Core-Shell Sr2CeO4@SiO2 Filled COC-Based Composites with Low Dielectric Loss for High-Frequency Substrates
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis and Surface Modification of Sr2CeO4
2.3. Fabrication of COC/Sr2CeO4@SiO2 Composites
2.4. Characterization
3. Result and Discussion
3.1. Characterization of Fillers and Composites
3.2. Dielectric Properties
3.3. Thermal Conductivity
3.4. Moisture Absorption and Corrosion Resistance
3.5. Coefficient of Thermal Expansion and Mechanical Properties
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Niu, H.; Ren, Y.; Guo, H.; Malycha, K.; Orzechowski, K.; Bai, S. Recent progress on thermally conductive and electrical insulating rubber composites: Design, processing, and applications. Compos. Commun. 2020, 22, 100430. [Google Scholar] [CrossRef]
- Zhang, F.; Feng, Y.; Feng, W. Three-dimensional interconnected networks for thermally conductive polymer composites: Design, preparation, properties, and mechanisms. Mater. Sci. Eng. R Rep. 2020, 142, 100580. [Google Scholar] [CrossRef]
- Chen, Y.; Hou, X.; Liao, M.; Dai, W.; Wang, Z.; Yan, C.; Li, H. Constructing a “pea-pod-like” alumina-graphene binary architecture for enhancing thermal conductivity of epoxy composite. Chem. Eng. J. 2020, 381, 122690. [Google Scholar] [CrossRef]
- Han, Y.; Shi, X.; Yang, X.; Guo, Y.; Zhang, J.; Kong, J.; Gu, J. Enhanced thermal conductivities of epoxy nanocomposites via incorporating in-situ fabricated hetero-structured SiC-BNNS fillers. Compos. Sci. Technol. 2020, 187, 107944. [Google Scholar] [CrossRef]
- Hu, D.; Liu, H.; Ma, W. Rational design of nanohybrids for highly thermally conductive polymer composites. Compos. Commun. 2020, 21, 100427. [Google Scholar] [CrossRef]
- Gao, Y.; Zhang, M.; Chen, X.; Zhu, Y.; Wang, H.; Yuan, S. A high-performance thermal conductive and outstanding electrical insulating composite based on robust neuron-like microstructure. Chem. Eng. J. 2021, 426, 131280. [Google Scholar] [CrossRef]
- Peng, H.; Ren, H.; Dang, M.; Zhang, Y.; Yao, X.; Lin, H. Novel high dielectric constant and low loss PTFE/CNT composites. Ceram. Int. 2018, 44, 16556–16560. [Google Scholar] [CrossRef]
- Wang, H.; Yang, H.; Wang, Q.; Tong, J.; Wen, J.; Zhang, Q. Surface-modified Li3Mg2NbO6 ceramic particles and hexagonal boron nitride sheets filled PTFE composites with high through-plane thermal conductivity and extremely low dielectric loss. Compos. Commun. 2020, 22, 100523. [Google Scholar] [CrossRef]
- Ge, M.; Zhang, J.; Zhao, C.; Lu, C.; Du, G. Effect of hexagonal boron nitride on the thermal and dielectric properties of polyphenylene ether resin for high-frequency copper clad laminates. Mater. Des. 2019, 182, 108028. [Google Scholar] [CrossRef]
- Guo, J.; Wang, H.; Zhang, C.; Zhang, Q.; Yang, H. MPPE/SEBS composites with low dielectric loss for high-frequency copper clad laminates applications. Polymers 2020, 12, 1875. [Google Scholar] [CrossRef] [PubMed]
- Yu, X.; Liang, W.; Cao, J.; Wu, D. Mixed rigid and flexible component design for high-performance polyimide films. Polymers 2017, 9, 451. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Ji, Y.; Bai, Y.; Liu, X.; Jia, K. Progress of liquid crystal polyester (LCP) for 5G application. Adv. Ind. Eng. Polym. Res. 2020, 3, 160–174. [Google Scholar] [CrossRef]
- Lyu, X.; Xiao, A.; Shi, D.; Li, Y.; Shen, Z.; Chen, E. Liquid crystalline polymers: Discovery, development, and the future. Polymer 2020, 202, 122740. [Google Scholar] [CrossRef]
- Cui, J.; Yang, J.; Pan, L.; Li, Y. Synthesis of novel cyclic olefin polymer with high glass transition temperature via ring-opening metathesis polymerization. Macromol. Chem. Phys. 2016, 217, 2708–2716. [Google Scholar] [CrossRef]
- Zhang, Y.; Yang, J.; Pan, L.; Li, Y. Synthesis of high performance cyclic olefin polymers using highly efficient WCl6-based catalyst system. Chin. J. Polym. Sci. 2018, 36, 214–221. [Google Scholar] [CrossRef]
- Zeng, X.; Yao, Y.; Gong, Z.; Wang, F.; Sun, R.; Xu, J. Ice-templated assembly strategy to construct 3D boron nitride nanosheet networks in polymer composites for thermal conductivity improvement. Small 2015, 11, 6205–6213. [Google Scholar] [CrossRef]
- Chen, C.; Xue, Y.; Li, Z.; Wen, Y.; Li, X.; Wu, F. Construction of 3D boron nitride nanosheets/silver networks in epoxy-based composites with high thermal conductivity via in-situ sintering of silver nanoparticles. Chem. Eng. J. 2019, 369, 1150–1160. [Google Scholar] [CrossRef]
- Liu, Z.; Li, J.; Liu, X. Novel functionalized BN nanosheets/epoxy composites with advanced thermal conductivity and mechanical properties. ACS Appl. Mater. Interfaces 2020, 12, 6503–6515. [Google Scholar] [CrossRef]
- Yuan, Y.; Li, Z.; Cao, L.; Tang, B.; Zhang, S. Modification of Si3N4 ceramic powders and fabrication of Si3N4/PTFE composite substrate with high thermal conductivity. Ceram. Int. 2019, 45, 16569–16576. [Google Scholar] [CrossRef]
- Yuan, Y.; Yin, Y.; Yu, D.; Lin, H.; Wang, J.; Tang, B. Effects of compound coupling agents on the properties of PTFE/SiO2 microwave composites. J. Mater. Sci. Mater. Electron. 2016, 28, 3356–3363. [Google Scholar] [CrossRef]
- Ouyang, Y.; Hou, G.; Bai, L.; Li, B.; Yuan, F. Constructing continuous networks by branched alumina for enhanced thermal conductivity of polymer composites. Compos. Sci. Technol. 2018, 165, 307–313. [Google Scholar] [CrossRef]
- Huang, X.; Iizuka, T.; Jiang, P.; Ohki, Y.; Tanaka, T. Role of interface on the thermal conductivity of highly filled dielectric epoxy/AlN composites. J. Phys. Chem. C 2012, 116, 13629–13639. [Google Scholar] [CrossRef]
- Yao, Y.; Zhu, X.; Zeng, X.; Sun, R.; Xu, J.; Wong, C. Vertically aligned and interconnected SiC nanowire networks leading to significantly enhanced thermal conductivity of polymer composites. ACS Appl. Mater. Interfaces 2018, 10, 9669–9678. [Google Scholar] [CrossRef] [PubMed]
- Chen, C.; Tang, Y.; Ye, Y.; Xue, Z.; Xue, Y.; Xie, X. High-performance epoxy/silica coated silver nanowire composites as underfill material for electronic packaging. Compos. Sci. Technol. 2014, 105, 80–85. [Google Scholar] [CrossRef]
- Zhou, Y.; Bai, Y.; Yu, K.; Kang, Y.; Wang, H. Excellent thermal conductivity and dielectric properties of polyimide composites filled with silica coated self-passivated aluminum fibers and nanoparticles. Appl. Phys. Lett. 2013, 102, 252903. [Google Scholar] [CrossRef]
- Wang, F.; Zeng, X.; Yao, Y.; Sun, R.; Xu, J.; Wong, C. Silver nanoparticle-deposited boron nitride nanosheets as fillers for polymeric composites with high thermal conductivity. Sci. Rep. 2016, 6, 19394. [Google Scholar] [CrossRef] [Green Version]
- Zhou, F.; Wang, H.; Guo, J.; Yang, H.; Zhang, Q. Sintering behavior and microwave dielectric properties of Sr2CeO4 ceramics doped with Li2CO3-Bi2O3. J. Mater. Sci. Mater. Electron. 2020, 31, 21693–21701. [Google Scholar] [CrossRef]
- Liang, X.; Yu, S.; Sun, R.; Luo, S.; Wan, J. Microstructure and dielectric behavior of the three-phase Ag@SiO2/BaTiO3/PVDF composites with high permittivity. J. Mater. Res. 2012, 27, 991–998. [Google Scholar] [CrossRef]
- Liang, X.; Wang, P.; Gao, Y.; Huang, H.; Tong, F.; Huang, B. Design and synthesis of porous M-ZnO/CeO2 microspheres as efficient plasmonic photocatalysts for nonpolar gaseous molecules oxidation: Insight into the role of oxygen vacancy defects and M=Ag, Au nanoparticles. Appl. Catal. B 2020, 260, 118151. [Google Scholar] [CrossRef]
- Zhou, Z.; Wang, H.; Zhu, Z.; Yang, H.; Zhang, Q. Enhanced dielectric, electromechanical and hydrophobic behaviors of core shell AgNWs@SiO2/PDMS composites. Colloids Surf. A 2019, 563, 59–67. [Google Scholar] [CrossRef]
- Contino, A.; Maccarrone, G.; Spitaleri, L.; Torrisi, L.; Nicotra, G.; Gulino, A. One pot synthesis of Au_ZnO core-Shell nanoparticles using a Zn complex acting as ZnO precursor, capping and reducing agent during theformation of Au NPs. Eur. J. Inorg. Chem. 2018, 43, 4678–4683. [Google Scholar] [CrossRef]
- Fiorenza, R.; Bellardita, M.; Balsamo, S.; Spitaleri, L.; Gulino, A.; Condorelli, M. A solar photothermocatalytic approach for the CO2 conversion: Investigation of different synergisms on CoO-CuO/brookite TiO2-CeO2 catalysts. Chem. Eng. J. 2022, 428, 131249. [Google Scholar] [CrossRef]
- Bellardita, M.; Fiorenza, R.; D’Urso, L.; Spitaleri, L.; Gulino, A.; Compagnini, G. Exploring the photothermo-catalytic performance of brookite TiO2-CeO2 composites. Catalysts 2020, 10, 765. [Google Scholar] [CrossRef]
- Talik, E.; Lipin’ska, L.; Skrzypek, D.; Skuta, A.; Zajdel, P.; Guzik, A. Electronic structure analysis and properties of Sr2CeO4 grown by sol–gel method. Mater. Res. Bull. 2012, 47, 3107–3113. [Google Scholar] [CrossRef]
- Zhan, X.; Zhao, S.; Wan, F.; Ma, Y.; Wang, L.; Chen, D. Improving dielectric properties of BaTiO3/poly(vinylidene flfluoride) composites by employing core-shell structured BaTiO3@Poly(methylmethacrylate) and BaTiO3@Poly(triflfluoroethyl methacrylate) nanoparticles. Appl. Surf. Sci. 2017, 403, 71–79. [Google Scholar] [CrossRef]
- Duwe, S.; Arlt, C.; Aranda, S.; Riedel, U.; Ziegmann, G. A detailed thermal analysis of nanocomposites fifilled with SiO2, AlN or boehmite at varied contents and a review of selected rules of mixture. Compos. Sci. Technol. 2012, 72, 1324–1330. [Google Scholar] [CrossRef]
- Chen, H.; Ginzburg, V.; Yang, J.; Yang, Y.; Li, W.; Huang, Y. Thermal conductivity of polymer-based composites: Fundamentals and applications. Prog. Polym. Sci. 2016, 59, 41–85. [Google Scholar] [CrossRef]
- Xue, Y.; Li, X.; Wang, H.; Zhang, D.; Chen, Y. Thermal conductivity improvement in electrically insulating silicone rubber composites by the construction of hybrid three-dimensional filler networks with boron nitride and carbon nanotubes. J. Appl. Polym. Sci. 2019, 136, 46929. [Google Scholar] [CrossRef]
- Ou, Z.; Gao, F.; Zhao, H.; Dang, S.; Zhu, L. Research on the thermal conductivity and dielectric properties of AlN and BN co-filled addition-cure liquid silicone rubber composites. RSC Adv. 2019, 9, 28851. [Google Scholar] [CrossRef] [Green Version]
- Fang, H.; Bai, S.; Wong, C. Thermal, mechanical and dielectric properties of flexible BN foam and BN nanosheets reinforced polymer composites for electronic packaging application. Compos. Part A 2017, 100, 71–80. [Google Scholar] [CrossRef]
- Gu, J.; Lv, Z.; Wu, Y.; Guo, Y.; Tian, L.; Qiu, H. Dielectric thermally conductive boron nitride/polyimide composites with outstanding thermal stabilities via in-situ polymerization-electrospinning-hot press method. Compos. Part A 2017, 94, 209–216. [Google Scholar] [CrossRef]
Sample | Si 2p | O 1s | Sr 3d | Ce 3d | C 1s |
---|---|---|---|---|---|
Sr2CeO4 | - | 56.24 | 12.98 | 1.05 | 29.73 |
Sr2CeO4@SiO2 | 6.17 | 67.05 | 7.21 | 0.16 | 19.42 |
Composites | Loading | εr | τε | F (Hz) | TC (W·m−1·K−1) | Reference |
---|---|---|---|---|---|---|
PPE/BN@SiO2 | 50.0 wt.% | 3.94 | 0.0040 | 5 × 109 | 1.08 | [9] |
PTFE/Si3N4 | 62.0 vol% | 4.03 | 0.0014 | 1010 | 1.30 | [19] |
SIR/BN/CNTs | 12.9 vol% | 2.90 | 0.0010 | 106 | 0.28 | [38] |
SIR/BN/AlN | 50.0 wt.% | 3.98 | 0.0085 | 106 | 0.56 | [39] |
PDMS/BNNS/BNF | 10.4 wt.% | 2.97 | 0.0050 | 109 | 0.56 | [40] |
PAA/BN | 30.0 wt.% | 3.77 | 0.0070 | 106 | 0.70 | [41] |
COC/Sr2CeO4@SiO2 | 20.0 vol% | 3.50 | 0.0023 | 1010 | 0.90 | This work |
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Wang, Q.; Wang, H.; Zhang, C.; Zhang, Q.; Yang, H. Core-Shell Sr2CeO4@SiO2 Filled COC-Based Composites with Low Dielectric Loss for High-Frequency Substrates. Polymers 2021, 13, 4006. https://doi.org/10.3390/polym13224006
Wang Q, Wang H, Zhang C, Zhang Q, Yang H. Core-Shell Sr2CeO4@SiO2 Filled COC-Based Composites with Low Dielectric Loss for High-Frequency Substrates. Polymers. 2021; 13(22):4006. https://doi.org/10.3390/polym13224006
Chicago/Turabian StyleWang, Qinlong, Hao Wang, Caixia Zhang, Qilong Zhang, and Hui Yang. 2021. "Core-Shell Sr2CeO4@SiO2 Filled COC-Based Composites with Low Dielectric Loss for High-Frequency Substrates" Polymers 13, no. 22: 4006. https://doi.org/10.3390/polym13224006