Google Scholar] [CrossRef]
  51. Gyorgy, E.M.; Van Dover, R.B.; Jackson, K.A.; Schneemeyer, L.F.; Waszczak, J.V. Anisotropic critical currents in Ba2YCuO7 analyzed using an extended Bean model. Appl. Phys. Lett. 1989, 55, 283–285. [Google Scholar] [CrossRef]
  52. Yeshurun, Y.; Malozemoff, A.P.; Shaulov, A. Magnetic relaxation in high-temperature superconductors. Rev. Mod. Phys. 1996, 68, 911–949. [Google Scholar] [CrossRef]
  53. Feigelman, M.V.; Geshkenbein, V.B.; Larkin, A.I.; Vinokur, V.M. Theory of collective flux creep. Phys. Rev. Lett. 1989, 63, 2303–2306. [Google Scholar] [CrossRef] [PubMed]
  54. Abulafia, Y.; Shaulov, A.; Wolfus, Y.; Prozorov, R.; Burlachkov, L.; Yeshurun, Y.; Majer, D.; Zeldov, E.; Wühl, H.; Geshkenbein, V.B.; et al. Plastic vortex creep in YBa2Cu3O7-x crystals. Phys. Rev. Lett. 1996, 77, 1596–1599. [Google Scholar] [CrossRef] [PubMed]
  55. Ito, W.; Mahajan, S.; Yoshida, Y.; Morishita, T.; Kumagai, M.; Yabuta, K. Influence of Crystal Strain on Superconductivity of a-Axis Oriented YBa2Cu3Ox Films. Jpn. J. Appl. Phys. 1994, 33, 5701. [Google Scholar] [CrossRef]
  56. Miu, L.; Mele, P.; Crisan, A.; Ionescu, A.; Miu, D. Evolution of vortex dynamics in YBa2Cu3O7 films with nanorods by adding nanoparticles. Phys. C Supercond. Appl. 2014, 500, 40–43. [Google Scholar] [CrossRef]
  57. Kuncser, V.; Miu, L. Size Effects in Nanostructures; Springer: Berlin/Heidelberg, Germany, 2014; ISBN 9783662444788. [Google Scholar]
  58. Blatter, G.; Feigel’Man, M.V.; Geshkenbein, V.B.; Larkin, A.I.; Vinokur, V.M. Vortices in high-temperature superconductors. Rev. Mod. Phys. 1994, 66, 1125–1388. [Google Scholar] [CrossRef]
  59. Ionescu, A.M.; Bihler, M.; Simmendinger, J.; Miksch, C.; Fischer, P.; Cristiani, G.; Rabinovich, K.S.; Schütz, G.; Albrecht, J. Transient increase of Tc and Jc in superconducting/metallic heterostructures. Mater. Chem. Phys. 2021, 263, 124390. [Google Scholar] [CrossRef]
  60. Albrecht, J.; Djupmyr, M.; Brück, S. Universal temperature scaling of flux line pinning in high-temperature superconducting thin films. J. Phys. Condens. Matter 2007, 19, 216211. [Google Scholar] [CrossRef]
  61. Djupmyr, M.; Soltan, S.; Habermeier, H.U.; Albrecht, J. Temperature-dependent critical currents in superconducting YBa2Cu3O7-δ and ferromagnetic La2/3Ca1/3MnO3 hybrid structures. Phys. Rev. B—Condens. Matter Mater. Phys. 2009, 80, 184507. [Google Scholar] [CrossRef]
  62. Stangl, A.; Palau, A.; Deutscher, G.; Obradors, X.; Puig, T. Ultra-high critical current densities of superconducting YBa2Cu3O7-δ thin films in the overdoped state. Sci. Rep. 2021, 11, 8176. [Google Scholar] [CrossRef]
  63. Prajapat, C.L.; Singh, S.; Bhattacharya, D.; Ravikumar, G.; Basu, S.; Mattauch, S.; Zheng, J.G.; Aoki, T.; Paul, A. Proximity effects across oxide-interfaces of superconductor-insulator-ferromagnet hybrid heterostructure. Sci. Rep. 2018, 8, 3732. [Google Scholar] [CrossRef] [PubMed]
Materials 15 02345 g001
Figure 1. The three steps process together with the related FESEM images of the surface of each film: I: YBCO or YBCO/STO deposition on STO, II: deposition of CRO on the two samples, III: post oxygenation of the samples at T = 550 °C for 15 h.
Figure 1. The three steps process together with the related FESEM images of the surface of each film: I: YBCO or YBCO/STO deposition on STO, II: deposition of CRO on the two samples, III: post oxygenation of the samples at T = 550 °C for 15 h.
Materials 15 02345 g001
Materials 15 02345 g002
Figure 2. (a) m(T) in an applied filed of μ0H = 1 mT under ZFC conditions; (b) temperature-dependent critical current density Jc(T) in the remnant state of reference samples (blue, open circles—I-a, light blue, closed circles—II-a), and the heterostructures (black, open squares—II-a; gray, closed squares- II-b, orange, open triangles III-a, and red, closed triangles III-b).
Figure 2. (a) m(T) in an applied filed of μ0H = 1 mT under ZFC conditions; (b) temperature-dependent critical current density Jc(T) in the remnant state of reference samples (blue, open circles—I-a, light blue, closed circles—II-a), and the heterostructures (black, open squares—II-a; gray, closed squares- II-b, orange, open triangles III-a, and red, closed triangles III-b).
Materials 15 02345 g002
Materials 15 02345 g003
Figure 3. Main panel: Hysteresis loops of all the studied samples measured at 300 K. Inset: M(T) ZFC-FC above Tc in an applied field of 10 mT for sample II-a.
Figure 3. Main panel: Hysteresis loops of all the studied samples measured at 300 K. Inset: M(T) ZFC-FC above Tc in an applied field of 10 mT for sample II-a.
Materials 15 02345 g003
Materials 15 02345 g004
Figure 4. (a) Magnetic relaxation m(t) curves normalized to t = 100 s in a log–log plot for all samples at 20 K in an applied magnetic field of μ0H = 0.2 T. The normalized vortex-creep activation energy U* was extracted and represented in panel (b).
Figure 4. (a) Magnetic relaxation m(t) curves normalized to t = 100 s in a log–log plot for all samples at 20 K in an applied magnetic field of μ0H = 0.2 T. The normalized vortex-creep activation energy U* was extracted and represented in panel (b).
Materials 15 02345 g004
Materials 15 02345 g005
Figure 5. Ratio of Jc with and without STO decoupling layer for each step (Jc(I-b)/Jc (I-a), Jc (II-b)/Jc (II-a) and Jc (III-b)/Jc (III-a)), open symbols, and ratio of the corresponding pinning energy U*, filled symbols.
Figure 5. Ratio of Jc with and without STO decoupling layer for each step (Jc(I-b)/Jc (I-a), Jc (II-b)/Jc (II-a) and Jc (III-b)/Jc (III-a)), open symbols, and ratio of the corresponding pinning energy U*, filled symbols.
Materials 15 02345 g005
Materials 15 02345 g006
Figure 6. XRD characterization in: (a) 2θ-ω scan were the lines corresponding to multiple reflections on the (001) planes of the cubic STO substrate, of the orthorhombic YBCO structure, and of the orthorhombic CRO (in pseudocubic indexing, CROpc) are detected; (b) RSMs around the -103 and -013 nodes of STO substrate for all samples.
Figure 6. XRD characterization in: (a) 2θ-ω scan were the lines corresponding to multiple reflections on the (001) planes of the cubic STO substrate, of the orthorhombic YBCO structure, and of the orthorhombic CRO (in pseudocubic indexing, CROpc) are detected; (b) RSMs around the -103 and -013 nodes of STO substrate for all samples.
Materials 15 02345 g006
Table 1. Lattice constants and strain calculated from RSMs.
Table 1. Lattice constants and strain calculated from RSMs.
YBCO-Layer
Samplea (Å)
Strain		b (Å)
Strain		c (Å)
Strain
YBCO
Bulk
a = 3.817 Å
b = 3.883 Å
c = 11.682 Å		I-a3.793
−0.63%		3.834
−1.26%		11.69
0.07%
I-b3.845
0.74%		3.905
0.57%		11.657
−0.21%
II-a3.834
0.45%		3.88
−0.08%		11.73
0.41%
II-b3.857
1.04%		3.88
−0.08%		11.705
0.2%
III-a3.88
1.64%		3.88
−0.08%		11.697
0.13%
III-b3.861
1.14%		3.88
−0.08%		11.69
0.07%
CRO-Layer
Samplea (Å)
Strain		b (Å)
Strain		c (Å)
Strain
CROpc
Bulk pc
a = 3.840 Å		II-a3.826
−0.35%		3.883
1.13%		3.818
−0.57%
II-b3.861
0.53%		3.887
1.24%		3.813
−0.7%
III-a3.88
1.03%		3.876
0.93%		3.813
−0.7%
III-b3.864
0.63%		3.887
1.24%		3.812
−0.73%
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Ionescu, A.M.; Ivan, I.; Locovei, C.; Onea, M.; Crisan, A.; Soltan, S.; Schütz, G.; Albrecht, J. Ferromagnetism and Superconductivity in CaRuO3/YBa2Cu3O7-δ Heterostructures. Materials 2022, 15, 2345. https://doi.org/10.3390/ma15072345

AMA Style

Ionescu AM, Ivan I, Locovei C, Onea M, Crisan A, Soltan S, Schütz G, Albrecht J. Ferromagnetism and Superconductivity in CaRuO3/YBa2Cu3O7-δ Heterostructures. Materials. 2022; 15(7):2345. https://doi.org/10.3390/ma15072345

Chicago/Turabian Style

Ionescu, Alina Marinela, Ion Ivan, Claudiu Locovei, Melania Onea, Adrian Crisan, Soltan Soltan, Gisela Schütz, and Joachim Albrecht. 2022. "Ferromagnetism and Superconductivity in CaRuO3/YBa2Cu3O7-δ Heterostructures" Materials 15, no. 7: 2345. https://doi.org/10.3390/ma15072345

APA Style

Ionescu, A. M., Ivan, I., Locovei, C., Onea, M., Crisan, A., Soltan, S., Schütz, G., & Albrecht, J. (2022). Ferromagnetism and Superconductivity in CaRuO3/YBa2Cu3O7-δ Heterostructures. Materials, 15(7), 2345. https://doi.org/10.3390/ma15072345

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