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Crystals, Volume 7, Issue 8

2017 August - 27 articles

Cover Story: Graphene, a monoatomic layer of carbon atoms arranged on a honeycomb lattice, exhibits extraordinary electronic properties resulting from its peculiar band structure. The conductance and valence band touch each other conically at the corners of the hexagonal Brillouin zone leading to a linear dispersion relation and, thus, the relativistic phenomena exhibited by graphene. With increasing energy the dispersion relation changes from linear to quadratic. This transition takes place at its saddle points, which correspond to the van Hove singularities. View Paper here
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Articles (27)

  • Article
  • Open Access
6 Citations
7,782 Views
10 Pages

20 August 2017

Copper wires have been attracting much attention for Large Scale Integration (LSI) bonding because of their excellent mechanical and electrical properties, in addition to their low material cost. The ends of these wires are usually joined to pads or...

  • Article
  • Open Access
5 Citations
5,610 Views
10 Pages

Mechanical Anisotropy in Austenitic NiMnGa Alloy: Nanoindentation Studies

  • Ashwin Jayaraman,
  • M. S. R. N. Kiran and
  • Upadrasta Ramamurty

17 August 2017

Abstract: Mechanical anisotropy in an austenitic ferromagnetic shape memory alloy (SMA), Ni50Mn26.25Ga23.75, is investigated along (010), (120), (121), (231) and (232) using nanoindentation. While (010) exhibits the highest reduced modulus, Er, and h...

  • Review
  • Open Access
6 Citations
7,875 Views
13 Pages

Structural Basis of DEAH/RHA Helicase Activity

  • Michael C. Chen and
  • Adrian R. Ferré-D’Amaré

15 August 2017

DEAH/RHA helicases are members of a large group of proteins collectively termed DExH-box, which also include Ski2-like and NS3/NPH-II helicases. By binding and remodeling DNA and RNA, DEAH/RHA helicases play critical roles in many cellular processes...

  • Article
  • Open Access
28 Citations
9,361 Views
9 Pages

Interfacial Kinetics of Efficient Perovskite Solar Cells

  • Pankaj Yadav,
  • Daniel Prochowicz,
  • Michael Saliba,
  • Pablo P. Boix,
  • Shaik M. Zakeeruddin and
  • Michael Grätzel

13 August 2017

Perovskite solar cells (PSCs) have immense potential for high power conversion efficiency with an ease of fabrication procedure. The fundamental understanding of interfacial kinetics in PSCs is crucial for further improving of their photovoltaic perf...

  • Article
  • Open Access
35 Citations
5,298 Views
15 Pages

9 August 2017

Two new Co(II) complexes, [{Co(L)}2{Co(Pic)2(CH3OH)2}] (1) and [{CoL(μ-OAc)}2Co] (2), where H2L = 2,2′-[Ethylenedioxybis(nitrilomethylidyne)]dinaphthol, were designed, synthesized and characterized by elemental analysis, FT-IR spectra, UV-Vis spectra...

  • Article
  • Open Access
22 Citations
5,814 Views
11 Pages

Crystal Growth and Luminescence Properties of Dy3+ and Ge4+ Co-Doped Bi4Si3O12 Single Crystals for High Power Warm White LED

  • Tian Tian,
  • Haiwei Feng,
  • Yan Zhang,
  • Ding Zhou,
  • Hui Shen,
  • Hongchao Wang and
  • Jiayue Xu

9 August 2017

Φ1 inch Dy3+ and Ge4+ co-doped bismuth silicate (Bi4Si3O12, BSO) single crystals with the length of 80–100 mm were successfully grown by Bridgman method. They are transparent, free of cracks and inclusions. The white residual at the top parts of BSO...

  • Article
  • Open Access
6 Citations
7,110 Views
18 Pages

9 August 2017

This paper presents a simple behavioral model with experimentally extracted parameters for packaged cascode gallium nitride (GaN) field-effect transistors (FETs). This study combined a level-1 metal–oxide–semiconductor field-effect transistor (MOSFET...

  • Article
  • Open Access
5 Citations
4,770 Views
10 Pages

9 August 2017

Two s-shaped polyaromatic dibenzo[c,l]chrysene derivatives have been synthesized by a two-step process, via. The Wittig reaction, followed by iodine, promoted photocyclization. These molecules have been characterized by 1H NMR, FAB-MS, and elemental...

  • Article
  • Open Access
4 Citations
5,771 Views
15 Pages

8 August 2017

Iron oxide nanoparticles are widely prevalent in our aqueous environment (e.g., streams, seawater, hydrothermal vents). Their aggregation and crystal growth depend on their chemical surroundings, for instance just a change in pH or salt concentration...

  • Article
  • Open Access
16 Citations
6,959 Views
17 Pages

7 August 2017

The localization properties of the wave functions of vibrations in two-dimensional (2D) crystals are studied numerically for square and hexagonal lattices within the framework of an algebraic model. The wave functions of 2D lattices have remarkable l...

  • Article
  • Open Access
9 Citations
6,703 Views
10 Pages

Precipitant-Free Crystallization of Protein Molecules Induced by Incision on Substrate

  • Anindita Sengupta Ghatak,
  • Gaurav Rawal and
  • Animangsu Ghatak

5 August 2017

Nucleation of protein crystals has been shown to be facilitated by substrates decorated with both nano- to micro-scale hierarchical undulations and spatially varying surface potential. In fact, on such surfaces, several proteins were found to crystal...

  • Review
  • Open Access
45 Citations
11,144 Views
19 Pages

4 August 2017

In this mini-review, we summarize the evidences of lamellar twisting in the birefringent banded polymer spherulites demonstrated by various characterization techniques, such as polarized optical microscopy, real-time atomic force microscopy, micro-fo...

  • Article
  • Open Access
7 Citations
12,365 Views
8 Pages

4 August 2017

Extracting AlCl3·6H2O from acid leaching solution through crystallization is one of the key processes to extracting aluminum from fly ash, coal gangue and other industrial solid wastes. However, the obtained products usually have low purity and a key...

  • Article
  • Open Access
6 Citations
6,077 Views
29 Pages

A Novel Approach to Data Collection for Difficult Structures: Data Management for Large Numbers of Crystals with the BLEND Software

  • Anastasia Mylona,
  • Stephen Carr,
  • Pierre Aller,
  • Isabel Moraes,
  • Richard Treisman,
  • Gwyndaf Evans and
  • James Foadi

4 August 2017

The present article describes how to use the computer program BLEND to help assemble complete datasets for the solution of macromolecular structures, starting from partial or complete datasets, derived from data collection from multiple crystals. The...

  • Article
  • Open Access
24 Citations
10,801 Views
16 Pages

4 August 2017

A continuum theory for high temperature creep of polycrystalline solids is developed. It includes the relevant deformation mechanisms for diffusional and dislocation creep: elasticity with eigenstrains resulting from vacancy diffusion, dislocation cl...

  • Article
  • Open Access
11 Citations
6,077 Views
15 Pages

1 August 2017

The influence of in-plane residual stress on Hertzian nanoindentation for single-crystal copper thin film is investigated using molecular dynamics simulations (MD). It is found that: (i) the yield strength of incipient plasticity increases with compr...

  • Article
  • Open Access
2 Citations
4,449 Views
8 Pages

31 July 2017

Pr9.33(SiO4)6O2 crystals have been grown by the Cz-method for the first time for near UV–visible Faraday rotation applications. Rietveld refinement of XRD data demonstrates that the compound crystallizes in the oxyapatite structure with space group P...

  • Communication
  • Open Access
2 Citations
6,696 Views
4 Pages

Self-Assembled Microwires of Terephthalic Acid and Melamine

  • Hong Wang,
  • Arben Kojtari,
  • Xiaohe Xu and
  • Hai-Feng Ji

31 July 2017

Self-assembled microwires of terephthalic acid (TPA) and melamine are prepared through the evaporation of water in a solution mixture of TPA and melamine. The microwires were characterized by using scanning electron microscope (SEM), attenuated total...

  • Article
  • Open Access
6 Citations
7,506 Views
12 Pages

The Internal Structure of Yellow Cuboid Diamonds from Alluvial Placers of the Northeastern Siberian Platform

  • Alexey Ragozin,
  • Dmitry Zedgenizov,
  • Konstantin Kuper,
  • Viktoria Kalinina and
  • Alexey Zemnukhov

31 July 2017

Yellow cuboid diamonds are commonly found in diamondiferous alluvial placers of the Northeastern Siberian platform. The internal structure of these diamonds have been studied by optical microscopy, X-Ray topography (XRT) and electron backscatter diff...

  • Review
  • Open Access
46 Citations
11,027 Views
15 Pages

31 July 2017

Diamond is a unique mineral widely used in diverse fields due to its remarkable properties. The development of synthesis technology made it possible to create diamond-based semiconductor devices. In addition, doped diamond can be used as single photo...

  • Article
  • Open Access
37 Citations
8,686 Views
9 Pages

31 July 2017

The results of a high-resolution Raman scattering study of a diamond crystal with a high content of single substitutional nitrogen impurities (550 ppm) in the temperature range from 50 to 673 K are presented and compared with the data for defect-free...

  • Article
  • Open Access
3 Citations
4,468 Views
12 Pages

30 July 2017

Continuum dislocation dynamics (CDD) is a single crystal strain gradient plasticity theory based exclusively on the evolution of the dislocation state. Recently, we derived a constitutive theory for the average dislocation velocity in CDD in a phase...

  • Review
  • Open Access
25 Citations
6,742 Views
19 Pages

29 July 2017

The determination of the molecular structures of metallacarboranes by X-ray diffraction remains critical to the development of the field, in some cases being the only viable way in which the overall architecture and the isomeric form of the molecule...

  • Review
  • Open Access
18 Citations
10,684 Views
15 Pages

Ferroelectricity in Simple Binary Crystals

  • Akira Onodera and
  • Masaki Takesada

28 July 2017

The origin of ferroelectricity in doped binary crystals, Pb1−xGexTe, Cd1−xZnxTe, Zn1−xLixO, and Hf1−xZrxO2 is discussed, while no binary ferroelectrics have been reported except for two crystals, HCl and HBr. The ferroelectricity is induced only in d...

  • Article
  • Open Access
16 Citations
6,417 Views
11 Pages

Non-Destructive In Situ Study of Plastic Deformations in Diamonds: X-ray Diffraction Topography and µFTIR Mapping of Two Super Deep Diamond Crystals from São Luiz (Juina, Brazil)

  • Giovanna Agrosì,
  • Gioacchino Tempesta,
  • Giancarlo Della Ventura,
  • Mariangela Cestelli Guidi,
  • Mark Hutchison,
  • Paolo Nimis and
  • Fabrizio Nestola

28 July 2017

Diamonds from Juina, Brazil, are well-known examples of superdeep diamond crystals formed under sublithospheric conditions and evidence would indicate their origins lie as deep as the Earth’s mantle transition zone and the Lower Mantle. Detailed char...

  • Review
  • Open Access
37 Citations
9,438 Views
20 Pages

Light-Triggered Formation of Surface Topographies in Azo Polymers

  • Matthew Hendrikx,
  • Albertus P. H. J. Schenning,
  • Michael G. Debije and
  • Dirk J. Broer

26 July 2017

Properties such as friction, wettability and visual impact of polymer coatings are influenced by the surface topography. Therefore, control of the surface structure is of eminent importance to tuning its function. Photochromic azobenzene-containing p...

  • Article
  • Open Access
12 Citations
4,890 Views
9 Pages

Lattice Site of Rare-Earth Ions in Stoichiometric Lithium Niobate Probed by OH Vibrational Spectroscopy

  • László Kovács,
  • Laura Kocsor,
  • Zsuzsanna Szaller,
  • Ivett Hajdara,
  • Gabriella Dravecz,
  • Krisztián Lengyel and
  • Gábor Corradi

25 July 2017

Rare-earth (RE = Er3+, Nd3+, or Yb3+) ion-doped stoichiometric LiNbO3 crystals were grown by the Czochralski and the high-temperature top-seeded solution growth methods. For the 0.22–0.87 mol% concentration range of the RE oxides in the melt/solution...

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Crystals - ISSN 2073-4352