Conversion of 5-Methyl-3-Heptanone to C8 Alkenes and Alkane over Bifunctional Catalysts
Abstract
:1. Introduction
2. Results and Discussions
2.1. Characterization of Catalysts
2.1.1. X-Ray Diffraction (XRD)
2.1.2. Transmission Electron Microscopy (TEM)
2.1.3. N2 Adsorption
2.1.4. Temperature Programmed Desorption (NH3–TPD) and (CO2–TPD)
2.2. Catalytic Conversion of C8 Ketone to C8 Alkenes and C8 Alkane in a Fixed Bed Reactor
2.2.1. Effect of Different Supported Catalysts on the Reaction of C8 Ketone
2.2.2. Effect of Reaction Temperature
2.2.3. Effect of H2/C8 Ketone Molar Ratio
2.2.4. Effect of Space Time
2.2.5. Catalyst Stability
3. Materials and Methods
3.1. Materials
3.2. Preparation of Supported Catalysts
3.3. Catalytic Reaction
3.4. Catalyst Characterization
3.4.1. X-Ray Diffraction (XRD)
3.4.2. Brunauer–Emmett–Teller (BET)
3.4.3. Transmission Electron Microscopy (TEM)
3.4.4. Temperature Programmed Desorption (NH3–TPD and CO2–TPD)
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Catalyst | Particle Size of Metal Species (nm) a | Particle Size of Metal Species (nm) b | Surface Area (m2/g) c | Total Pore Volume (cm3/g) c | Average Pore Dimeter (Å) c | NH3 Desorbed (mmol/g) d | CO2 Desorbed (mmol/g) d |
---|---|---|---|---|---|---|---|
Al2O3 | _ | _ | 225 | 0.698 | 124 | 0.16 | 0.039 |
1% Pt–Al2O3 | _ | ~7 | 195 | 0.633 | 130 | 0.44 | 0.114 |
1% Cu–Al2O3 | _ | ~8 | 193 | 0.64 | 133 | 0.21 | 0.066 |
20% Cu–Al2O3 (4 h) | 20 | ~18 | 168 | 0.513 | 122 | 0.54 | 0.155 |
20% Cu–Al2O3 (8 h) | 20.5 | ~18 | 168 | 0.532 | 126 | 0.4 | 0.115 |
Catalyst | Conv. of C8 Ketone (%) | Sel. for C8 Alkenes (%) | Sel. for C8 Alkane (%) | Others (%) a |
---|---|---|---|---|
20% Cu–Al2O3 | 100 | 45 | 54 | 1 |
1% Cu–Al2O3 | 51 | 66 | 10 | 24 |
1% Pt–Al2O3 | 100 | 0 | 98 | 2 |
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Al-Auda, Z.; Al-Atabi, H.; Li, X.; Thapa, P.; Hohn, K. Conversion of 5-Methyl-3-Heptanone to C8 Alkenes and Alkane over Bifunctional Catalysts. Catalysts 2019, 9, 845. https://doi.org/10.3390/catal9100845
Al-Auda Z, Al-Atabi H, Li X, Thapa P, Hohn K. Conversion of 5-Methyl-3-Heptanone to C8 Alkenes and Alkane over Bifunctional Catalysts. Catalysts. 2019; 9(10):845. https://doi.org/10.3390/catal9100845
Chicago/Turabian StyleAl-Auda, Zahraa, Hayder Al-Atabi, Xu Li, Prem Thapa, and Keith Hohn. 2019. "Conversion of 5-Methyl-3-Heptanone to C8 Alkenes and Alkane over Bifunctional Catalysts" Catalysts 9, no. 10: 845. https://doi.org/10.3390/catal9100845
APA StyleAl-Auda, Z., Al-Atabi, H., Li, X., Thapa, P., & Hohn, K. (2019). Conversion of 5-Methyl-3-Heptanone to C8 Alkenes and Alkane over Bifunctional Catalysts. Catalysts, 9(10), 845. https://doi.org/10.3390/catal9100845