Calcined Co(II)-Triethylenetetramine, Co(II)- Polyaniline-Thiourea as the Cathode Catalyst of Proton Exchanged Membrane Fuel Cell
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Preparation of CoNxC Catalyst
2.3. Fourier-Transform Infrared Spectroscopy (FTIR)
2.4. X-ray Photoelectron Spectroscopy (XPS)
2.5. WXRD (Wide Angle X-ray Diffraction: Powder X-ray Diffraction)
2.6. Raman Spectroscopy
2.7. Scanning Electronic Microscopy (SEM)
2.8. Electrochemical Characterization
2.8.1. Linear Sweep Voltammetry (LSV)
2.8.2. Membrane Electrode Assemblies (MEA) Preparation
2.9. Single-Cell Performance Testing
3. Results and Discussion
3.1. Fourier-Transform Infrared Spectroscopy (FTIR) Spectra
3.2. X-ray Photoelectron Spectroscopy (XPS)
3.3. Wide Angle X-ray Diffraction: Powder X-ray Diffraction (WXRD)
3.4. Raman Spectroscopy
3.5. Scanning Electronic Microscopy (SEM)
3.6. Oxygen Reduction Reaction (ORR) Performance
Linear Sweep Voltammetry (LSV) Curves
3.7. Single Cell Testing
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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I100/I002 (a) | ID/IG (b) | |
---|---|---|
Co–C | 0.459 | 0.970 |
CoNxC | 0.432 | 0.973 |
CoSyC | 0.427 | 0.978 |
CoNxSyC | 0.412 | 0.987 |
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Huang, W.-Y.; Jheng, L.-C.; Hsieh, T.-H.; Ho, K.-S.; Wang, Y.-Z.; Gao, Y.-J.; Tseng, P.-H. Calcined Co(II)-Triethylenetetramine, Co(II)- Polyaniline-Thiourea as the Cathode Catalyst of Proton Exchanged Membrane Fuel Cell. Polymers 2020, 12, 3070. https://doi.org/10.3390/polym12123070
Huang W-Y, Jheng L-C, Hsieh T-H, Ho K-S, Wang Y-Z, Gao Y-J, Tseng P-H. Calcined Co(II)-Triethylenetetramine, Co(II)- Polyaniline-Thiourea as the Cathode Catalyst of Proton Exchanged Membrane Fuel Cell. Polymers. 2020; 12(12):3070. https://doi.org/10.3390/polym12123070
Chicago/Turabian StyleHuang, Wen-Yao, Li-Cheng Jheng, Tar-Hwa Hsieh, Ko-Shan Ho, Yen-Zen Wang, Yi-Jhun Gao, and Po-Hao Tseng. 2020. "Calcined Co(II)-Triethylenetetramine, Co(II)- Polyaniline-Thiourea as the Cathode Catalyst of Proton Exchanged Membrane Fuel Cell" Polymers 12, no. 12: 3070. https://doi.org/10.3390/polym12123070