The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement
Abstract
:1. Introduction
2. Materials and Methods
2.1. Raw Materials and Mixture Design
2.2. Sample Preparations
2.3. Characterization Methods
3. Results and Discussion
3.1. Effect of CCK and LS on the Mechanical Properties
3.2. Effect of CCK and LS on the Cement Hydration
3.3. Effect of CCK and LS on the Cement Pore Structure
4. Conclusions
- (1)
- The dilution effect of CCK and LS dominate the strength development at early hydration age, as all ternary blends represent a similar compressive strength of cement at 3 days; however, the synergistic effect of CCK and LS significantly promotes further strength development at a late hydration age. The highest compressive strength reached 47.2 MPa at 28 days. An optimal mass ratio of CCK to LS exists, wherein a ratio of 2:1 enables the blends to achieve comparable strength development.
- (2)
- CCK and LS notably influence the early hydration of cement within the first day, as evidenced by the inverse relationship between heat release and CCK content. Additionally, both CCK and LS promote a more pronounced exothermic process during hydration; all PGLC blends show similar total heat release results, and PGLC 4 represents 86.2% of total heat release as compared to reference PC after 80 h of hydration.
- (3)
- Both CCK and LS enhance the DoH of clinker throughout the hydration process, stimulating the formation of additional C-(A)-S-H and carboaluminates by consuming portlandite. The content of MC in the system is higher than 10 wt% after 56 days of hydration, and the content of CCK in raw materials only has slight impact on the content of MC at late hydration age. The additional hydration products optimized the pore structure evolution at a late hydration age; the reduction of harmful pores favors the further strength development of the system at late hydration.
- (4)
- This work establishes that the combination of CCK and LS is an ideal design for SCMs. However, it is important to consider that the incorporation of CCK increases the CO2 footprint of these blends, necessitating an optimization of the mass ratio of CCK to LS. In terms of balancing CO2 emissions and blend performance, a CCK–to–LS ratio of 2:1 exhibits comparable performance under the conditions explored in this study. This work provides a new insight into the application of LC3 systems and reduces the CO2 footprint in the cement industry.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Shah, V.; Parashar, A.; Mishra, G.; Medepalli, S.; Krishnan, S.; Bishnoi, S. Influence of cement replacement by limestone calcined clay pozzolan on the engineering properties of mortar and concrete. Adv. Cem. Res. 2020, 32, 101–111. [Google Scholar] [CrossRef]
- Wang, Y.; Lei, L.; Shi, C. Effect of diethanolisopropanolamine and ethyldiisopropylamine on hydration and strength development of cement-fly ash-limestone ternary blend. Cem. Concr. Compos. 2024, 145, 105354. [Google Scholar] [CrossRef]
- Gong, Y.; Shao, C.; Wang, Z.; Liu, R.; Zhang, Q.; Ren, Z.; Zhu, Z.; Zhao, D.; Bai, J.; Tian, J.; et al. Feasibility study on the preparation of ternary cement with calcined slag powder and seashell powder as supplementary cementitious materials. Constr. Build. Mater. 2023, 409, 134223. [Google Scholar] [CrossRef]
- Lin, R.S.; Liao, Y.; Han, Y.; Oh, S.; Park, K.B.; Yang, H.M.; Wang, X.Y.; Yang, B.; Meng, L.Y. Low-CO2 Optimization Design of Quaternary Binder Containing Calcined Clay, Slag, and Limestone. Materials 2023, 16, 6385. [Google Scholar] [CrossRef]
- Zhang, Y.; Ling, T.-C. Reactivity activation of waste coal gangue and its impact on the properties of cement-based materials—A review. Constr. Build. Mater. 2020, 234, 117424. [Google Scholar] [CrossRef]
- Marchetti, G.; Rahhal, V.; Pavlík, Z.; Pavlíková, M.; Irassar, E.F. Assessment of packing, flowability, hydration kinetics, and strength of blended cements with illitic calcined shale. Constr. Build. Mater. 2020, 254, 119042. [Google Scholar] [CrossRef]
- Varhen, C.; Dilonardo, I.; de Oliveira Romano, R.C.; Pileggi, R.G.; de Figueiredo, A.D. Effect of the substitution of cement by limestone filler on the rheological behaviour and shrinkage of microconcretes. Constr. Build. Mater. 2016, 125, 375–386. [Google Scholar] [CrossRef]
- Sun, J.; Zunino, F.; Scrivener, K. Hydration and phase assemblage of limestone calcined clay cements (LC3) with clinker content below 50%. Cem. Concr. Res. 2024, 177, 107417. [Google Scholar] [CrossRef]
- Zunino, F.; Scrivener, K. Insights on the role of alumina content and the filler effect on the sulfate requirement of PC and blended cements. Cem. Concr. Res. 2022, 160, 106929. [Google Scholar] [CrossRef]
- Barbhuiya, S.; Nepal, J.; Das, B.B. Properties, compatibility, environmental benefits and future directions of limestone calcined clay cement (LC3) concrete: A review. J. Build. Eng. 2023, 79, 107794. [Google Scholar] [CrossRef]
- Bae, S.-C.; Yang, K.-H.; Jang, S.Y.; Kwon, S.-J.; Wang, X.-Y. Sustainable design of low-CO2 hybrid concrete incorporating calcined clay and limestone powder. J. Build. Eng. 2024, 92, 109798. [Google Scholar] [CrossRef]
- Qian, X.; Ruan, Y.; Jamil, T.; Hu, C.; Wang, F.; Hu, S.; Liu, Y. Sustainable cementitious material with ultra-high content partially calcined limestone-calcined clay. Constr. Build. Mater. 2023, 373, 130891. [Google Scholar] [CrossRef]
- Golaszewska, M.; Giergiczny, Z. Study of the Properties of Blended Cements Containing Various Types of Slag Cements and Limestone Powder. Materials 2021, 14, 6072. [Google Scholar] [CrossRef] [PubMed]
- Tamma, V.R.; Pancharathi, R.K.; Bibekananda, M.; Pallapothu, S.N.R.G. Strength and microstructure characteristics of low-grade (LG) limestone-based cements for a sustainable concrete. Environ. Dev. Sustain. 2023, 26, 22907–22927. [Google Scholar] [CrossRef]
- Blouch, N.; Rashid, K.; Ju, M. Exploring low-grade clay minerals diving into limestone calcined clay cement (LC3): Characterization−Hydration−Performance. J. Clean. Prod. 2023, 426, 139065. [Google Scholar] [CrossRef]
- Scrivener, K.; Avet, F.; Maraghechi, H.; Zunino, F.; Ston, J.; Hanpongpun, W.; Favier, A. Impacting factors and properties of limestone calcined clay cements (LC3). Green Mater. 2019, 7, 3–14. [Google Scholar] [CrossRef]
- Wang, Y.-S.; Wang, X.-Y. Multi-characterizations of the hydration, microstructure, and mechanical properties of a biochar–limestone calcined clay cement (LC3) mixture. J. Mater. Res. Technol. 2023, 24, 3691–3703. [Google Scholar] [CrossRef]
- Hu, Y.; Xiong, L.; Yan, Y.; Geng, G. Performance of limestone calcined clay cement (LC3) incorporating low-grade marine clay. Case Stud. Constr. Mater. 2024, 20, e03283. [Google Scholar] [CrossRef]
- Li, J.; Wang, J. Comprehensive utilization and environmental risks of coal gangue: A review. J. Clean. Prod. 2019, 239, 117946. [Google Scholar] [CrossRef]
- Alujas, A.; Fernández, R.; Quintana, R.; Scrivener, K.L.; Martirena, F. Pozzolanic reactivity of low grade kaolinitic clays: Influence of calcination temperature and impact of calcination products on OPC hydration. Appl. Clay Sci. 2015, 108, 94–101. [Google Scholar] [CrossRef]
- Taylor-Lange, S.C.; Lamon, E.L.; Riding, K.A.; Juenger, M.C.G. Calcined kaolinite–bentonite clay blends as supplementary cementitious materials. Appl. Clay Sci. 2015, 108, 84–93. [Google Scholar] [CrossRef]
- Zunino, F.; Scrivener, K. Microstructural developments of limestone calcined clay cement (LC3) pastes after long-term (3 years) hydration. Cem. Concr. Res. 2022, 153, 106693. [Google Scholar] [CrossRef]
- Snellings, R.; Salze, A.; Scrivener, K.L. Use of X-ray diffraction to quantify amorphous supplementary cementitious materials in anhydrous and hydrated blended cements. Cem. Concr. Res. 2014, 64, 89–98. [Google Scholar] [CrossRef]
- Bullard, J.W.; Jennings, H.M.; Livingston, R.A.; Nonat, A.; Scherer, G.W.; Schweitzer, J.S.; Scrivener, K.L.; Thomas, J.J. Mechanisms of cement hydration. Cem. Concr. Res. 2011, 41, 1208–1223. [Google Scholar] [CrossRef]
- Schöler, A.; Lothenbach, B.; Winnefeld, F.; Haha, M.B.; Zajac, M.; Ludwig, H.-M. Early hydration of SCM-blended Portland cements: A pore solution and isothermal calorimetry study. Cem. Concr. Res. 2017, 93, 71–82. [Google Scholar] [CrossRef]
- Liu, X.; Chen, Q.; Song, F.; Zhang, Q.; Guo, S.; Qiao, Y.; Jiang, Z.; Zhu, H. Research on limestone calcined clay cement-based ultra-high performance concrete with high cement substitution: Mixture design and engineering properties. Constr. Build. Mater. 2023, 409, 133913. [Google Scholar] [CrossRef]
- Wang, Y.; Tan, Y.; Wang, Y.; Liu, C. Mechanical properties and chloride permeability of green concrete mixed with fly ash and coal gangue. Constr. Build. Mater. 2020, 233, 117166. [Google Scholar] [CrossRef]
- Wang, Y.; Shui, Z.; Gao, X.; Huang, Y.; Yu, R.; Li, X.; Yang, R. Utilizing coral waste and metakaolin to produce eco-friendly marine mortar: Hydration, mechanical properties and durability. J. Clean. Prod. 2019, 219, 763–774. [Google Scholar] [CrossRef]
- Tang, J.; Ma, S.H.; Li, W.F.; Yang, H.; Shen, X.D. Research Progress on the Hydration of Portland Cement with Calcined Clay and Limestone. Mater. Sci. Forum 2021, 1036, 240–246. [Google Scholar] [CrossRef]
- Avet, F.; Scrivener, K. Investigation of the calcined kaolinite content on the hydration of Limestone Calcined Clay Cement (LC3). Cem. Concr. Res. 2018, 107, 124–135. [Google Scholar] [CrossRef]
- Avet, F.; Li, X.; Scrivener, K. Determination of the amount of reacted metakaolin in calcined clay blends. Cem. Concr. Res. 2018, 106, 40–48. [Google Scholar] [CrossRef]
- Grzegorz, L.G. Enhancement fracture behavior of sustainable cementitious composites using synergy between fly ash (FA) and nanosilica (NS) in the assessment based on digital image processing procedure. Theor. Appl. Fract. Mech. 2024, 131, 104442. [Google Scholar]
- Zhang, P.; Sun, X.Y.; Wang, F. Mechanical Properties and Durability of Geopolymer Recycled Aggregate Concrete: A Review. Polymers 2023, 15, 615. [Google Scholar] [CrossRef] [PubMed]
- Tang, J.; Wei, S.; Li, W.; Ma, S.; Ji, P.; Shen, X. Synergistic effect of metakaolin and limestone on the hydration properties of Portland cement. Constr. Build. Mater. 2019, 223, 177–184. [Google Scholar] [CrossRef]
- Zhang, W.; Tang, J.; Li, W.; Ma, S.; Sun, J. The properties and hydration of a calcined coal series metakaolin-limestone-Portland cement system. J. Therm. Anal. Calorim. 2024, 149, 5153–5163. [Google Scholar] [CrossRef]
- Maddalena, R.; Roberts, J.J.; Hamilton, A. Can Portland cement be replaced by low-carbon alternative materials? A study on the thermal properties and carbon emissions of innovative cements. J. Clean. Prod. 2018, 186, 933–942. [Google Scholar] [CrossRef]
- Kaminskas, R.; Monstvilaite, D.; Valanciene, V. Influence of low-pozzolanic activity calcined mica clay on hydration and hardening of Portland cement. Adv. Cem. Res. 2018, 30, 231–239. [Google Scholar] [CrossRef]
- Li, X.; Cao, M. Recent Developments on the Effects of Micro- and Nano-Limestone on the Hydration Process, Products, and Kinetics of Cement. Materials 2024, 17, 2133. [Google Scholar] [CrossRef]
- Yu, T.; Zhang, B.; Yuan, P.; Guo, H.; Liu, D.; Chen, J.; Liu, H.; Setti Belaroui, L. Optimization of mechanical performance of limestone calcined clay cement: Effects of calcination temperature of nanosized tubular halloysite, gypsum content, and water/binder ratio. Constr. Build. Mater. 2023, 389, 131709. [Google Scholar] [CrossRef]
- Li, X.; Ouzia, A.; Scrivener, K. Laboratory synthesis of C3S on the kilogram scale. Cem. Concr. Res. 2018, 108, 201–207. [Google Scholar] [CrossRef]
- Wu, M.; Zhang, Y.; Liu, Z.; She, W.; Liu, C.; Wang, D.; Sui, S. Study on the composition of calcium alumina silicate hydrate (CASH) in lime-activated low carbon cementitious materials: The influence of alkaline additives. Constr. Build. Mater. 2023, 392, 132089. [Google Scholar] [CrossRef]
Chemical Composition (%) | SiO2 | Al2O3 | Fe2O3 | TiO2 | CaO | MgO | SO3 | K2O | Na2O | TOL | |
Clinker | 21.29 | 5.66 | 3.78 | 0.29 | 65.99 | 1.16 | 0.37 | 0.50 | 0.32 | 0 | |
Gypsum | 6.13 | 1.64 | 0.44 | 0.09 | 31.98 | 1.21 | 36.35 | 0.35 | 0.12 | 21.07 | |
Limestone | 0.85 | 0.32 | 0.31 | 0.027 | 54.19 | 0.89 | 0.035 | 0.12 | 0.011 | 43.06 | |
CCK-raw | 44.79 | 23.32 | 7.80 | 1.96 | 2.13 | 1.07 | 0.32 | 1.14 | 0.16 | 18.78 | |
CCK-750 | 50.22 | 28.83 | 9.03 | 2.52 | 2.26 | 1.24 | 0.39 | 1.33 | 0 | 3.33 | |
Phase composition (%) | C3S | C2S | C3A | C4AF | CaO | CaSO4 | Blaine specific surface | ||||
Clinker | 66.03 | 9.26 | 12.11 | 8.62 | 1.95 | 0.06 | 314 m2/kg |
Clinker (%) | Gypsum (%) | CCK (%) | LS (%) | |
---|---|---|---|---|
PC | 95 | 5 | - | - |
PLC | 52.25 | 2.75 | - | 45 |
PGC | 52.25 | 2.75 | 45 | - |
PGLC1 | 52.25 | 2.75 | 15 | 30 |
PGLC2 | 52.25 | 2.75 | 22.5 | 22.5 |
PGLC3 | 52.25 | 2.75 | 30 | 15 |
PGLC4 | 52.25 | 2.75 | 35 | 10 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Tang, J.; Yu, Y.; Bu, Y.; Ma, B.; Zhou, H.; Zhou, R.; Wang, J.; Zhang, H. The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement. Materials 2024, 17, 4512. https://doi.org/10.3390/ma17184512
Tang J, Yu Y, Bu Y, Ma B, Zhou H, Zhou R, Wang J, Zhang H. The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement. Materials. 2024; 17(18):4512. https://doi.org/10.3390/ma17184512
Chicago/Turabian StyleTang, Jin, Yue Yu, Yuanqing Bu, Bing Ma, Hao Zhou, Rong Zhou, Jiaqing Wang, and Houhu Zhang. 2024. "The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement" Materials 17, no. 18: 4512. https://doi.org/10.3390/ma17184512
APA StyleTang, J., Yu, Y., Bu, Y., Ma, B., Zhou, H., Zhou, R., Wang, J., & Zhang, H. (2024). The Synergistic Effect of Calcained Coal-Series Kaolinite and Limestone on the Hydration of Portland Cement. Materials, 17(18), 4512. https://doi.org/10.3390/ma17184512