Growth of Carbon Nanofibers and Carbon Nanotubes by Chemical Vapour Deposition on Half-Heusler Alloys: A Computationally Driven Experimental Investigation
Abstract
:1. Introduction
2. Materials and Methods
2.1. Experimental Section
2.1.1. Half-Heusler Alloys
2.1.2. CVD Process Description
2.1.3. Characterization of Produced Coatings
2.2. Computational Section
2.2.1. Governing Equations and Model Assumptions
2.2.2. Gas-Phase Reactions
3. Results
3.1. Characterization of the Catalytic Substrate
3.1.1. Elemental Analysis through SEM/EDS
3.1.2. Crystallographic Structure of Half-Heusler Alloy
3.2. Numerical Analysis
3.2.1. Flow and Temperature Field
3.2.2. Chemical Species
Effect of Process Temperature
Effect of Inlet Flow
3.3. Deposited CNFs and CNTs on (ZrTi)Ni(SnSb)
3.3.1. Visual Observation
3.3.2. Morphological and Structural Characterisation of CNF/CNT Coatings
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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ID | C2H2 Flow (mL/min) | N2 Flow (mL/min) | Reaction Time (min) | Reaction Temperature (°C) | Extra Steps |
---|---|---|---|---|---|
HH1 | 46.4 | 180 | 30 | 700 | - |
HH2 (repeated) | 46.4 | 180 | 30 | 700 | - |
HH3 | 46.4 | 200 | 30 | 700 | H2 flow 100 mL/min |
HH4 | 46.4 | 360 | 15 | 700 | Thermal annealing at 400 °C |
HH5 | 46.4 | 360 | 15 | 750 | - |
Element | Point 1 | Point 2 | Point 3 |
---|---|---|---|
C | 13.8 | 2.9 | 0.0 |
Ti | 6.6 | 0.4 | 25.1 |
Ni | 1.4 | 23.7 | 3.6 |
Zr | 74.0 | 0.0 | 27.1 |
Sn | 4.2 | 73.0 | 44.2 |
Sb | 0.0 | 0.0 | 0.0 |
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Aviziotis, I.G.; Manasi, A.; Ntziouni, A.; Gakis, G.P.; Trompeta, A.-F.A.; Li, X.; Dong, H.; Charitidis, C.A. Growth of Carbon Nanofibers and Carbon Nanotubes by Chemical Vapour Deposition on Half-Heusler Alloys: A Computationally Driven Experimental Investigation. Materials 2024, 17, 3144. https://doi.org/10.3390/ma17133144
Aviziotis IG, Manasi A, Ntziouni A, Gakis GP, Trompeta A-FA, Li X, Dong H, Charitidis CA. Growth of Carbon Nanofibers and Carbon Nanotubes by Chemical Vapour Deposition on Half-Heusler Alloys: A Computationally Driven Experimental Investigation. Materials. 2024; 17(13):3144. https://doi.org/10.3390/ma17133144
Chicago/Turabian StyleAviziotis, Ioannis G., Apostolia Manasi, Afroditi Ntziouni, Georgios P. Gakis, Aikaterini-Flora A. Trompeta, Xiaoying Li, Hanshan Dong, and Costas A. Charitidis. 2024. "Growth of Carbon Nanofibers and Carbon Nanotubes by Chemical Vapour Deposition on Half-Heusler Alloys: A Computationally Driven Experimental Investigation" Materials 17, no. 13: 3144. https://doi.org/10.3390/ma17133144