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Crystals, Volume 10, Issue 5

2020 May - 83 articles

Cover Story: Although gold nanoclusters represent the link species between atoms and nanoparticles and are the subject of current research, a high-resolution characterization is still missing. Here, we used the band forming experiment in analytical ultracentrifugation (AUC) to characterize the gold nanoclusters in the moment of their generation. The formation of different cluster species from the smallest, Au4, up to Au911 could be observed. Very stable clusters as Au55 appear in every experiment, and other cluster sizes appear more rarely. The extracted UV/Vis spectra could additionally be correlated to every cluster. These results present the characterization of the different nanocluster generations directly in the formation process of nanoparticles and therefore are a contribution to the understanding of their formation. View this paper
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Articles (83)

  • Article
  • Open Access
16 Citations
6,191 Views
12 Pages

Degradation-Induced Actuation in Oxidation-Responsive Liquid Crystal Elastomers

  • Mahjabeen Javed,
  • Seelay Tasmim,
  • Mustafa K. Abdelrahman,
  • Cedric P. Ambulo and
  • Taylor H. Ware

25 May 2020

Stimuli-responsive materials that exhibit a mechanical response to specific biological conditions are of considerable interest for responsive, implantable medical devices. Herein, we report the synthesis, processing and characterization of oxidation-...

  • Article
  • Open Access
16 Citations
4,145 Views
16 Pages

Dual Photonic–Phononic Crystal Slot Nanobeam with Gradient Cavity for Liquid Sensing

  • Nan-Nong Huang,
  • Yi-Cheng Chung,
  • Hsiao-Ting Chiu,
  • Jin-Chen Hsu,
  • Yu-Feng Lin,
  • Chien-Ting Kuo,
  • Yu-Wen Chang,
  • Chun-Yu Chen and
  • Tzy-Rong Lin

25 May 2020

A dual photonic–phononic crystal slot nanobeam with a gradient cavity for liquid sensing is proposed and analyzed using the finite-element method. Based on the photonic and phononic crystals with mode bandgaps, both optical and acoustic waves c...

  • Article
  • Open Access
14 Citations
5,270 Views
18 Pages

24 May 2020

We improved the three-dimensional (3D) crosstalk level of multi-view 3D displays using a lens array with small f-number, thereby facilitating a wide 3D viewing window. In particular, we designed a polarization-dependent-switching liquid crystal (LC)-...

  • Article
  • Open Access
3,594 Views
11 Pages

Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H2O)2] 4-dpds

  • Chih-Chieh Wang,
  • Zi-Ling Huang,
  • Yueh-Yi Tseng,
  • Gia-Bin Sheu,
  • Shih-I Lu,
  • Gene-Hsiang Lee and
  • Hwo-Shuenn Sheu

24 May 2020

A two-dimensional (2D) coordination polymer, [Co(4-dpds)(bdc)(H2O)2]·4-dpds (1) (4-dpds = 4,4′-dipyridyldusulfide and bdc2− = dianion of benzenedicarboxylic acid), has been synthesized and structurally determined by single-crystal...

  • Article
  • Open Access
4 Citations
5,315 Views
9 Pages

23 May 2020

The state-of-the-art silicon insulated-gate bipolar transistor (IGBT) features a trench gate, since it enhances the conductivity modulation. The SiC trench IGBT, however, faces the critical challenge of a high electric field in the gate oxide, which...

  • Article
  • Open Access
25 Citations
3,976 Views
15 Pages

Hot Deformation Behavior and Microstructure Characterization of an Al-Cu-Li-Mg-Ag Alloy

  • Lingfei Cao,
  • Bin Liao,
  • Xiaodong Wu,
  • Chaoyang Li,
  • Guangjie Huang and
  • Nanpu Cheng

22 May 2020

The flow behavior of an Al-Cu-Li-Mg-Ag alloy was studied by thermal simulation tests at deformation temperatures between 350 °C and 470 °C and strain rates between 0.01–10 s−1. The microstructures of the deformed materials were characterized by elect...

  • Article
  • Open Access
8 Citations
3,886 Views
9 Pages

Narrow/Broad-Band Absorption Based on Water-Hybrid Metamaterial

  • Bui Xuan Khuyen,
  • Vu Thi Hong Hanh,
  • Bui Son Tung,
  • Vu Dinh Lam,
  • Young Ju Kim,
  • YoungPak Lee,
  • Hua-Tian Tu and
  • Liang Yao Chen

22 May 2020

In this work, the possibility of a switchable metamaterial absorber is proposed to control absorption bandwidth in the WiMAX/LTE (worldwide interoperability for microwave access/long term evolution) band, by taking advantage of the low cost and myria...

  • Article
  • Open Access
5 Citations
3,926 Views
11 Pages

21 May 2020

The synthesis of YBa2Cu3O7−x (YBCO or 123) superconductor was carried out under hyper- and hypo-eutectic conditions with different ammonium compounds, i.e., ammonium nitrate, formate, acetate, carbonate, bicarbonate, and tetramethylammonium nitrate....

  • Article
  • Open Access
49 Citations
7,542 Views
11 Pages

Reduced Sintering Temperatures of Li+ Conductive Li1.3Al0.3Ti1.7(PO4)3 Ceramics

  • Katja Waetzig,
  • Christian Heubner and
  • Mihails Kusnezoff

20 May 2020

All-solid-state batteries (ASSB) are considered promising candidates for future energy storage and advanced electric mobility. When compared to conventional Li-ion batteries, the substitution of Li-ion conductive, flammable liquids by a solid electro...

  • Article
  • Open Access
6 Citations
2,931 Views
12 Pages

20 May 2020

Rare-earth-doped SiAlON and Si3N4 materials from aluminosilicate starting materials have been reported to show superior photoluminescence (PL) properties. Three different starting materials, including pulverized coal furnace fly ash, diatomite and ra...

  • Article
  • Open Access
7 Citations
3,905 Views
11 Pages

20 May 2020

(Sc,Ti)Fe2 Laves phases present a relatively unique case of first-order ferro-ferromagnetic transition originating from an instability of the Fe moment. In addition to large magnetoelastic effects making them potential negative thermal expansion mate...

  • Article
  • Open Access
7 Citations
4,735 Views
19 Pages

20 May 2020

Compression tests at low strains were performed to theoretically analyze the effects of anisotropic elasticity, misorientation, grain boundary (GB) stiffness, interfacial dislocations, free surfaces, and critical force on dislocation pile-ups in micr...

  • Article
  • Open Access
16 Citations
3,876 Views
16 Pages

(Ti,Cr)C-Based Cermets with Varied Nicr Binder Content via Elemental SHS for Perspective Cutting Tools

  • Stepan Vorotilo,
  • Philipp V. Kiryukhantsev-Korneev,
  • Boris S. Seplyarskii,
  • Roman A. Kochetkov,
  • Nail I. Abzalov,
  • Ivan D. Kovalev,
  • Tatyana G. Lisina and
  • Alexander A. Zaitsev

20 May 2020

The effects of granulation of reactive mixtures Ti-Cr-C and Ti-Cr-C-Ni on the combustion temperature and velocity, as well as phase composition and mechanical properties (crushing ability) of combustion products, were studied. Granulation was associa...

  • Article
  • Open Access
6 Citations
3,923 Views
15 Pages

20 May 2020

The isoflavone compound 3-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-6-methoxy-4H-chromen-4-one (6) was prepared and structurally characterized using NMR, mass spectrum and X-ray crystallography. Compound 6, C18H14O5, was crystallized in the monoclinic sp...

  • Article
  • Open Access
45 Citations
6,280 Views
13 Pages

19 May 2020

Poly acrylic acid (PAA) and polyepoxysuccinic acid (PESA) were investigated as scale inhibitors. The static experiments certified that PAA was superior to PESA for the inhibition of calcium carbonate in the low molecular weight range. The X-ray diffr...

  • Article
  • Open Access
8 Citations
3,833 Views
19 Pages

Role of Potassium Substitution in the Magnetic Properties and Magnetocaloric Effect in La0.8−xKxBa0.05Sr0.15MnO3 (0 ≤ x ≤ 0.20)

  • Dhawud Sabilur Razaq,
  • Budhy Kurniawan,
  • Dicky Rezky Munazat,
  • Kazumitsu Watanabe and
  • Hidekazu Tanaka

19 May 2020

The magnetic and magnetocaloric effects of potassium-substituted La0.8−xKxBa0.05Sr0.15MnO3 (0 ≤ x ≤ 0.20) manganite were explored. The samples in polycrystalline form were synthesized by the sol–gel method, with a final sintering te...

  • Review
  • Open Access
8 Citations
5,368 Views
16 Pages

17 May 2020

Laser crystallization of a-Si film on insulating substrate is a promising technology to fabricate three-dimensional integrations (3D ICs), flat panel displays (FPDs), or flexible electronics, because the crystallization can be performed on room tempe...

  • Article
  • Open Access
14 Citations
5,221 Views
15 Pages

16 May 2020

β -aescin is a versatile biosurfactant extracted from the seeds of the horse chestnut tree Aesculus hippocastanum with anti-cancer potential and is commonly used in the food and pharmaceutical and cosmetic industries. In this article, wide-...

  • Article
  • Open Access
30 Citations
7,024 Views
22 Pages

Investigation of Total Phenolic Content and Antioxidant Activities of Spruce Bark Extracts Isolated by Deep Eutectic Solvents

  • Michal Jablonsky,
  • Veronika Majova,
  • Petra Strizincova,
  • Jozef Sima and
  • Jozef Jablonsky

16 May 2020

Extracts from spruce bark obtained using different deep eutectic solvents were screened for their total phenolic content (TPC) and antioxidant activities. Water containing choline chloride-based deep eutectic solvents (DESs) with lactic acid and 1,3-...

  • Article
  • Open Access
14 Citations
4,539 Views
17 Pages

16 May 2020

Lightweight, high-strength metal matrix composites have attracted considerable interest because of their attractive physical, mechanical and tribological properties. Moreover, they may offer distinct advantages due to good strength and wear resistanc...

  • Review
  • Open Access
13 Citations
5,286 Views
9 Pages

16 May 2020

Lipase B from Candida antarctica (CAL-B) belongs to the family of α/β-hydrolases, and is one from the most extensively used biocatalysts in the kinetic resolution of amines and alcohols in a racemic state, in the desymmetrization of diacet...

  • Article
  • Open Access
32 Citations
6,855 Views
13 Pages

Characterization of Silver Nanoparticles Obtained by a Green Route and Their Evaluation in the Bacterium of Pseudomonas aeruginosa

  • Juan Carlos Martínez Espinosa,
  • Raúl Carrera Cerritos,
  • Maria Antonieta Ramírez Morales,
  • Karla Paola Sánchez Guerrero,
  • Rocio Alejandra Silva Contreras and
  • Juan H. Macías

15 May 2020

Metal nanoparticles are widely used in different areas such as biotechnology and biomedicine, for example in drug delivery, imaging and control of bacterial growth. The antimicrobial effect of silver has been identified as an alternative approach to...

  • Article
  • Open Access
10 Citations
3,574 Views
12 Pages

Luminescence Behavior of GdVO4: Tb Nanocrystals in Silica Glass-Ceramics

  • Shuai Han,
  • Yiting Tao,
  • Ying Du,
  • Sasa Yan,
  • Yanping Chen and
  • Danping Chen

15 May 2020

Glass ceramics with GdVO4: Tb nanocrystals impregnated in the highly transparent silica glass were prepared by the porous glass and sintering process and confirmed by XRD, Raman spectrum, and TEM. Spectral analysis shows that there are multifarious e...

  • Article
  • Open Access
31 Citations
4,875 Views
14 Pages

15 May 2020

The Bi4I16·4(C6H9N2) 2(H2O) compound was synthesized by slow evaporation at room temperature. It exhibits a zero-dimensional (0D) tetrameric structure, comprising [Bi4I16]4− distorted octahedra, with strong I⋯I interactions among adjacen...

  • Article
  • Open Access
35 Citations
6,269 Views
12 Pages

The Effect of Printing Parameters on Electrical Conductivity and Mechanical Properties of PLA and ABS Based Carbon Composites in Additive Manufacturing of Upper Limb Prosthetics

  • Attila Pentek,
  • Miklos Nyitrai,
  • Adam Schiffer,
  • Hajnalka Abraham,
  • Matyas Bene,
  • Emese Molnar,
  • Roland Told and
  • Peter Maroti

15 May 2020

Additive manufacturing technologies are dynamically developing, strongly affecting almost all fields of industry and medicine. The appearance of electrically conductive polymers has had a great impact on the prototyping process of different electrica...

  • Article
  • Open Access
19 Citations
4,667 Views
11 Pages

15 May 2020

The LaFe1−xZrxO3 (x = 0.01, 0.05) ceramics were prepared by sol-gel and annealing method and studied by XRD, Raman scattering analysis, SEM, and impedance spectroscopy method. The crystal structure and phonon characteristics analysis revealed t...

  • Article
  • Open Access
16 Citations
3,987 Views
14 Pages

Enhanced Photocatalytic and Antibacterial Activities of K2Ti6O13 Nanowires Induced by Copper Doping

  • Weiwei Zhang,
  • Xin Wang,
  • Yuanhui Ma,
  • Haoran Wang,
  • Yumin Qi and
  • Chunxiang Cui

15 May 2020

Cu-doped K2Ti6O13 (Cu–KTO) nanowires were prepared using a combination of sol–gel and hydrothermal methods to improve the photocatalytic and antibacterial performance of K2Ti6O13 (KTO) nanowires. The Cu–KTO nanowires maintained the...

  • Article
  • Open Access
5 Citations
4,351 Views
10 Pages

14 May 2020

In liquid crystal applications, boundary conditions are essential to ensuring suitable bulk molecular orientation and a deterministic response to external fields. Be it confinement to a droplet or a shell, a glass plate, or an interface with air or a...

  • Article
  • Open Access
14 Citations
4,572 Views
15 Pages

Systematic Investigations on Continuous Fluidized Bed Crystallization for Chiral Separation

  • Erik Temmel,
  • Jonathan Gänsch,
  • Andreas Seidel-Morgenstern and
  • Heike Lorenz

14 May 2020

A recently developed continuous enantioseparation process utilizing two coupled fluidized bed crystallizers is systematically investigated to identify essential correlations between different operation parameters and the corresponding process perform...

  • Article
  • Open Access
4 Citations
4,038 Views
12 Pages

12 May 2020

The article presents the mechanical properties of the austenitic stainless steel X5CrMnNiMoN16-4-4 after deformation by cold rolling and subsequent short-term tempering (deformation and partitioning (D&P) treatment). Tensile strengths of 1700&nda...

  • Article
  • Open Access
5 Citations
3,399 Views
11 Pages

11 May 2020

anhydride-poly(ethylene glycol) co-polymer (A-PEGCP) has been synthesized from maleic anhydride, poly(ethylene glycol) and bisphenol-A diglycidyl ether without using any organic solvent. The thin films produced from A-PEGCP solution were spin-coated...

  • Article
  • Open Access
4 Citations
3,413 Views
16 Pages

Novel Cd (II) Coordination Polymers Afforded with EDTA or Trans-1,2-Cdta Chelators and Imidazole, Adenine, or 9-(2-Hydroxyethyl) Adenine Coligands

  • Jeannette Carolina Belmont-Sánchez,
  • María Eugenia García-Rubiño,
  • Antonio Frontera,
  • Antonio Matilla-Hernández,
  • Alfonso Castiñeiras and
  • Juan Niclós-Gutiérrez

11 May 2020

Three mixed-ligands of Cd(II) coordination polymers were unintentionally obtained: {[Cd(µ3-EDTA)(Him)·Cd(Him)(H2O)2]·H2O}n (1), {[Cd(µ4-CDTA)(Hade)·Cd(Hade)2]}n (2), and {[Cd(µ3-EDTA)(H2O)·Cd(H9heade)(H2O...

  • Article
  • Open Access
26 Citations
3,587 Views
19 Pages

Silver(I) and Copper(I) Complexation with Decachloro-Closo-Decaborate Anion

  • Varvara V. Avdeeva,
  • Grigoriy A. Buzanov,
  • Elena A. Malinina,
  • Nikolay T. Kuznetsov and
  • Anna V. Vologzhanina

10 May 2020

A series of complexation reactions of silver(I) and copper(I) in the presence of a polyhedral weakly coordinating [B10Cl10]2− anion has been carried out. The effect of the solvent and the presence of Ph3P on the composition and structure of the...

  • Article
  • Open Access
55 Citations
5,900 Views
24 Pages

Enhancement of ZnO Nanorods Properties Using Modified Chemical Bath Deposition Method: Effect of Precursor Concentration

  • Ahmed Fattah Abdulrahman,
  • Sabah Mohammed Ahmed,
  • Naser Mahmoud Ahmed and
  • Munirah Abullah Almessiere

9 May 2020

In this study, the effects of different precursor concentrations on the growth and characteristics properties of the zinc oxide (ZnO) nanorods (NRs) synthesized by using modified and conventional chemical bath deposition (CBD) methods were investigat...

  • Article
  • Open Access
24 Citations
3,808 Views
14 Pages

Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I/I2 Ternary System

  • Matteo Savastano,
  • Carla Bazzicalupi,
  • Cristina Gellini and
  • Antonio Bianchi

9 May 2020

The Stoddart’s blue box (BB) (cyclobis(paraquat-p-phenylene))/iodide binary system was recently demonstrated to give rise to porous three-dimensional networks which can hardly be classified as common XOF-type materials (X = M, C, S, i.e., metal...

  • Article
  • Open Access
4 Citations
4,160 Views
13 Pages

9 May 2020

As the luminescence from conventional organic luminophores is typically quenched in constrained environments, the aggregation-induced emission (AIE) phenomenon is of interest for the development of materials that exhibit strong luminescence in conden...

  • Article
  • Open Access
11 Citations
3,450 Views
18 Pages

Enhanced Mechanical Properties of Surface Treated AZ31 Reinforced Polymer Composites

  • Muhammad Shoaib Butt,
  • Adnan Maqbool,
  • Malik Adeel Umer,
  • Mohsin Saleem,
  • Rizwan Ahmed Malik,
  • Ibrahim M. Alarifi and
  • Hussein Alrobei

8 May 2020

To enhance the potential application of naturally biodegradable polylactic acid (PLA)-based composites reinforced with magnesium alloy, anodized coatings between Mg and PLA were fabricated on AZ31 magnesium alloy rods. After anodizing (AO) at four di...

  • Feature Paper
  • Article
  • Open Access
11 Citations
6,042 Views
10 Pages

8 May 2020

Nowadays, displays are ubiquitous in our daily lives. Long-time exposure to a display’s unnatural light could influence the user’s circadian rhythm, especially at night. Here, we propose a four-color micro-light-emitting diode (LED) displ...

  • Article
  • Open Access
9 Citations
4,482 Views
14 Pages

Formation of Nanoclusters in Gold Nucleation

  • Cornelia M. Schneider and
  • Helmut Cölfen

8 May 2020

Gold nanoclusters consisting of a specific atom number have gained popularity in research in recent years due to their outstanding properties. Due to their molecule-like behavior, their properties depend strongly on their size. Although they represen...

  • Article
  • Open Access
10 Citations
4,319 Views
12 Pages

Optimization of Ultra-Thin Pulsed-DC Magnetron Sputtered Aluminum Films for the Technology of Hyperbolic Metamaterials

  • Robert Mroczyński,
  • Daniel Iwanicki,
  • Bartosz Fetliński,
  • Monika Ożga,
  • Michał Świniarski,
  • Arkadiusz Gertych,
  • Mariusz Zdrojek and
  • Marek Godlewski

8 May 2020

The future applications of hyperbolic metamaterials demand stacks of materials with alternative ultra-thin conductive/dielectric films with good homogeneity of the thickness and reduced roughness level. In this work, the technology of pulsed-DC magne...

  • Article
  • Open Access
8 Citations
3,259 Views
13 Pages

Scintillation and Energy-Storage Properties of Micro-Pulling-Down Grown Crystals of Sc3+- and La3+-Doped YAlO3 Perovskite

  • Wojciech Gieszczyk,
  • Anna Mrozik,
  • Paweł Bilski,
  • Vitaliy Vistovskyy,
  • Anatoliy Voloshinovskii,
  • Kazimierz Paprocki,
  • Tetiana Zorenko and
  • Yuriy Zorenko

8 May 2020

The scintillation and energy-storage properties of YAlO3 (YAP) crystals doped with Sc3+ and La3+ isoelectronic dopants were investigated in this work. The YAP:Sc and YAP:La crystals were grown from the melt with a nominal Sc and La content in the 0.2...

  • Article
  • Open Access
1 Citations
3,755 Views
9 Pages

Sol-Gel Coatings for Subaquatic Self-Cleaning Windows

  • Andrew I. M. Greer,
  • David Moodie,
  • Graham Kerr and
  • Nikolaj Gadegaard

7 May 2020

Self-cleaning windows are well known for their ability to function with airborne pollutants, but there is a growing industry for semi-permanent subaquatic optical devices, where the performance of such windows should be considered. Here sol-gel techn...

  • Article
  • Open Access
7 Citations
4,969 Views
10 Pages

Crystallization of Diamond from Melts of Europium Salts

  • Yuri M. Borzdov,
  • Alexander F. Khokhryakov,
  • Igor N. Kupriyanov,
  • Denis V. Nechaev and
  • Yuri N. Palyanov

7 May 2020

Diamond crystallization in melts of europium salts (Eu2(C2O4)3·10H2O, Eu2(CO3)3·3H2O, EuCl3, EuF3, EuF2) at 7.8 GPa and in a temperature range of 1800–2000 °C was studied for the first time. Diamond growth on seed crystals was...

  • Article
  • Open Access
3,230 Views
12 Pages

7 May 2020

In this article, we report on the synthesis and characterization of crown-ether appended hexaazatrinaphthylene derivatives with two alkoxy chains. The complexation of a derivative having shorter alkoxy chains with metal ions, such as NaI and KI, prom...

  • Feature Paper
  • Article
  • Open Access
13 Citations
4,116 Views
12 Pages

Effect of HPHT Treatment on Spectroscopic Features of Natural Type Ib-IaA Diamonds Containing Y Centers

  • Igor N. Kupriyanov,
  • Yuri N. Palyanov,
  • Alexander A. Kalinin and
  • Vladislav S. Shatsky

7 May 2020

In this paper, we report a spectroscopic study of natural type Ib-IaA diamonds containing Y centers subjected to high-pressure high-temperature treatment at 7–7.5 GPa and 1700–2200 °C. Diamond samples showing the Y centers as the domi...

  • Article
  • Open Access
6 Citations
2,783 Views
10 Pages

7 May 2020

The cocrystal formed by hexamethylbenzene (HMB) with 1,3-diiodotetrafluorobenzene (1,3-DITFB) was first synthesized and found to have an unexpected sandwiched-layer structure with alternating HMB layers and 1,3-DITFB layers. To better understand the...

  • Article
  • Open Access
9 Citations
4,564 Views
17 Pages

7 May 2020

The kinetic parameters of stochastic primary nucleation were estimated for the batch-cooling crystallization of L-arginine. It is difficult for process analytical tools to detect the first nucleus. In this study, the latent period for the total numbe...

  • Article
  • Open Access
9 Citations
9,284 Views
8 Pages

6 May 2020

We present a free-standing terahertz metasurface supercell that consists of four complementary mirrored asymmetric split-rectangular resonators. The quality factor of the excited resonance of this supercell has been significantly improved by 250% whe...

  • Article
  • Open Access
7 Citations
2,984 Views
17 Pages

Deformation Induced Soft and Hard Lath Packets Enhance Ductility in Martensitic Steels

  • Éva Ódor,
  • Bertalan Jóni,
  • Gábor Ribárik,
  • Nguyen Quang Chinh,
  • Tamás Ungár and
  • Péter J. Szabó

6 May 2020

Martensitic steels are widely used structural materials with outstanding mechanical properties. Their high strength is provided by the non-diffusional phase transformation of fcc γ into thin lamellar bcc plates during fast cooling. Coherency st...

  • Article
  • Open Access
3 Citations
2,687 Views
13 Pages

6 May 2020

Within the scope of the comprehensive elucidation of the entire process chain for the production of highly functional thin films made of semiconducting aluminum-doped zinc oxide ( A Z O ) nanocrystals, this work deals with the detailed investig...

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Crystals - ISSN 2073-4352