Investigation on the Curing and Thermal Properties of Epoxy/Amine/Phthalonitrile Blend
Abstract
:1. Introduction
2. Experiment
2.1. Materials
2.2. Preparation of the Bisphenol A-Type Phthalonitrile (BAPH)
2.3. Preparation of the Thermosets
2.4. Characterization
3. Results and Discussion
3.1. Characterization of the Synthesized BAPH
3.2. Rheological Properties of the E51/DDS/BAPH Blend
3.3. Curing Process of the E51/DDS/BAPH Blend
3.4. Thermal Behaviors of the E51/DDS/BAPH Thermosets
3.5. The Morphology of the Blending Thermoset
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Specimen | E51 (g) | BAPH (g) | DDS (g) |
---|---|---|---|
ED | 10.00 | 0 | 3.16 |
EDPH1 | 9.00 | 1.00 | 2.89 |
EDPH2 | 8.00 | 2.00 | 2.63 |
EDPH3 | 7.00 | 3.00 | 2.36 |
Sample | T5% a /°C | Char Yield (Measured) b /% | Char Yield (Calculated) /% | Tmax /°C | (dw/dT)max |
---|---|---|---|---|---|
ED | 363 | 16 | / | 389.2 | -1.47 |
EDPH1 | 368.5 | 44.3 | 21 | 390 | -0.6 |
EDPH2 | 374.2 | 46.7 | 26.2 | 397 | -0.5 |
EDPH3 | 390.2 | 59.6 | 31.7 | 411.2 | -0.3 |
Sample | E′ at 50 °C (MPa) | E′r (MPa) | Tg (°C) | C (mol·cm3) |
---|---|---|---|---|
ED | 2827 | 12.8 | 181.2 | 0.0010 |
EDPH1 | 2437 | 35.6 | 187.1 | 0.0030 |
EDPH2 | 2358 | 30.2 | 192.3 | 0.0024 |
EDPH3 | 1864 | 23.7 | 195 | 0.0019 |
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Peng, C.; Luo, T.; Wu, Z.; Li, S. Investigation on the Curing and Thermal Properties of Epoxy/Amine/Phthalonitrile Blend. Materials 2024, 17, 4411. https://doi.org/10.3390/ma17174411
Peng C, Luo T, Wu Z, Li S. Investigation on the Curing and Thermal Properties of Epoxy/Amine/Phthalonitrile Blend. Materials. 2024; 17(17):4411. https://doi.org/10.3390/ma17174411
Chicago/Turabian StylePeng, Cong, Tao Luo, Zhanjun Wu, and Shichao Li. 2024. "Investigation on the Curing and Thermal Properties of Epoxy/Amine/Phthalonitrile Blend" Materials 17, no. 17: 4411. https://doi.org/10.3390/ma17174411