Hydrotreating of Waste Tire Pyrolysis Oil over Highly Dispersed Ni2P Catalyst Supported on SBA-15
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterizations of the Supported Nickel Phosphide Catalysts
2.2. Characterizations of the Tire Pyrolysis Oil (TPO)
2.3. Activity Test
3. Experimental Section
3.1. Synthesis and Characterization of Supported Nickel Phosphide Catalysts
3.2. Activity Test of Hydrotreating of Tire Pyrolysis-Oil (TPO)
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
- Chen, D.M.C.; Bodirsky, B.L.; Krueger, T.; Mishra, A.; Popp, A. The world’s growing municipal solid waste: Trends and impacts. Environ. Res. Lett. 2020, 15, 074021. [Google Scholar] [CrossRef]
- Palos, R.; Gutiérrez, A.; Vela, F.J.; Olazar, M.; Arandes, J.M.; Bilbao, J. Waste Refinery: The Valorization of Waste Plastics and End-of-Life Tires in Refinery Units. A Review. Energy Fuels 2021, 35, 3529–3557. [Google Scholar] [CrossRef]
- Gamboa, A.R.; Rocha, A.M.A.; dos Santos, L.R.; de Carvalho, J.A. Tire pyrolysis oil in Brazil: Potential production and quality of fuel. Renew. Sustain. Energy Rev. 2020, 120, 109614. [Google Scholar] [CrossRef]
- Laresgoiti, M.F.; Caballero, B.M.; De Marco, I.; Torres, A.; Cabrero, M.A.; Chomón, M.J. Characterization of the liquid products obtained in tyre pyrolysis. J. Anal. Appl. Pyrolysis 2004, 71, 917–934. [Google Scholar] [CrossRef]
- Williams, P.T.; Besler, S. Pyrolysis-thermogravimetric analysis of tyres and tyre components. Fuel 1995, 74, 1277–1283. [Google Scholar] [CrossRef]
- Williams, P.T. Pyrolysis of waste tyres: A review. Waste Manag. 2013, 33, 1714–1728. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Dos Santos, R.G.; Rocha, C.L.; Felipe, F.L.S.; Cezario, F.T.; Correia, P.J.; Rezaei-Gomari, S. Tire waste management: An overview from chemical compounding to the pyrolysis-derived fuels. J. Mater. Cycles Waste Manag. 2020, 22, 628–641. [Google Scholar] [CrossRef]
- Cheng, Z.; Li, M.; Li, J.; Lin, F.; Ma, W.; Yan, B.; Chen, G. Transformation of nitrogen, sulfur and chlorine during waste tire pyrolysis. J. Anal. Appl. Pyrolysis 2020, 153, 104987. [Google Scholar] [CrossRef]
- Mirmiran, S.; Pakdel, H.; Roy, C. Characterization of used tire vacuum pyrolysis oil: Nitrogenous compounds from the naphtha fraction. J. Anal. Appl. Pyrolysis 1992, 22, 205–215. [Google Scholar] [CrossRef]
- Hita, I.; Gutiérrez, A.; Olazar, M.; Bilbao, J.; Arandes, J.M.; Castaño, P. Upgrading model compounds and Scrap Tires Pyrolysis Oil (STPO) on hydrotreating NiMo catalysts with tailored supports. Fuel 2015, 145, 158–169. [Google Scholar] [CrossRef]
- Hwang, Y.-H.; Lee, Y.-K. Structure and activity of unsupported NiWS2 catalysts for slurry phase hydrocracking of vacuum residue: XAFS studies. J. Catal. 2021, in press. [Google Scholar] [CrossRef]
- Dujardin, C.; Lélias, M.A.; van Gestel, J.; Travert, A.; Duchet, J.C.; Maugé, F. Towards the characterization of active phase of (Co)Mo sulfide catalysts under reaction conditions-Parallel between IR spectroscopy, HDS and HDN tests. Appl. Catal. A 2007, 322, 46–57. [Google Scholar] [CrossRef]
- Ho, T.C. Deep HDS of diesel fuel: Chemistry and catalysis. Catal. Today 2004, 98, 3–18. [Google Scholar] [CrossRef]
- Yun, G.N.; Ahn, S.J.; Takagaki, A.; Kikuchi, R.; Oyama, S.T. Hydrodeoxygenation of Γ-valerolactone on bimetallic NiMo phosphide catalysts. J. Catal. 2017, 353, 141–151. [Google Scholar] [CrossRef]
- Yun, G.N.; Takagaki, A.; Kikuchi, R.; Ted Oyama, S. Hydrodeoxygenation of gamma-valerolactone on transition metal phosphide catalysts. Catal. Sci. Technol. 2017, 7, 281–292. [Google Scholar] [CrossRef]
- Yun, G.N.; Cho, K.S.; Kim, Y.S.; Lee, Y.K. A new approach to deep desulfurization of light cycle oil over Ni2P catalysts: Combined selective oxidation and hydrotreating. Catalysts 2018, 8, 102. [Google Scholar] [CrossRef] [Green Version]
- Yun, G.-N.; Lee, Y.-K. Dispersion effects of Ni2P catalysts on hydrotreating of light cycle oil. Appl. Catal. B 2014, 150–151, 647–655. [Google Scholar] [CrossRef]
- Djandja, O.S.; Wang, Z.; Duan, P.; Wang, F.; Xu, Y. Hydrotreatment of pyrolysis oil from waste tire in tetralin for production of high-quality hydrocarbon rich fuel. Fuel 2021, 285, 119185. [Google Scholar] [CrossRef]
- Han, Y.; Stankovikj, F.; Garcia-Perez, M. Co-hydrotreatment of tire pyrolysis oil and vegetable oil for the production of transportation fuels. Fuel Process. Technol. 2017, 159, 328–339. [Google Scholar] [CrossRef] [Green Version]
- Dębek, C.; Walendziewski, J. Hydrorefining of oil from pyrolysis of whole tyres for passenger cars and vans. Fuel 2015, 159, 659–665. [Google Scholar] [CrossRef]
- Rundqvist, S. X-Ray Investigations of Mn3P, Mn2P, and Ni2P. Acta Chem. Scand. 1962, 16, 992–998. [Google Scholar] [CrossRef] [Green Version]
- Pan, Y.; Yang, D.; Sun, K.; Wang, X.; Zhou, Y.; Huang, Q. Pyrolytic transformation behavior of hydrocarbons and heteroatom compounds of scrap tire volatiles. Fuel 2020, 276, 118095. [Google Scholar] [CrossRef]
- Hita, I.; Aguayo, A.T.; Olazar, M.; Azkoiti, M.J.; Bilbao, J.; Arandes, J.M.; Castaño, P. Kinetic Modeling of the Hydrotreating and Hydrocracking Stages for Upgrading Scrap Tires Pyrolysis Oil (STPO) toward High-Quality Fuels. Energy Fuels 2015, 29, 7542–7553. [Google Scholar] [CrossRef]
- Oyama, S.T.; Lee, Y.-K. The active site of nickel phosphide catalysts for the hydrodesulfurization of 4,6-DMDBT. J. Catal. 2008, 258, 393–400. [Google Scholar] [CrossRef]
- Lee, Y.K.; Shu, Y.; Oyama, S.T. Active phase of a nickel phosphide (Ni2P) catalyst supported on KUSY zeolite for the hydrodesulfurization of 4,6-DMDBT. Appl. Catal. A 2007, 322, 191–204. [Google Scholar] [CrossRef]
- Kim, J.; Jang, J.G.; Lee, Y.K. Reactivity of sulfur compounds in FCC decant oils for hydrodesulfurization over CoMoS2/Al2O3 catalysts. Korean J. Chem. Eng. 2021, 38, 1179–1187. [Google Scholar] [CrossRef]
- Jang, J.-G.; Lee, Y.-K. Promotional effect of Ga for Ni2P catalyst on hydrodesulfurization of 4,6-DMDBT. Appl. Catal. B 2019, 250, 181–188. [Google Scholar] [CrossRef]
Sample | BET Surface Area /m2 g−1 | CO Uptake /mol g−1 | Crystallite Size a /nm |
---|---|---|---|
SBA-15 | 687 | - | - |
Ni2P/SBA-15 | 340 | 84.3 | 3.8 |
SiO2(EH-5) | 200 | - | - |
Ni2P/SiO2 | 124 | 71.2 | 9.1 |
Physical Properties | TPO | |
---|---|---|
S/ppm | 14,500 | |
N/ppm | 4070 | |
Aromatics/wt.% | Total | 41 |
Mono | 27 | |
Di | 8 | |
Tri+ | 6 | |
Distillation/°C | IBP/20/31 44/58/72 80/EP | 110/150/180 210/240/270 290/320 |
NiMoS | Ni2P/SBA-15 | Ni2P/SiO2 | ||
---|---|---|---|---|
HDS conversion/% | Total S | 94.5 | 89.3 | 73.0 |
Light S | 90.8 | 82.5 | 57.4 | |
Benzothiazole | 100 | 100 | 100 | |
Heavy S | 47.9 | 79.9 | 43.0 | |
HDN conversion/% | Total N | 72.9 | 60.7 | 41.0 |
Light N (Aniline) | 78.4 (72.5) | 63.8 (58.2) | 70.2 (56.9) | |
Benzothiazole | 99.5 | 100 | 100 | |
Heavy N (Dimethylquinoline) | 93.0 (84.3) | 90.7 (84.3) | 96.9 (93) |
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Yun, G.-N.; Kim, K.-D.; Lee, Y.-K. Hydrotreating of Waste Tire Pyrolysis Oil over Highly Dispersed Ni2P Catalyst Supported on SBA-15. Catalysts 2021, 11, 1272. https://doi.org/10.3390/catal11111272
Yun G-N, Kim K-D, Lee Y-K. Hydrotreating of Waste Tire Pyrolysis Oil over Highly Dispersed Ni2P Catalyst Supported on SBA-15. Catalysts. 2021; 11(11):1272. https://doi.org/10.3390/catal11111272
Chicago/Turabian StyleYun, Gwang-Nam, Ki-Duk Kim, and Yong-Kul Lee. 2021. "Hydrotreating of Waste Tire Pyrolysis Oil over Highly Dispersed Ni2P Catalyst Supported on SBA-15" Catalysts 11, no. 11: 1272. https://doi.org/10.3390/catal11111272