Quadratic Non-Linear Optical Properties of the poly(2,5-bis(but-2-ynyloxy) Benzoate Containing the 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethanol) Chromophore
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis of Polymer and Total Material Characterization
2.2. Morphological and Spectroscopic Film Characterizations
2.3. Quadratic SHG/NLO-Photophysical Characterizations
3. Experimental Section
3.1. Materials and Instrumentation
3.2. Synthesis and Characterization of the Monomer and then, the Polymer
3.2.1. 2-(ethyl(4-iodophenyl)amino)ethanol (2)
3.2.2. 2-(ethyl(4-((trimethylsilyl)ethynyl)phenyl)amino)ethanol (4)
3.2.3. 2-(ethyl(4-ethynylphenyl)amino)ethanol (5)
3.2.4. 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethanol (7)
3.2.5. 2.,5-bis(prop-2-ynyloxy)benzoyl chloride (8)
3.2.6. 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethyl-2,5-bis(but-2-ynyloxy)benzoate (9)
3.2.7. poly(2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethyl2,5-bis(but-2-ynyloxy) benzoate) (10)
3.3. Thin Film Deposition and Corona Poling Process
3.4. Morphological AFM-Film Inspections
3.5. NLO/SHG Measurements
3.6. EPR Spectroscopy
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Castañón-Alonso, S.L.; Morales-Saavedra, O.G.; Almaraz-Girón, M.A.; Báez-Pimiento, S.; Islas-Jácome, A.; Rocha-Ramírez, L.M.; Domínguez-Ortiz, A.; Esparza-Schulz, M.; Romero-Galarza, A.; Hernández-Rojas, M.E. Quadratic Non-Linear Optical Properties of the poly(2,5-bis(but-2-ynyloxy) Benzoate Containing the 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethanol) Chromophore. Polymers 2020, 12, 241. https://doi.org/10.3390/polym12010241
Castañón-Alonso SL, Morales-Saavedra OG, Almaraz-Girón MA, Báez-Pimiento S, Islas-Jácome A, Rocha-Ramírez LM, Domínguez-Ortiz A, Esparza-Schulz M, Romero-Galarza A, Hernández-Rojas ME. Quadratic Non-Linear Optical Properties of the poly(2,5-bis(but-2-ynyloxy) Benzoate Containing the 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethanol) Chromophore. Polymers. 2020; 12(1):241. https://doi.org/10.3390/polym12010241
Chicago/Turabian StyleCastañón-Alonso, Sandra L., Omar G. Morales-Saavedra, Marco A. Almaraz-Girón, Sandro Báez-Pimiento, Alejandro Islas-Jácome, L. M. Rocha-Ramírez, Armando Domínguez-Ortiz, Marcos Esparza-Schulz, Adolfo Romero-Galarza, and María E. Hernández-Rojas. 2020. "Quadratic Non-Linear Optical Properties of the poly(2,5-bis(but-2-ynyloxy) Benzoate Containing the 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethanol) Chromophore" Polymers 12, no. 1: 241. https://doi.org/10.3390/polym12010241