Polymer Capsules for Enzymatic Catalysis in Confined Environments
Abstract
:1. Introduction
2. Compartmentalized Spaces
2.1. Hollow Polymer Capsules Preparation Routes
2.2. Molecular Diffusion Through Polymeric Capsules
3. Polymer Capsules as Reactors—General Outlook
3.1. Hollow Capsules for Inorganic Catalysts
3.2. Polymer Capsules for Biocatalysts
3.2.1. Polymerosomes
3.2.2. Layer by Layer Assemblies
3.2.3. Pickering Emulsions
3.2.4. Flow Focusing
4. Conclusions and Perspectives
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Catalysts | Reference |
---|---|
Acid phosphatase (AP) | [81] |
Alcohol oxidase (AOX) | [88] |
Benzaldehyde lyase (BL) | [86] |
Catalase (CAT) | [5,70,79,80,88] |
β-galactosidase (β-GAL) | [77,78] |
Glucose oxidase (GOX) | [61,62,63,72,75,79,80] |
Glutathione reductase (GR) | [83] |
Horseradish peroxidase (HRP) | [61,62,63,64,71,72,73,75] |
Laccase (LAC) | [76] |
β-lactamase (BL) | [19,82] |
Lactoperoxidase (LPO) | [38,70] |
Lipase A (CALA) | [86] |
Lipase B (CALB) | [61,63,65,86] |
Lipase (from Pseudomonas cepacia) (PCL) | [87] |
Luciferase (LUC) | [19] |
Myoglobin (MB) | [74,75] |
Penicilln acylase (PA) | [69] |
Superoxide Dismutase (SOD) | [38,66,68,70] |
Uricase (UOX) | [73] |
Membrane Composition | Reference | |
---|---|---|
Polymer Name | Acronym | |
Poly(o-methoxy aniline) | POMA | [60] |
Polystyrene-polyisocyanoalanine (2-thiophen-3-yl-ethyl)amide) | Copolymer PS–PIAT | [61,62,63,64,65] |
Poly(2-methyloxazoline)-poly(dimethylsiloxane)-poly(2-methyloxazoline) | Copolymer PMOXA-PDMS-PMOXA | [36,38,66,67,68,69,70,71,72,73] |
Poly(ethylene glycol)-poly(diethylaminoethyl methacrylate)-poly(3,4-dimethyl maleic imidobutyl methacrylate) | Copolymer PEG-PDEAEM-PDMIBM | [74] |
Poly(ethylene glycol)-poly-(styrene-co-3-isopropenyl dimethylbenzylisocyanate) | Copolymer PEG-P(S-co-TMI)n | [86] |
Poly(N-vinylpyrrolidone)-poly(dimethylsiloxane)-poly(N-vinylpyrrolidone) | Copolymer PNVP-b-PDMS-b-PNVP | [76] |
Poly(ethylene glycol)-b-poly(aspartic acid):poly([8-aminoctyl]-α,β-aspartamide) | Copolymer PEG-PArg:Homo-P(Asp-C8) | [77,78] |
Poly(ethylene glycol)-block-poly(ε-caprolactone) | Copolymer PEG-PCL | [34] |
Cholesterol-modified poly(L-lysine)/liposomes layer/poly(methacrylic acid)-co-(cholesteryl methacrylate)/poly(N-vinyl pyrrolidone)/thiol-functionalized poly(methacrylic acid) | Multilayer film PLLc/liposomes/PMAc/PVP/PMASH | [19,82] |
Alginate/Chitosan | Multilayer film ALG/CHI | [7,22,42,43] |
Poly(sodium-styrene sulfonate)/poly(allylamine) hydrochloride | Multilayer film PSS/PAH | [5] |
Glucose oxidase/Catalase | Multilayer film GOX/CAT | [79] |
Glucose oxidase/polyethylenimine/Catalase | Multilayer film GOX/PEI/CAT | [80] |
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Cuomo, F.; Ceglie, A.; De Leonardis, A.; Lopez, F. Polymer Capsules for Enzymatic Catalysis in Confined Environments. Catalysts 2019, 9, 1. https://doi.org/10.3390/catal9010001
Cuomo F, Ceglie A, De Leonardis A, Lopez F. Polymer Capsules for Enzymatic Catalysis in Confined Environments. Catalysts. 2019; 9(1):1. https://doi.org/10.3390/catal9010001
Chicago/Turabian StyleCuomo, Francesca, Andrea Ceglie, Antonella De Leonardis, and Francesco Lopez. 2019. "Polymer Capsules for Enzymatic Catalysis in Confined Environments" Catalysts 9, no. 1: 1. https://doi.org/10.3390/catal9010001