Impregnation of CaO from Eggshell Waste with Magnetite as a Solid Catalyst (Fe3O4/CaO) for Transesterification of Palm Oil Off-Grade
Abstract
:1. Introduction
2. Results and Discussion
2.1. Extraction of Palm Oil Off-Grade
2.1.1. Catalyst Characterization
2.1.2. Hammett Indicator Titration
2.1.3. Braunaeur–Emmet–Teller (BET)
2.2. Catalytic Study of Fe3O4/CaO
2.2.1. Biodiesel Yield
2.2.2. Biodiesel Characterization
2.3. Separation of Fe3O4/CaO Catalyst
3. Experimental Section
3.1. Materials
3.2. Equipment
3.3. Raw Material Preparation
3.4. Preparation of Fe3O4/CaO Base Catalysts
3.5. Catalytic Study
3.6. Catalyst Characterization
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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No. | Parameter | Unit | Value | Standard CPO SNI 01-2901-2006 |
---|---|---|---|---|
1 2 3 4 5 | Density (40°) Viscosity (40°) Moisture FFA Color | kg/m3 mm2/s % % | 894 29.50 3.5 6.9 Orange | - - Max 0.5 Max 0.5 Orange |
Dehydration Temperature (°C) | Dehydration (h) | Strength (H_) |
---|---|---|
500 °C | 2 | 7.2 < H_ < 9.3 |
3 | 7.2 < H_ < 9.3 | |
4 | 7.2 < H_ < 9.3 | |
600 °C | 2 | 9.3 < H_ < 12.2 |
3 | 12.2 < H_ < 15.0 | |
4 | 7.2 < H_ < 9.3 | |
700 °C | 2 | 7.2 < H_ < 9.3 |
3 | 7.2 < H_ < 9.3 | |
4 | 7.2 < H_ < 9.3 |
Dehydration Temperature (°C) | Dehydration Time (h) | Surface Area (m2/g) |
---|---|---|
500 °C | 2 | 27.70 |
3 | 31.55 | |
4 | 46.75 | |
600 °C | 2 | 148.65 |
3 | 265.37 | |
4 | 49.43 | |
700 °C | 2 | 15.67 |
3 | 35.67 | |
4 | 44.24 |
No. | Characteristics | Unit | Result | SNI 7182:2015 |
---|---|---|---|---|
1 | Density | kg/m3 | 871.59 | 850–890 |
2 | Kinematic viscosity | mm2/s | 3.81 | 2.3–6.0 |
3 | Flash point | °C | 135 | Min. 100 |
4 5 | Acid number Cetane number | mg-KOH/g | 0.423 53 | Max. 0.5 >48 |
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Helwani, Z.; Ramli, M.; Saputra, E.; Bahruddin, B.; Yolanda, D.; Fatra, W.; Idroes, G.M.; Muslem, M.; Mahlia, T.M.I.; Idroes, R. Impregnation of CaO from Eggshell Waste with Magnetite as a Solid Catalyst (Fe3O4/CaO) for Transesterification of Palm Oil Off-Grade. Catalysts 2020, 10, 164. https://doi.org/10.3390/catal10020164
Helwani Z, Ramli M, Saputra E, Bahruddin B, Yolanda D, Fatra W, Idroes GM, Muslem M, Mahlia TMI, Idroes R. Impregnation of CaO from Eggshell Waste with Magnetite as a Solid Catalyst (Fe3O4/CaO) for Transesterification of Palm Oil Off-Grade. Catalysts. 2020; 10(2):164. https://doi.org/10.3390/catal10020164
Chicago/Turabian StyleHelwani, Zuchra, Muliadi Ramli, Edy Saputra, Bahruddin Bahruddin, Delvi Yolanda, Warman Fatra, Ghazi Mauer Idroes, Muslem Muslem, Teuku Meurah Indra Mahlia, and Rinaldi Idroes. 2020. "Impregnation of CaO from Eggshell Waste with Magnetite as a Solid Catalyst (Fe3O4/CaO) for Transesterification of Palm Oil Off-Grade" Catalysts 10, no. 2: 164. https://doi.org/10.3390/catal10020164
APA StyleHelwani, Z., Ramli, M., Saputra, E., Bahruddin, B., Yolanda, D., Fatra, W., Idroes, G. M., Muslem, M., Mahlia, T. M. I., & Idroes, R. (2020). Impregnation of CaO from Eggshell Waste with Magnetite as a Solid Catalyst (Fe3O4/CaO) for Transesterification of Palm Oil Off-Grade. Catalysts, 10(2), 164. https://doi.org/10.3390/catal10020164