Duplex Fluorinated and Atomic Layer Deposition-Derived ZrO2 Coatings Improve the Corrosion Resistance and Mechanical Properties of Mg-2Zn-0.46Y-0.5Nd (wt.%) Alloy Plates and Screws
Abstract
:1. Introduction
2. Materials and Methods
2.1. Specimen Preparation
2.2. Microstructure and Surface Characterization
2.3. In Vitro Experiment
2.4. Micro-Computed Tomography Analysis
2.5. Loading Test
2.6. Statistical Analysis
3. Results
3.1. Microstructure of the Samples
3.2. Degradation of the Plate–Screw System
3.3. Loading Test
4. Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Group A | Group B | Group C | p | |
---|---|---|---|---|
Plate residual (mm3) | 17.18 ± 2.41 | 33.01 ± 4.94 | 43.55 ± 2.12 | <0.001 * |
Plate residual (%) | 30.02 | 57.68 | 76.09 | |
Screw residual (mm3) | 9.66 ± 0.41 | 10.65 ± 0.86 | 12.15 ± 0.55 | <0.001 * |
Screw residual (%) | 73.19 | 80.69 | 92.06 | |
Screw head residual (mm3) | 1.23 ± 0.30 | 1.91 ± 0.52 | 3.17 ± 0.48 | <0.001 * |
Screw head residual (%) | 31.49 | 48.89 | 81.14 | |
Screw shaft residual (mm3) | 8.43 ± 0.36 | 8.74 ± 0.89 | 8.98 ± 0.25 | 0.077 |
Screw shaft residual (%) | 91.10 | 94.45 | 97.04 |
Group Description | Time Point | 1 mm Displacement (N) | 3 mm Displacement (N) | 5 mm Displacement (N) | 10 mm Displacement (N) |
---|---|---|---|---|---|
No surface coating | T1 | 0.351 ± 0.079 | 0.898 ± 0.064 | 1.632 ± 0.141 | 3.790 ± 0.397 |
T2 | 0.255 ± 0.051 | 0.717 ± 0.072 | 1.428 ± 0.101 | 2.837 ± 0.267 | |
T3 | 0.134 ± 0.061 | 0.462 ± 0.030 | 0.931 ± 0.126 | 1.419 ± 0.161 | |
Fluorinated coating | T1 | 0.555 ± 0.073 | 1.593 ± 0.262 | 2.554 ± 0.247 | 4.457 ± 0.567 |
T2 | 0.356 ± 0.038 | 1.059 ± 0.047 | 1.977 ± 0.252 | 3.453 ± 0.573 | |
T3 | 0.298 ± 0.045 | 0.687 ± 0.137 | 1.274 ± 0.116 | 2.085 ± 0.363 | |
Duplex fluorinated and ALD ZrO2 coating | T1 | 0.556 ± 0.032 | 1.749 ± 0.265 | 2.764 ± 0.385 | 4.687 ± 0.617 |
T2 | 0.514 ± 0.042 | 1.637 ± 0.221 | 2.606 ± 0.339 | 4.223 ± 0.484 | |
T3 | 0.489 ± 0.068 | 1.351 ± 0.283 | 2.252 ± 0.389 | 3.474 ± 0.493 | |
T4 | 0.276 ± 0.074 | 0.604 ± 0.133 | 1.377 ± 0.430 | 1.983 ± 0.372 |
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Qiu, T.; Yang, R.; Chen, L.; Liu, G.; Han, J.; Guo, C. Duplex Fluorinated and Atomic Layer Deposition-Derived ZrO2 Coatings Improve the Corrosion Resistance and Mechanical Properties of Mg-2Zn-0.46Y-0.5Nd (wt.%) Alloy Plates and Screws. Materials 2024, 17, 3485. https://doi.org/10.3390/ma17143485
Qiu T, Yang R, Chen L, Liu G, Han J, Guo C. Duplex Fluorinated and Atomic Layer Deposition-Derived ZrO2 Coatings Improve the Corrosion Resistance and Mechanical Properties of Mg-2Zn-0.46Y-0.5Nd (wt.%) Alloy Plates and Screws. Materials. 2024; 17(14):3485. https://doi.org/10.3390/ma17143485
Chicago/Turabian StyleQiu, Tiancheng, Rong Yang, Liangwei Chen, Guanqi Liu, Jianmin Han, and Chuanbin Guo. 2024. "Duplex Fluorinated and Atomic Layer Deposition-Derived ZrO2 Coatings Improve the Corrosion Resistance and Mechanical Properties of Mg-2Zn-0.46Y-0.5Nd (wt.%) Alloy Plates and Screws" Materials 17, no. 14: 3485. https://doi.org/10.3390/ma17143485