Nano-Hydroxyapatite from White Seabass Scales as a Bio-Filler in Polylactic Acid Biocomposite: Preparation and Characterization
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of nHAp Powder from White Sea Bass Scales
2.2. Preparation of PLA/nHAp Composite Films
2.3. Characterization of nHAp Powder
2.4. Characterization of PLA/nHAp Composite Films
2.5. Preparation of PLA/nHAp Fibers by Electrospinning Technique and Their Electrospinnability
3. Results and Discussion
3.1. Characterization of nHAp Powder
3.2. Characterization of PLA/nHAp Composite Films
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Properties | Materials | |
---|---|---|
1DP-nHAp | 2DP-nHAp | |
Crystallinity (%) | 71.41 | 80.99 |
Crystallite size, (nm) | 19.41 | 13.87 |
BET surface area (cm3/g) | 50 | 41 |
Total pore volume (cm3/g) | 0.26 | 0.17 |
Mean pore diameter (nm) | 21.25 | 16.32 |
Designation | nHAp Content (phr) | Young’s Modulus (GPa) | Tensile Strength (MPa) | Elongation at Break (%) |
---|---|---|---|---|
PLA | − | 1.73 ± 0.18 | 38.21 ± 0.95 | 23.39 ± 1.97 |
2.5 | 1.94 ± 0.27 | 54.45 ± 1.42 | 14.74 ± 2.92 | |
5 | 2.65 ± 0.05 | 66.41 ± 3.63 | 4.32 ± 0.34 | |
5 | 2.38 ± 0.11 | 52.21 ± 4.67 | 3.44 ± 0.66 | |
10 | 2.02 ± 0.18 | 45.80 ± 1.78 | 4.72 ± 0.59 |
Designation | Tg (°C) | Tcc (°C) | ∆Hcc (J·g−1) | Tm (°C) | ∆Hm (J·g−1) | Xc (%) |
---|---|---|---|---|---|---|
PLA | 60.10 | 127.89 | 3.57 | 151.60 | 3.16 | 7.23 |
60.81 | 128.39 | 6.71 | 151.59 | 6.51 | 14.50 | |
61.00 | 122.40 | 12.98 | 150.61 | 15.69 | 32.38 | |
60.77 | 121.90 | 19.72 | 150.44 | 16.74 | 41.17 | |
61.14 | 126.07 | 11.22 | 151.28 | 10.21 | 25.35 |
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Injorhor, P.; Trongsatitkul, T.; Wittayakun, J.; Ruksakulpiwat, C.; Ruksakulpiwat, Y. Nano-Hydroxyapatite from White Seabass Scales as a Bio-Filler in Polylactic Acid Biocomposite: Preparation and Characterization. Polymers 2022, 14, 4158. https://doi.org/10.3390/polym14194158
Injorhor P, Trongsatitkul T, Wittayakun J, Ruksakulpiwat C, Ruksakulpiwat Y. Nano-Hydroxyapatite from White Seabass Scales as a Bio-Filler in Polylactic Acid Biocomposite: Preparation and Characterization. Polymers. 2022; 14(19):4158. https://doi.org/10.3390/polym14194158
Chicago/Turabian StyleInjorhor, Preeyaporn, Tatiya Trongsatitkul, Jatuporn Wittayakun, Chaiwat Ruksakulpiwat, and Yupaporn Ruksakulpiwat. 2022. "Nano-Hydroxyapatite from White Seabass Scales as a Bio-Filler in Polylactic Acid Biocomposite: Preparation and Characterization" Polymers 14, no. 19: 4158. https://doi.org/10.3390/polym14194158