Green- and Blue-Emitting Tb3+-Activated Linde Type A Zeolite-Derived Boro-Aluminosilicate Glass for Deep UV Detection/Imaging
Abstract
:1. Introduction
2. Experimental Processes
2.1. Sample Preparation
2.2. Characterization
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Nominal (wt%) | Experimental (wt%) | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Na | Al | Si | O | B | Tb | Na | Al | Si | O | B | Tb | Y | |
#1 | 8.5 | 10.0 | 10.4 | 58.7 | 9.8 | 0.2 | 6.2 | 15.1 | 25.3 | 47.9 | 0 | 2.4 | 3.2 |
#2 | 8.5 | 10.0 | 10.3 | 58.3 | 9.8 | 0.9 | 6.8 | 16.95 | 21.2 | 45.1 | 0 | 3.5 | 6.5 |
#3 | 7.8 | 9.1 | 9.5 | 54.8 | 9.0 | 7.7 | 10.1 | 12.65 | 13.8 | 45.1 | 0 | 6.7 | 11.8 |
Tb3+-Doped Glass Material | Composition | Decay Time (ms) | Refs. |
---|---|---|---|
LTA zeolite-derived boro-aluminosilicate | xTb2O3-68(Na2O-Al2O3-SiO2)–32B2O3 (x = 0.2, 1.0 and 10 extra wt%) | τ1~1.2 μs, τ2~12 μs τm = 18, 14, 17 μs | Present study |
calcium aluminosilicate | 47.2CaO-41.3Al2O-4.1MgO-7.0SiO2-xTb4O7 (x = 0.04–15) (in wt%) and 33.2CaO-27.7Al2O3-4.1MgO-34SiO2-0.5Tb4O7 (in wt%) | 1.9, 2.3 | [14,19] |
fluorophosphate | 44P2O5-17K2O-(29 − x) SrF2-9Al2O3-x Tb4O7 (x = 0.1–4) (in mol%) | 2.65–2.94 | [16] |
fluoroborate | (50 − x)B2O3-20ZnF2-30BaF2-xTbF3 (x = 0.1–4.0) (in mol%) | 3.33–4.57 | [17] |
zinc phosphate | 60P2O5-15ZnO-5Al2O3-10BaO-10PbO-xTb2O3 (in mol%) (x = 1.0–5.0) (in wt%) | 2.62–2.94 | [18] |
LTA zeolite-derived aluminosilicate | Na+ was ion-exchanged with Tb3+ in Na12Al12Si12O48 | 2.398 | [19] |
calcium aluminosilicate | (100 − x)(58SiO2-23CaO-5Al2O3-4MgO-0NaF in mol%)-xTb2O3 (x = 0.25–40 in wt%) | 2.32–3.38 | [20] |
zinc phosphate | (100.0 − x)Zn(PO3)2-xTb2O3 (x = 0.6–5.0) (in mol%) | 2.76–2.97 | [22] |
zinc fluorophosphate | 44P2O5-17K2O-9Al2O3-(29 − x)ZnF2-xTb4O7 (x = 0.1–2.0) (in mol%) | 3.12–3.78 | [23] |
borogermanate | 25B2O3-40GeO2-(35 − x)Gd2O3-xTb2O3 (x = 0.25–16) (in mol%) | 1.0–1.8 | [24] |
lead germanate | 45PbO-45GeO2-9.5Ga2O3-0.5Tb2O3 (in mol%) | 1.34 | [25] |
strontium aluminoborate | 50B2O3-15Al2O3-35-xSrO-xTb4O7 (x = 0.1–5.0) (in mol%) | 2.2–2.6 | [26] |
strontium fluoroaluminate | 70SiO2-7Al2O3-16SrF2-7GdF3-4TbF3 (in mol%) | ~3.1 | [30] |
borogermanate | 50GeO2-25B2O3-(25 − x)La2O3/Gd2O3-xTb2O3 (x = 1–4) | 1.87–1.97 | [31] |
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Xiao, Y.; Hou, S.; Yang, Z.; Huang, X.; Guo, Y.; Ji, S.; Huang, X.; Wang, F.; Hu, Q.; Guo, X. Green- and Blue-Emitting Tb3+-Activated Linde Type A Zeolite-Derived Boro-Aluminosilicate Glass for Deep UV Detection/Imaging. Materials 2024, 17, 671. https://doi.org/10.3390/ma17030671
Xiao Y, Hou S, Yang Z, Huang X, Guo Y, Ji S, Huang X, Wang F, Hu Q, Guo X. Green- and Blue-Emitting Tb3+-Activated Linde Type A Zeolite-Derived Boro-Aluminosilicate Glass for Deep UV Detection/Imaging. Materials. 2024; 17(3):671. https://doi.org/10.3390/ma17030671
Chicago/Turabian StyleXiao, Yongneng, Shaoyi Hou, Zhenhuai Yang, Xingxing Huang, Yuanjun Guo, Siyu Ji, Xiaochan Huang, Fengshuang Wang, Qiang Hu, and Xiaodong Guo. 2024. "Green- and Blue-Emitting Tb3+-Activated Linde Type A Zeolite-Derived Boro-Aluminosilicate Glass for Deep UV Detection/Imaging" Materials 17, no. 3: 671. https://doi.org/10.3390/ma17030671