Spectroscopic Studies of Styrylquinoline Copolymers with Different Substituents
Abstract
:1. Introduction
2. Materials and Methods
2.1. Measurement Methods and Equipments
2.2. Synthesis
2.3. Polymerization
2.4. Thin Films Preparation
2.5. Theoretical Calculations
3. Results and Discussion
3.1. Experimental Results
3.2. Theoretical Results
3.2.1. Chromophore Absorption
3.2.2. Copolymer Structure and Photophysics
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Polymer | R1 | Hammett σ Constant | Monomers Mole Ratio | n/m a | Yield % | Mw b g/mol | Mn b g/mol | Mw/Mn b | Tg c |
---|---|---|---|---|---|---|---|---|---|
COP1 | OCH3 | −0.268 donor | 1:3 | 1:2.9 | 80 | 10,500 | 6000 | 1.75 | 136.82 |
COP2 | Cl | 0.227 acceptor | 1:3 | 1:2.7 | 65 | 6000 | 4100 | 1.45 | 120.08 |
COP3 | CF3 | 0.540 acceptor | 1:3 | 1:2.8 | 73 | 9800 | 5500 | 1.78 | 139.68 |
Ground State S0 | Excited State S1 | Excited State 4 | ||||||||
---|---|---|---|---|---|---|---|---|---|---|
Dipole Moment μ | Dipole Moment μ | Δμ (S1-S0) | D [Å] | Q [a.u.] | Dipole Moment μ | Δμ (S4-S0) | D [Å] | Q [a.u.] | ||
A0 | E | 3.4702 | 3.1978 | −0.2724 | 0.262 | 0.347 | 3.9490 | 0.4788 | 0.844 | 0.360 |
Z | 3.8096 | 1.9713 | −1.8383 | 0.660 | 0.581 | 3.2343 | −0.5753 | 0.863 | 0.383 | |
A1 | E | 1.8144 | 3.0786 | 1.2642 | 1.684 | 0.412 | 2.7227 | 0.9083 | 1.102 | 0.374 |
Z | 2.6324 | 3.4264 | 0.7940 | 1.985 | 0.500 | 2.6414 | 0.0090 | 0.870 | 0.373 | |
A2 | E | 4.8433 | 4.5960 | −0.2473 | 0.148 | 0.352 | 4.6476 | −0.1957 | 0.843 | 0.365 |
Z | 5.5503 | 3.6939 | −1.8564 | 0.691 | 0.563 | 4.8970 | −0.6533 | 0.777 | 0.380 | |
A3 | E | 6.0855 | 8.1472 | 2.0617 | 1.315 | 0.361 | 6.2343 | 0.1488 | 0.619 | 0.361 |
Z | 6.6407 | 5.8906 | −0.7501 | 0.315 | 0.580 | 7.1717 | 0.5310 | 0.672 | 0.359 |
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Sypniewska, M.; Kaczmarek-Kędziera, A.; Apostoluk, A.; Smokal, V.; Krupka, A.; Szczesny, R.; Derkowska-Zielinska, B. Spectroscopic Studies of Styrylquinoline Copolymers with Different Substituents. Polymers 2022, 14, 4040. https://doi.org/10.3390/polym14194040
Sypniewska M, Kaczmarek-Kędziera A, Apostoluk A, Smokal V, Krupka A, Szczesny R, Derkowska-Zielinska B. Spectroscopic Studies of Styrylquinoline Copolymers with Different Substituents. Polymers. 2022; 14(19):4040. https://doi.org/10.3390/polym14194040
Chicago/Turabian StyleSypniewska, Malgorzata, Anna Kaczmarek-Kędziera, Alexandra Apostoluk, Vitaliy Smokal, Anastasiia Krupka, Robert Szczesny, and Beata Derkowska-Zielinska. 2022. "Spectroscopic Studies of Styrylquinoline Copolymers with Different Substituents" Polymers 14, no. 19: 4040. https://doi.org/10.3390/polym14194040