Carboxyl-Rich Carbon Dots as Highly Selective and Sensitive Fluorescent Sensor for Detection of Fe3+ in Water and Lactoferrin
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Characterization
2.3. Synthesis of COOH-CDs
2.4. Toxicity Experiment
2.5. Fluorescence Selectivity and Sensitive of COOH-CDs towards Fe3+ and Lactoferrin
2.6. Theoretical Calculations
3. Results and Discussion
3.1. Characterizations of COOH-CDs
3.2. Effects of Excitation Wavelength and pH on Fluorescent Emission
3.3. Toxicity Study of COOH-CDs
3.4. Fluorescent Selectivity and Sensitivity toward Fe3+
3.5. Theoretical Analysis for the Selectivity of COOH-CDs toward Metal Ions
3.6. Fluorescent Sensing Performance of LF
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sensor System | Analyte | Limit of Detection (LoD) | Refs. |
---|---|---|---|
Carbon dot decorated natural microcline membrane | Fe3+ | 61.6 μM | [39] |
Carbon dots | Fe3+ | 0.16 μM | [40] |
Carbon dots | Fe3+ | 0.703 μM | [41] |
Polyurethane–nitrogen-doped carbon dot nanocomposites | Fe3+ | 10.10 μM | [42] |
B, N, S-doped carbon dots | Fe3+ | 87 nM | [43] |
S-doped silicon quantum dots | Fe3+ | 0.21 μM | [44] |
Eu3+-doped metal–organic framework | Fe3+ | 0.897 μM | [45] |
N, B-co-doped carbon dots | Fe3+ | 0.74 μM | [46] |
N, P-doped carbon dots | Fe3+ | 0.1 μM | [47] |
Biomass-based polymer nanoparticles | Fe3+ | 0.17 μM | [48] |
COOH-CDs/Mn+ Complexes | BEs (kcal/mol) | Egs (eV) | Charge Distributions at Mn+ Surface (Δ a) (a.u.) |
---|---|---|---|
COOH-CDs/Fe3+ | −593.82 | 1.87 | 0.87 (−2.13) |
COOH-CDs/Cu2+ | −291.52 | 2.11 | 0.78 (−1.22) |
COOH-CDs/Co2+ | −229.54 | 2.15 | 1.34 (−0.63) |
COOH-CDs/Zn2+ | −211.19 | 2.14 | 1.70 (−0.30) |
COOH-CDs/Fe2+ | −198.64 | 2.33 | 1.47 (−0.53) |
COOH-CDs/Mn2+ | −169.55 | 2.52 | 1.68 (−0.32) |
COOH-CDs/Mg2+ | −146.23 | 2.40 | 1.77 (−0.23) |
COOH-CDs/Pb2+ | −122.68 | 2.45 | 1.28 (−0.72) |
COOH-CDs/Ba2+ | −114.39 | 2.68 | 1.47 (−0.53) |
COOH-CDs/Cr3+ | -- b | -- b | -- b |
Detect Method | Analyte | Limit of Detection (LoD) | Refs. |
---|---|---|---|
Thin-Layer Chromatography | LF | 3.5 µg/mL | [10] |
Colorimetric | LF | 110 µg/mL | [9] |
HPLC-UV | LF | 35.4 µg/mL | [51] |
HPLC | LF | 0.57 mg/L | [11] |
Sandwich Immunoassay | LF | 3.23 ng/mL | [52] |
Ultrahigh-Performance Liquid Chromatography-Tandem Mass Spectrometry | LF | 3.8 mg/kg | [53] |
Ultrahigh-Performance Liquid Chromatography-Tandem Mass Spectrometry | LF | 1 mg/100 g | [8] |
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Wang, X.; Zhao, Y.; Wang, T.; Liang, Y.; Zhao, X.; Tang, K.; Guan, Y.; Wang, H. Carboxyl-Rich Carbon Dots as Highly Selective and Sensitive Fluorescent Sensor for Detection of Fe3+ in Water and Lactoferrin. Polymers 2021, 13, 4317. https://doi.org/10.3390/polym13244317
Wang X, Zhao Y, Wang T, Liang Y, Zhao X, Tang K, Guan Y, Wang H. Carboxyl-Rich Carbon Dots as Highly Selective and Sensitive Fluorescent Sensor for Detection of Fe3+ in Water and Lactoferrin. Polymers. 2021; 13(24):4317. https://doi.org/10.3390/polym13244317
Chicago/Turabian StyleWang, Xinxin, Yanan Zhao, Ting Wang, Yan Liang, Xiangzhong Zhao, Ke Tang, Yutong Guan, and Hua Wang. 2021. "Carboxyl-Rich Carbon Dots as Highly Selective and Sensitive Fluorescent Sensor for Detection of Fe3+ in Water and Lactoferrin" Polymers 13, no. 24: 4317. https://doi.org/10.3390/polym13244317