Visible-Light Driven Photocatalytic Degradation of Pirimicarb by Pt-Doped AgInS2 Nanoparticles
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the as-Prepared Undoped and Pt-doped AgInS2 samples
2.2. Photocatalytic Reaction
2.2.1. Effect of Pt Content
2.2.2. Effect of Catalyst Dosage
2.2.3. Effect of Initial Ph Value
2.2.4. Identification of Active Species (Quenching and ESR Studies)
2.2.5. Reaction Pathway of Pirimicarb Degradation
2.2.6. Efficiency of Recycled Catalyst
2.2.7. Photocatalytic Treatment of Natural Water Samples
3. Materials and Methods
3.1. Materials
3.2. Preparation and Characterization Of Pt/Agins2
3.3. Apparatus and Instruments
3.4. Procedures and Analyses
3.5. Procedure for Degradation of Pirimicarb in Natural Water Samples
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Photocatalysts | Oxidants | Degradation Efficiency (%) | Degradation Time | Light Source | References |
---|---|---|---|---|---|
TiO2 | No oxidant | 50% | 72 h | UV light | [19] |
Single-walled carbon nanotubes-TiO2 hybrid | No oxidant | 32–33% | 30 min | UV light (full light) | [20] |
ZnMoO4 | No oxidant | 93% | 12 h | UV light | [15] |
PMS | 98% | 3 h | UV light | [15] | |
BiVO4 | No oxidant | <5% | 16 h | Visible light | [16] |
H2O2 | 97.6% | 4 h | Visible light | [16] | |
Pt/AgInS2 | No oxidant | 98% | 24 h | Visible light | Present work |
Experiment | Conditions | Results (After 24 h) |
---|---|---|
I-Adsorption (no Pt) | ♦ Pirimicarb (10 mg L−1) ♦ AgInS2 (0.5 g L−1) (No Pt doping, no visible light) | Less than 15% of pirimicarb adsorption |
II-Adsorption (Pt) | ♦ Pirimicarb (10 mg L−1) ♦ Pt/AgInS2 (0.5 g L−1) (No visible light) | Less than 15% of pirimicarb adsorption |
III-Photolysis | ♦ Pirimicarb (10 mg L−1) ♦ Visible light (No Pt/AgInS2) | negligible pirimicarb degradation |
IV-Photocatalysis | ♦ Pirimicarb (10 mg L−1) ♦ Pt/AgInS2 (0.5 g L−1) (Visible light) | 85% pirimicarb degradation |
Pt content (wt%) | kapp (hr−1) | R2 |
---|---|---|
0 | 0.015 | 0.97 |
0.25 | 0.043 | 0.96 |
0.5 | 0.045 | 0.98 |
1.0 | 0.092 | 0.93 |
1.5 | 0.055 | 0.94 |
Structure | tR (min) | Characteristic Ions (m/z) |
---|---|---|
34.11 | [M]+ = 239, 195, 182 (PMC) 2-dimethylamino-5,6-dimethyl pyrimidin-4-yl-dimethylcarbamate | |
31.61 | [M]+ = 253, 225, 196 (A) 2-[(methylformyl)amino]-5,6-dimethyl pyrimidin-4-yl-dimethylcarbamate | |
28.83 | [M]+ = 225, 180, 168 (B) 2-methylamino-5,6-dimethylpyrimidin- 4-yl-dimethylcarbamate | |
27.13 | [M]+ = 239, 211, 182 (C) 2-(formylamino)-5,6-dimethylpyrimidin- 4-yl-dimethylcarbamate | |
25.63 | [M]+ = 211, 166, 154 (D) 2-amino-5,6-dimethylpyrimidin- 4-yl-dimethylcarbamate | |
20.49 | [M]+ = 168, 123, 98 (E) 2-dimethylamino-5,6-dimethyl-4- hydroxypyrimidine | |
18.31 | [M]+ = 154, 137, 98 (F) 2-methylamino-5,6-dimethyl-4- hydroxypyrimidine | |
14.70 | [M]+ = 140, 123, 98 (G) 2-amino-5,6-dimethyl-4-hydroxy pyrimidine |
Parameter | River Water | Lake Water |
---|---|---|
pH | 6.30 | 6.24 |
Conductivity (μmho cm−1) | 420 | 378 |
Turbidity (NTU) | 2.9 | 4.9 |
TOC (mg L−1) | 13.43 | 3.44 |
Sulfate (mg L−1) | 48.1 | 50.9 |
Chloride (mg L−1) | 22.6 | 16.7 |
Nitrate (mg L−1) | 84.8 | 2.9 |
Nitrite (mg L−1) | 1.12 | 0.02 |
Catalysts | Pt loading (wt%) | |
---|---|---|
Intended | Actual | |
0.25 wt% Pt/AgInS2 | 0.25 | 0.267 |
0.5 wt% Pt/AgInS2 | 0.5 | 0.586 |
1.0 wt% Pt/AgInS2 | 1.0 | 1.060 |
1.5 wt% Pt/AgInS2 | 1.5 | 1.530 |
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Tsai, H.; Shaya, J.; Tesana, S.; Golovko, V.B.; Wang, S.-Y.; Liao, Y.-Y.; Lu, C.-S.; Chen, C.-C. Visible-Light Driven Photocatalytic Degradation of Pirimicarb by Pt-Doped AgInS2 Nanoparticles. Catalysts 2020, 10, 857. https://doi.org/10.3390/catal10080857
Tsai H, Shaya J, Tesana S, Golovko VB, Wang S-Y, Liao Y-Y, Lu C-S, Chen C-C. Visible-Light Driven Photocatalytic Degradation of Pirimicarb by Pt-Doped AgInS2 Nanoparticles. Catalysts. 2020; 10(8):857. https://doi.org/10.3390/catal10080857
Chicago/Turabian StyleTsai, Hweiyan, Janah Shaya, Siriluck Tesana, Vladimir B. Golovko, Syuan-Yun Wang, Yi-Yen Liao, Chung-Shin Lu, and Chiing-Chang Chen. 2020. "Visible-Light Driven Photocatalytic Degradation of Pirimicarb by Pt-Doped AgInS2 Nanoparticles" Catalysts 10, no. 8: 857. https://doi.org/10.3390/catal10080857