Design and Preparation of Imidazole Ionic Liquid-Based Magnetic Polymers and Its Adsorption on Sunset Yellow Dye
Abstract
:1. Introduction
2. Materials and Method
2.1. Materials and Characteristics
2.2. Preparation of Magnetic Polymers
2.2.1. Surface Modification of γ-Fe2O3
2.2.2. Preparation of γ-Fe2O3@GMA
2.2.3. Preparation of γ-Fe2O3@GMA@IM
2.3. Batch Adsorption Studies
2.3.1. Contrast Experiment
2.3.2. Effect of pH
2.3.3. Adsorption Kinetics
2.3.4. Adsorption Isotherm
2.3.5. Regeneration Experiment
3. Results and Discussion
3.1. Description
3.2. Comparative Experimental Analysis
3.3. The Influence of pH
3.4. Adsorption Kinetics
3.5. Adsorption Isotherm
3.6. Repeatability
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Parameters | γ-Fe2O3@GMA@IM |
---|---|
Matrix structure | Acrylic |
Water content (%) | 55–60% |
Diameter (μm) | 50 |
Average pore size (nm) | 3.421 |
BET specific surface area (m2/g) | 14.703 |
Total pore volume (cm3/g) | 0.042 |
Adsorbate | Pseudo-First-Order Model | Pseudo-Second-Order Model | ||||
---|---|---|---|---|---|---|
k1 | qe | R12 | k2 | qe | R22 | |
FCF | 0.1966 | 190.8 | 0.988 | 0.00215 | 196.7 | 0.996 |
Adsorbate | T (°C) | Langmuir Model | Freundlich Model | ||||
---|---|---|---|---|---|---|---|
KL | Qmax | R2 | n | KF | R2 | ||
FCF | 25 °C | 0.661 | 369.9 | 0.809 | 6.27 | 162.45 | 0.971 |
35 °C | 1.146 | 376.4 | 0.830 | 6.76 | 178.23 | 0.960 | |
45 °C | 3.257 | 378.6 | 0.783 | 7.52 | 197.20 | 0.934 |
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Liu, Y.; Shi, Y.; Cui, Y.; Zhao, F.; Chen, M. Design and Preparation of Imidazole Ionic Liquid-Based Magnetic Polymers and Its Adsorption on Sunset Yellow Dye. Materials 2022, 15, 2628. https://doi.org/10.3390/ma15072628
Liu Y, Shi Y, Cui Y, Zhao F, Chen M. Design and Preparation of Imidazole Ionic Liquid-Based Magnetic Polymers and Its Adsorption on Sunset Yellow Dye. Materials. 2022; 15(7):2628. https://doi.org/10.3390/ma15072628
Chicago/Turabian StyleLiu, Yafei, Yiyu Shi, Yan Cui, Fen Zhao, and Mindong Chen. 2022. "Design and Preparation of Imidazole Ionic Liquid-Based Magnetic Polymers and Its Adsorption on Sunset Yellow Dye" Materials 15, no. 7: 2628. https://doi.org/10.3390/ma15072628