The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement
Abstract
:1. Introduction
2. Materials and Methods
2.1. Raw Materials and Mixture Design
2.2. Sample Preparations
2.3. Characterization Methods
3. Results and Discussion
3.1. Effect of CCK and LS on the Mechanical Properties
3.2. Effect of CCK and LS on the Cement Hydration
3.3. Effect of CCK and LS on the Cement Pore Structure
4. Conclusions
- (1)
- The dilution effect of CCK and LS dominate the strength development at early hydration age, as all ternary blends represent a similar compressive strength of cement at 3 days; however, the synergistic effect of CCK and LS significantly promotes further strength development at a late hydration age. The highest compressive strength reached 47.2 MPa at 28 days. An optimal mass ratio of CCK to LS exists, wherein a ratio of 2:1 enables the blends to achieve comparable strength development.
- (2)
- CCK and LS notably influence the early hydration of cement within the first day, as evidenced by the inverse relationship between heat release and CCK content. Additionally, both CCK and LS promote a more pronounced exothermic process during hydration; all PGLC blends show similar total heat release results, and PGLC 4 represents 86.2% of total heat release as compared to reference PC after 80 h of hydration.
- (3)
- Both CCK and LS enhance the DoH of clinker throughout the hydration process, stimulating the formation of additional C-(A)-S-H and carboaluminates by consuming portlandite. The content of MC in the system is higher than 10 wt% after 56 days of hydration, and the content of CCK in raw materials only has slight impact on the content of MC at late hydration age. The additional hydration products optimized the pore structure evolution at a late hydration age; the reduction of harmful pores favors the further strength development of the system at late hydration.
- (4)
- This work establishes that the combination of CCK and LS is an ideal design for SCMs. However, it is important to consider that the incorporation of CCK increases the CO2 footprint of these blends, necessitating an optimization of the mass ratio of CCK to LS. In terms of balancing CO2 emissions and blend performance, a CCK–to–LS ratio of 2:1 exhibits comparable performance under the conditions explored in this study. This work provides a new insight into the application of LC3 systems and reduces the CO2 footprint in the cement industry.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Chemical Composition (%) | SiO2 | Al2O3 | Fe2O3 | TiO2 | CaO | MgO | SO3 | K2O | Na2O | TOL | |
Clinker | 21.29 | 5.66 | 3.78 | 0.29 | 65.99 | 1.16 | 0.37 | 0.50 | 0.32 | 0 | |
Gypsum | 6.13 | 1.64 | 0.44 | 0.09 | 31.98 | 1.21 | 36.35 | 0.35 | 0.12 | 21.07 | |
Limestone | 0.85 | 0.32 | 0.31 | 0.027 | 54.19 | 0.89 | 0.035 | 0.12 | 0.011 | 43.06 | |
CCK-raw | 44.79 | 23.32 | 7.80 | 1.96 | 2.13 | 1.07 | 0.32 | 1.14 | 0.16 | 18.78 | |
CCK-750 | 50.22 | 28.83 | 9.03 | 2.52 | 2.26 | 1.24 | 0.39 | 1.33 | 0 | 3.33 | |
Phase composition (%) | C3S | C2S | C3A | C4AF | CaO | CaSO4 | Blaine specific surface | ||||
Clinker | 66.03 | 9.26 | 12.11 | 8.62 | 1.95 | 0.06 | 314 m2/kg |
Clinker (%) | Gypsum (%) | CCK (%) | LS (%) | |
---|---|---|---|---|
PC | 95 | 5 | - | - |
PLC | 52.25 | 2.75 | - | 45 |
PGC | 52.25 | 2.75 | 45 | - |
PGLC1 | 52.25 | 2.75 | 15 | 30 |
PGLC2 | 52.25 | 2.75 | 22.5 | 22.5 |
PGLC3 | 52.25 | 2.75 | 30 | 15 |
PGLC4 | 52.25 | 2.75 | 35 | 10 |
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Tang, J.; Yu, Y.; Bu, Y.; Ma, B.; Zhou, H.; Zhou, R.; Wang, J.; Zhang, H. The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement. Materials 2024, 17, 4512. https://doi.org/10.3390/ma17184512
Tang J, Yu Y, Bu Y, Ma B, Zhou H, Zhou R, Wang J, Zhang H. The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement. Materials. 2024; 17(18):4512. https://doi.org/10.3390/ma17184512
Chicago/Turabian StyleTang, Jin, Yue Yu, Yuanqing Bu, Bing Ma, Hao Zhou, Rong Zhou, Jiaqing Wang, and Houhu Zhang. 2024. "The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement" Materials 17, no. 18: 4512. https://doi.org/10.3390/ma17184512