Silver(I)-Catalyzed C4-H Amination of 1-Naphthylamine Derivatives with Azodicarboxylates at Room Temperature
Abstract
:1. Introduction
2. Results and Discussion
3. Experimental Section
3.1. General Information
3.2. General Procedure for Synthesis of Product 3aa
3.3. General Procedure for Synthesis of Product 3
3.4. Spectral Data for Products
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Entry | Catalyst | Solvent | Yield (%) b |
1 | Ag2O | DCE | 80 |
2 | Ag2O | dioxane | 90 |
3 | Ag2O | acetone | 97 |
4 | Ag2O | THF | 90 |
5 | Ag2O | DME | 80 |
6 | Ag2O | DCM | <5 |
7 | CuO | acetone | <5 |
8 | Cu2O | acetone | <5 |
9 | Fe2O3 | acetone | <5 |
10 | AgOAc | acetone | <5 |
11 | - | acetone | <5 |
12 c | Ag2O | acetone | 88 |
13 d | Ag2O | acetone | 46 |
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Zhang, Y.; Pei, M.; Yang, F.; Wu, Y. Silver(I)-Catalyzed C4-H Amination of 1-Naphthylamine Derivatives with Azodicarboxylates at Room Temperature. Catalysts 2022, 12, 1006. https://doi.org/10.3390/catal12091006
Zhang Y, Pei M, Yang F, Wu Y. Silver(I)-Catalyzed C4-H Amination of 1-Naphthylamine Derivatives with Azodicarboxylates at Room Temperature. Catalysts. 2022; 12(9):1006. https://doi.org/10.3390/catal12091006
Chicago/Turabian StyleZhang, Yuxue, Mengxue Pei, Fan Yang, and Yangjie Wu. 2022. "Silver(I)-Catalyzed C4-H Amination of 1-Naphthylamine Derivatives with Azodicarboxylates at Room Temperature" Catalysts 12, no. 9: 1006. https://doi.org/10.3390/catal12091006