An Insight into the Defects-Driven Plasticity in Ductile Cast Irons
Abstract
:1. Introduction
2. Experimental Section
Materials and Microstructure Characterization
- prismatic heavy section casting GJS400_P—two tensile specimens called C_1 and C_2 were machined off from the core of the block; two additional specimens, named S_1 and S_2, were taken from close to the external surface of the block, so materials from different cooling conditions could be tested;
- cylindrical heavy section casting GJS400_Ce—10tensile specimens were machined off from a 25 mm thick slice at about the 200 mm height of the cylindrical block, with codes ranging from Nr 11 to Nr 20;
3. Results
3.1. Microstructure
3.2. Tensile Properties
3.3. Fractography
3.4. Micro-Computer Tomography (μCT)
4. Discussion
4.1. Correlation between Tensile Behavior and Microstructure
4.2. Defects-Driven Plasticity (DDP)
4.3. Strain Hardening Considerations and a New Material Quality Index
- in sound materials, σP is higher than the saturation stresses σV of the tensile flow curves, and, as a consequence, the pivotal strain hardening rate ΘP is negative (non-real), as indicated in Figure 24b;
- in defective materials, the pivotal stress σP is between the mean YS and the saturation stresses σV, so that the strain hardening rate ΘP is positive (real), as shown in Figure 23a,b;
- as the material defectiveness increases, the mean yield strength (YS) and pivot stress (σP) become closer, causing the ratio of σP/YS to approach unity in very defective castings;
- with improving casting integrity, the ratio σP/YS increases.
5. Conclusions
- The lowest positions of the Voce parameters in the linear dataset correspond to the least defective microstructure, having also the longest elongations to rupture and the highest UTS;
- The highest positions of the Voce parameters in the linear dataset correspond to the most defective microstructure, also displaying the shortest elongations to rupture and the smallest UTS.
- 3.
- The linearity of the Voce parameters in MAD translates into the existence of a pivotal point belonging to all the experimental Voce differential curves, namely, (σP;ΘP);
- 4.
- In sound materials, σP is higher than the saturation stresses σV of the tensile flow curves, and, as a consequence, the pivotal strain hardening rate ΘP is negative (non-real);
- 5.
- In defective materials, the pivotal stress σP is between the mean YS and the saturation stresses σV, so that the strain hardening rate ΘP is positive (real);
- 6.
- As the material defectiveness increases, the mean yield strength (YS) and pivot stress (σP) become closer, causing the ratio of σP/YS to approach unity in defective castings, while with improving casting integrity, the ratio σP/YS increases well above the unity.
Author Contributions
Funding
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Code | C | Si | Mn | P | S | Mg | Cr | Ce | CEq * |
---|---|---|---|---|---|---|---|---|---|
GJS400_P | 3.60 | 2.29 | 0.08 | 0.039 | 0.011 | 0.053 | 0.005 | - | 4.38 |
GJS400_Ce | 3.75 | 2.32 | 0.16 | - | 0.009 | 0.046 | 0.040 | 0.006 | 4.53 |
GJS400_Y | 3.63 | 2.45 | 0.13 | 0.038 | 0.043 | 0.046 | 0.023 | - | 4.46 |
Casting | Tensile Specimen In-House Code | E (GPa) | YS (MPa) | UTS (MPa) | Elongation to Rupture (%) |
---|---|---|---|---|---|
GJS400_P | C_1 | 185.6 | 260.4 | 295.5 | 2.62 |
C_2 | 193.5 | 261.8 | 286.8 | 2.80 | |
E_1 | 168.8 | 282.6 | 361.5 | 6.47 | |
E_2 | 167.1 | 281.0 | 366.0 | 4.37 | |
GJS400_Ce | 11 | 151.4 | 269.4 | 326.3 | 2.82 |
12 | 169.6 | 272.5 | 376.5 | 7.80 | |
13 | 154.8 | 274.9 | 418.8 | 12.63 | |
14 | 157.6 | 270.6 | 429.3 | 12.53 | |
15 | 163.3 | 271.4 | 329.2 | 4.44 | |
16 | 174.7 | 269.1 | 341.3 | 5.95 | |
17 | 162.0 | 273.3 | 461.4 | 17.85 | |
18 | 159.6 | 269.5 | 438.1 | 14.69 | |
19 | 168.0 | 269.6 | 388.3 | 5.42 | |
20 | 162.7 | 267.4 | 321.9 | 2.53 |
Sample In-House Code | C_2 | E_2 |
---|---|---|
Graphitic agglomerates volume fraction in ferrite (%) | 6.3 | 6.1 |
VFerrite (ferrite + graphitic agglomerates) (%) | 65.9 | 72.9 |
VEutectic (eutectic cells with CHG) (%) | 34.1 | 27.1 |
Largest eutectic cell diameter (mm) | 1.37 | 0.30 |
Standard deviation of the largest eutectic cell diameter (mm) | 0.69 | 0.12 |
Largest ferritic volume diameter (mm) | 1.37 | 1.04 |
Standard deviation of the largest ferritic volume diameter (mm) | 0.69 | 0.57 |
Largest graphitic agglomerate diameter in VFerrite (mm) | 0.080 | 0.058 |
Standard deviation of the largest graphitic agglomerate diameter in VFerrite (mm) | 0.025 | 0.024 |
Casting | Tensile Specimen In-House Code | Θo (MPa) | 1/εc | σV (MPa) | σo (Mpa) | εCrit | εUnif |
---|---|---|---|---|---|---|---|
GJS400_P | C_1 | 73,282.1 | 238.2 | 307.6 | 231.5 | 0.009 | 0.017 |
C_2 | 148,939.4 | 499.8 | 298.0 | 201.1 | 0.006 | 0.010 | |
E_1 | 16,841.8 | 42.5 | 396.3 | 288.1 | 0.043 | 0.058 | |
E_2 | 22,435.2 | 56.2 | 399.2 | 291.3 | 0.037 | 0.049 | |
GJS400_Ce | 11 | 16,818.1 | 47.1 | 356.8 | 267.5 | 0.024 | 0.053 |
12 | 9619.9 | 22.2 | 434.8 | 274.8 | 0.046 | 0.097 | |
13 | 8366.0 | 18.3 | 456.1 | 274.9 | 0.090 | 0.111 | |
14 | 7980.3 | 17.1 | 465.3 | 273.6 | 0.099 | 0.117 | |
15 | 18,563.8 | 50.8 | 365.2 | 267.4 | 0.020 | 0.052 | |
16 | 13,097.1 | 33.6 | 389.6 | 266.9 | 0.029 | 0.071 | |
17 | 6790.2 | 13.9 | 488.6 | 281.4 | 0.146 | 0.133 | |
18 | 7156.1 | 15.0 | 478.3 | 274.6 | 0.108 | 0.128 | |
19 | 7710.4 | 16.5 | 467.7 | 272.5 | 0.054 | 0.121 | |
20 | 19,017.7 | 54.4 | 349.4 | 265.2 | 0.021 | 0.048 |
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Angella, G.; Taloni, M.; Górny, M.; Tarasiuk, J.; Wronski, S.; Montanari, R.; Pedranz, M.; Benedetti, M.; Fontanari, V.; Lusuardi, D. An Insight into the Defects-Driven Plasticity in Ductile Cast Irons. Materials 2023, 16, 3748. https://doi.org/10.3390/ma16103748
Angella G, Taloni M, Górny M, Tarasiuk J, Wronski S, Montanari R, Pedranz M, Benedetti M, Fontanari V, Lusuardi D. An Insight into the Defects-Driven Plasticity in Ductile Cast Irons. Materials. 2023; 16(10):3748. https://doi.org/10.3390/ma16103748
Chicago/Turabian StyleAngella, Giuliano, Marcello Taloni, Marcin Górny, Jacek Tarasiuk, Sebastian Wronski, Roberto Montanari, Matteo Pedranz, Matteo Benedetti, Vigilio Fontanari, and Danilo Lusuardi. 2023. "An Insight into the Defects-Driven Plasticity in Ductile Cast Irons" Materials 16, no. 10: 3748. https://doi.org/10.3390/ma16103748