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Article

Development of Novel Thin Polycaprolactone (PCL)/Clay Nanocomposite Films with Antimicrobial Activity Promoted by the Study of Mechanical, Thermal, and Surface Properties

by
Sylva Holešová
1,*,
Karla Čech Barabaszová
1,
Marianna Hundáková
1,
Michaela Ščuková
1,2,
Kamila Hrabovská
3,
Kamil Joszko
4,
Magdalena Antonowicz
5 and
Bożena Gzik-Zroska
5
1
Nanotechnology Centre, CEET, VŠB—Technical University of Ostrava, 17. Listopadu 2172/15, 708 00 Ostrava, Czech Republic
2
Faculty of Materials Science and Technology, VŠB—Technical University of Ostrava, 17. Listopadu 2172/15, 708 00 Ostrava, Czech Republic
3
Department of Physics, Faculty of Electrical Engineering and Computer Science, VŠB—Technical University of Ostrava, 17. Listopadu 2172/15, 708 00 Ostrava, Czech Republic
4
Department of Biomechatronics, Faculty of Biomedical Engineering, Silesian University of Technology, Roosevelta 40, 41-800 Zabrze, Poland
5
Department of Biomaterials and Medical Devices Engineering, Faculty of Biomedical Engineering, Silesian University of Technology, Roosevelta 40, 41-800 Zabrze, Poland
*
Author to whom correspondence should be addressed.
Polymers 2021, 13(18), 3193; https://doi.org/10.3390/polym13183193
Submission received: 17 August 2021 / Revised: 16 September 2021 / Accepted: 18 September 2021 / Published: 21 September 2021
(This article belongs to the Special Issue Biopolymers for Food Packaging Films and Coatings)

Abstract

Infection with pathogenic microorganisms is of great concern in many areas, especially in healthcare, but also in food packaging and storage, or in water purification systems. Antimicrobial polymer nanocomposites have gained great popularity in these areas. Therefore, this study focused on new approaches to develop thin antimicrobial films based on biodegradable polycaprolactone (PCL) with clay mineral natural vermiculite as a carrier for antimicrobial compounds, where the active organic antimicrobial component is antifungal ciclopirox olamine (CPX). For possible synergistic effects, a sample in combination with the inorganic antimicrobial active ingredient zinc oxide was also prepared. The structures of all the prepared samples were studied by X-ray diffraction, FTIR analysis and, predominantly, by SEM. The very different structure properties of the prepared nanofillers had a fundamental influence on the final structural arrangement of thin PCL nanocomposite films as well as on their mechanical, thermal, and surface properties. As sample PCL/ZnOVER_CPX possessed the best results for antimicrobial activity against examined microbial strains, the synergic effect of CPX and ZnO combination on antimicrobial activity was proved, but on the other hand, its mechanical resistance was the lowest.
Keywords: polycaprolactone; vermiculite; nanocomposites; thin films; antimicrobial activity polycaprolactone; vermiculite; nanocomposites; thin films; antimicrobial activity
Graphical Abstract

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MDPI and ACS Style

Holešová, S.; Čech Barabaszová, K.; Hundáková, M.; Ščuková, M.; Hrabovská, K.; Joszko, K.; Antonowicz, M.; Gzik-Zroska, B. Development of Novel Thin Polycaprolactone (PCL)/Clay Nanocomposite Films with Antimicrobial Activity Promoted by the Study of Mechanical, Thermal, and Surface Properties. Polymers 2021, 13, 3193. https://doi.org/10.3390/polym13183193

AMA Style

Holešová S, Čech Barabaszová K, Hundáková M, Ščuková M, Hrabovská K, Joszko K, Antonowicz M, Gzik-Zroska B. Development of Novel Thin Polycaprolactone (PCL)/Clay Nanocomposite Films with Antimicrobial Activity Promoted by the Study of Mechanical, Thermal, and Surface Properties. Polymers. 2021; 13(18):3193. https://doi.org/10.3390/polym13183193

Chicago/Turabian Style

Holešová, Sylva, Karla Čech Barabaszová, Marianna Hundáková, Michaela Ščuková, Kamila Hrabovská, Kamil Joszko, Magdalena Antonowicz, and Bożena Gzik-Zroska. 2021. "Development of Novel Thin Polycaprolactone (PCL)/Clay Nanocomposite Films with Antimicrobial Activity Promoted by the Study of Mechanical, Thermal, and Surface Properties" Polymers 13, no. 18: 3193. https://doi.org/10.3390/polym13183193

APA Style

Holešová, S., Čech Barabaszová, K., Hundáková, M., Ščuková, M., Hrabovská, K., Joszko, K., Antonowicz, M., & Gzik-Zroska, B. (2021). Development of Novel Thin Polycaprolactone (PCL)/Clay Nanocomposite Films with Antimicrobial Activity Promoted by the Study of Mechanical, Thermal, and Surface Properties. Polymers, 13(18), 3193. https://doi.org/10.3390/polym13183193

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