Facile Synthesis of a Polycatenane Compound Based on Ag-triazole Complexes and Phosphomolybdic Acid for the Catalytic Epoxidation of Olefins with Molecular Oxygen
Abstract
:1. Introduction
2. Results and Discussions
2.1. Synthesis and Structure of the Catalysts
2.2. Catalytic Properties
3. Materials and Methods
3.1. Synthesis of the Catalysts
3.1.1. Synthesis of {[Ag2(trz)2] [Ag24(trz)18]}[PMo12O40]2 (1)
3.1.2. Reference Sample Ag-trz3
3.2. Materials and Methods
3.3. Catalyst Test
4. Conclusions
Supplementary Materials
Author Contributions
Acknowledgments
Conflicts of Interest
References
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Catalyst | Substrate | Product | Time (h) | Conversion (%) | Related work |
---|---|---|---|---|---|
1 | 3 | 96 | this work | ||
Ag-trz3 | 3 | 23 | this work | ||
CH3COOAg | 3 | 51 | this work | ||
PMA | 3 | 5 | this work | ||
1 b | 2.5 | 94 | this work | ||
POM@MOF c | 4 | 95 d | Ref-31 | ||
1 | 4 | 90 | this work | ||
Ag-trz3 | 4 | 15 | this work | ||
CH3COOAg | 4 | 37 | this work | ||
PMA | 4 | 11 | this work | ||
POM@MOFc | 7 | 73 d | Ref-31 |
Entry | Solvent | Temperature (°C) | Conversion (%) |
---|---|---|---|
1 | EtOH | 60 | 64 |
2 | CHCl3 | 60 | 62 |
3 | CH3CN | 25 | 81 |
4 | CH3CN | 35 | 89 |
5 | CH3CN | 40 | 96 |
6 | CH3CN | 60 | 98 |
Entry | Substrate | Temperature (°C) | Time (h) | Conversion (%) | Selectivity (%) | |
---|---|---|---|---|---|---|
Epoxidation | Others | |||||
1 | 35 | 3 | 96 | 84 | 16 | |
2 | 61 | 8 | 74 | 75 | 25 | |
3 | 61 | 6 | 82 | >99 | -- |
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Du, J.; Liu, X.; Zhang, J.; Liu, Y.; Zhu, E.; Che, G.; Jia, M. Facile Synthesis of a Polycatenane Compound Based on Ag-triazole Complexes and Phosphomolybdic Acid for the Catalytic Epoxidation of Olefins with Molecular Oxygen. Catalysts 2019, 9, 568. https://doi.org/10.3390/catal9070568
Du J, Liu X, Zhang J, Liu Y, Zhu E, Che G, Jia M. Facile Synthesis of a Polycatenane Compound Based on Ag-triazole Complexes and Phosphomolybdic Acid for the Catalytic Epoxidation of Olefins with Molecular Oxygen. Catalysts. 2019; 9(7):568. https://doi.org/10.3390/catal9070568
Chicago/Turabian StyleDu, Juan, Xinyu Liu, Jiaxin Zhang, Yucun Liu, Enwei Zhu, Guangbo Che, and Mingjun Jia. 2019. "Facile Synthesis of a Polycatenane Compound Based on Ag-triazole Complexes and Phosphomolybdic Acid for the Catalytic Epoxidation of Olefins with Molecular Oxygen" Catalysts 9, no. 7: 568. https://doi.org/10.3390/catal9070568