Removing Sr(II) and Cs(I) from the Aqueous Phase Using Basil Seed and Elucidating the Adsorption Mechanism
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Adsorption Capability of Sr(II) And Cs(I) Using the BS, Calcined BS, And Enzyme-Treated BS
2.3. Adsorption Isotherms of Sr(II) And Cs(I) by the BS and Calcined BS
2.4. Effects of Contact Time And pH on the Adsorption of Sr(II) And Cs(I) by the BS and Calcined BS
3. Results and Discussion
3.1. Effect of Calcination Treatment on Physicochemical Properties
3.2. Adsorption Capability of Sr(II) And Cs(I)
3.3. Adsorption Kinetics of Sr(II) And Cs(I)
3.4. Adsorption Isotherms of Sr(II) And Cs(I)
3.5. Effect of pH on the Adsorption of Sr(II) And Cs(I)
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Adsorbents | Enzyme | pH | Temperature (°C) |
---|---|---|---|
M-BS | Mannanase BGM | 5.0 | 50–70 |
P-BS | Pectinase G | 4.0 | 50 |
H-BS | Hemicellulase | 4.5 | 45 |
C-BS | Cellulase A | 4.5 | 50–60 |
Adsorbents | pHpzc | Surface Functional Groups (mmol/g) | Specific Surface Area (m2/g) | Pore Volume (cc/g) | |||
---|---|---|---|---|---|---|---|
Acidic | Basic | Micro | Meso | Macro | |||
BS | 5.59 | 0.050 | 0.605 | 0.265 | N/A* | N/A* | N/A* |
BS500 | 9.85 | 0.006 | 0.127 | 0.937 | N/A* | 0.004 | 0.006 |
BS1000 | 0.006 | 0.006 | 0.187 | 0.187 | N/A* | 0.019 | 0.005 |
Samples | Adsorbents | Adsorption Capability (mg/g) | pH | Temp.(°C) | Initial Concentration (mg/L) | Contact Time (h) | Adsorbent (g/L) | Ref. |
---|---|---|---|---|---|---|---|---|
Sr(II) | Paprika biochar | 0.02 | - | 25 | 1 | 24 | 1 | [26] |
Spent mushroom biochar | 0.04 | - | 25 | 1 | 24 | 1 | [26] | |
Rice straw biochar | 0.05 | - | 25 | 1 | 24 | 1 | [26] | |
Brewery’s waste biomass | 7.91 | 4 | 30 | Approximately 700 | 3 | 2 | [10] | |
Rhizopus nigricans | 24.5 | 5 | 22 ± 1 | 1000 | 2 | - | [27] | |
BS | 0.63 | - | 25 | 1 | 24 | 1 | This study | |
Cs(I) | Brewery’s waste biomass | 10.1 | 4 | 30 | Approximately 700 | 3 | 2 | [10] |
Arca shell biomass | 4.00 | 5.5 | 25 ± 2 | 10–500 | 3 | 5 | [29] | |
Bamboo charcoal | 0.17 | - | 20 | 800 | 6 | 1 | [28] | |
Gracilaria corticata | 14.6 | 5.5 | 30 | 20–500 | 3 | 2 | [30] | |
BS | 0.52 | - | 25 | 1 | 24 | 1 | This study |
Samples | Adsorbents | qe,exp | Pseudo-First Order Model | Pseudo-Second Order Model | ||||
---|---|---|---|---|---|---|---|---|
k1 (1/h) | qe,cal (mg/g) | r | k2 (g/mg/h) | qe,cal (mg/g) | r | |||
Sr(II) | BS | 632.5 | 2.4 × 10−1 | 293.0 | 0.961 | 1.2 × 10−3 | 674.9 | 0.986 |
BS500 | 287.6 | 1.9 × 10−1 | 114.8 | 0.917 | 4.1 × 10−3 | 305.1 | 0.998 | |
BS1000 | 587.3 | 6.4 × 10−1 | 547.1 | 0.956 | 1.8 × 10−3 | 621.9 | 0.998 | |
Cs(I) | BS | 519.4 | 4.8 × 10−3 | 88.0 | 0.050 | −2.4 × 10−2 | 519.6 | 1.000 |
BS500 | 191.7 | 5.4 × 10−2 | 10.9 | 0.459 | −1.5 × 10−2 | 151.8 | 0.972 | |
BS1000 | 49.2 | 3.6 × 10−3 | 47.0 | 0.090 | −7.8 × 10−2 | 58.3 | 0.970 |
Samples | Adsorbents | Langmuir Constants | Freundlich Constants | ||||
---|---|---|---|---|---|---|---|
qmax (mg/g) | KL (L/mg) | r | logKF | 1/n | r | ||
Sr(II) | BS | 441.6 | 5.6 × 10−3 | 0.962 | 1.3 | 1.5 | 0.966 |
BS500 | 838.4 | 8.0 × 10−4 | 1.000 | 0.8 | 1.3 | 0.998 | |
BS1000 | 825.0 | 1.1 × 10−3 | 0.989 | 1.1 | 0.9 | 0.990 | |
Cs(I) | BS | 948.0 | 1.6 × 10−3 | 0.996 | 1.1 | 1.1 | 0.997 |
BS500 | 421.0 | 1.0 × 10−3 | 0.986 | 1.1 | 0.3 | 0.981 | |
BS1000 | 12.1 | 1.4 × 10−3 | 0.964 | 2.6 | 3.7 × 10−6 | 0.957 |
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Uematsu, Y.; Ogata, F.; Saenjum, C.; Nakamura, T.; Kawasaki, N. Removing Sr(II) and Cs(I) from the Aqueous Phase Using Basil Seed and Elucidating the Adsorption Mechanism. Sustainability 2020, 12, 2895. https://doi.org/10.3390/su12072895
Uematsu Y, Ogata F, Saenjum C, Nakamura T, Kawasaki N. Removing Sr(II) and Cs(I) from the Aqueous Phase Using Basil Seed and Elucidating the Adsorption Mechanism. Sustainability. 2020; 12(7):2895. https://doi.org/10.3390/su12072895
Chicago/Turabian StyleUematsu, Yugo, Fumihiko Ogata, Chalermpong Saenjum, Takehiro Nakamura, and Naohito Kawasaki. 2020. "Removing Sr(II) and Cs(I) from the Aqueous Phase Using Basil Seed and Elucidating the Adsorption Mechanism" Sustainability 12, no. 7: 2895. https://doi.org/10.3390/su12072895