An Efficient Support-Free Nanoporous Co Catalyst for Reverse Water–Gas Shift Reaction
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Catalyst Preparation
3.2. Catalyst Characterization
3.3. Activity Tests
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Catalysts | H2:CO2 | Temp. (°C) | WHSV (mL/g/h) | Conv. (%) (μmolCO2/g/s) | Sel. of CO (%) | Ref. |
---|---|---|---|---|---|---|
PtK/Mullite | 1:1 | 550 | 30,000 | 30.9 (52) | 99.2 | [23] |
Pd–In/SiO2 | 1:1 | 600 | 60,000 | 29.4 (44) | 100 | [24] |
K80-Pt/L | 1:1 | 400 | 30,000 | 13 (21.9) | 100 | [4] |
Au/CeO2 | 1:1 | 400 | 6000 | 21 (15.7) | 100 | [25] |
Mn–CeO2 | 4:1 | 400 | 60,000 | 8.1 (6.1) | 100 | [13] |
BaZr0.8Y0.16Zn0.04O3 | 1:1 | 600 | 2400 | 37.5 (5.6) | 97 | [12] |
Cu–Fe/SiO2 | 1:1 | 600 | 120,000 | 15 (112) | N/A | [26] |
Ni/nSiO2 | 4:1 | 400 | 400,000 | 25 (13) | 96 | [8] |
Co–CeO2 | 1:1 | 600 | 300,000 | 38 (711) | 100 | [9] |
Co–CeO2 | 4:1 | 400 | 60,000 | 35 (26.2) | 62 | [13] |
Mesoporous Co–CeO2 | 1:1 | 600 | 600,000 | 34.5 (1749) | 99.8 | [16] |
Fe2O3 | 1:1 | 510 | 120,000 | 28 (84) | 100 | [10] |
Cu/β-Mo2C | 2:1 | 600 | 300,000 | −(477) | 99.2 | [27] |
Co-400R | 1:1 | 400 | 300,000 | 12.3 (184) | 71.6 | This work |
Co-400R | 1:1 | 500 | 300,000 | 29.4 (440) | 80.9 | This work |
Co-400R | 1:1 | 600 | 300,000 | 45.8 (686) | 97.2 | This work |
Co-400R | 1:1 | 700 | 300,000 | 54.2 (812) | 99.9 | This work |
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Shen, Y.; Cao, Z.; Xiao, Z. An Efficient Support-Free Nanoporous Co Catalyst for Reverse Water–Gas Shift Reaction. Catalysts 2019, 9, 423. https://doi.org/10.3390/catal9050423
Shen Y, Cao Z, Xiao Z. An Efficient Support-Free Nanoporous Co Catalyst for Reverse Water–Gas Shift Reaction. Catalysts. 2019; 9(5):423. https://doi.org/10.3390/catal9050423
Chicago/Turabian StyleShen, Yongli, Zhen Cao, and Zihui Xiao. 2019. "An Efficient Support-Free Nanoporous Co Catalyst for Reverse Water–Gas Shift Reaction" Catalysts 9, no. 5: 423. https://doi.org/10.3390/catal9050423