Ladder Polyphenylsilsesquioxanes and Their Niobium–Siloxane Composite as Coating Materials: Spectroscopy and Atomic Oxygen Resistance Study
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Sample Preparation
2.3. Characterization
2.4. Atomic-Oxygen Exposition
3. Results and Discussion
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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Sample | σp, MPA | εp, % | E, MPA | Film Thickness, μm |
---|---|---|---|---|
L-PPSQ-322 | 26 ± 2 | 7.0 ± 1.0 | 930 ± 56 | 120 |
L-PPSQ-322-Nb-[(SiO)x] | 18 ± 1 | 2.5 ± 0.2 | 900 ± 54 | 38 |
L-PPSQ-1060 | 27 ± 2 | 6.0 ± 0.4 | 980 ± 59 | 50 |
L-PPSQ-1060-Nb-[(SiO)x] | 40 ± 2 | 6.0 ± 0.4 | 1250 ± 75 | 27 |
Sample | at F = 6.5 × 1020 Atom O/cm2 | at F = 10.0 × 1020 Atom O/cm2 |
---|---|---|
Kapton (reference) [7] | 3 × 10–24 | 3 × 10–24 |
L-PPSQ-322 | 3.0 × 10–26 | 2.5 × 10–26 |
L-PPSQ-322-Nb-[(SiO)x] | 3.0 × 10–26 | 2.4 × 10–26 |
L-PPSQ-1060 | 5.5 × 10–26 | 4.8 × 10–26 |
L-PPSQ-1060-Nb-[(SiO)x] | 4.6 × 10–26 | 4.0 × 10–26 |
PDMS-Nb-[(SiO)x] | 1.7 × 10–25 | 1.3 × 10–25 |
PI- Nb-[(SiO)x] [38] | 2.1 × 10–26 | 1.7 × 10–26 |
PMDA−ODA/HBPSi [27] | 5.38 × 10–25 | |
POSS PI [29] | 6.6 × 10–26 | |
PI-30 [26] | 1.1 × 10–25 |
Sample | τTS | τDT | Δτ | |||
---|---|---|---|---|---|---|
Before AO Exposure | After AO Exposure | Before AO Exposure | After AO Exposure | Before AO Exposure | After AO Exposure | |
L-PPSQ-322 | 0.98 | 0.98 | 0.99 | 0.99 | 0.01 | 0.01 |
L-PPSQ-322-Nb-[(SiO)x] | 0.59 | 0.63 | 0.95 | 0.94 | 0.36 | 0.31 |
L-PPSQ-1060 | 0.86 | 0.84 | 0.89 | 0.87 | 0.03 | 0.03 |
PPSQ-1060-Nb-[(SiO)x] | 0.79 | 0.79 | 0.94 | 0.94 | 0.15 | 0.15 |
PDMS-Nb-[(SiO)x] | 0.92 | – | 0.90 | – | 0.02 | – |
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Andropova, U.S.; Aysin, R.R.; Serenko, O.A.; Ershova, T.O.; Anisimov, A.A.; Chernik, V.N. Ladder Polyphenylsilsesquioxanes and Their Niobium–Siloxane Composite as Coating Materials: Spectroscopy and Atomic Oxygen Resistance Study. Polymers 2023, 15, 3299. https://doi.org/10.3390/polym15153299
Andropova US, Aysin RR, Serenko OA, Ershova TO, Anisimov AA, Chernik VN. Ladder Polyphenylsilsesquioxanes and Their Niobium–Siloxane Composite as Coating Materials: Spectroscopy and Atomic Oxygen Resistance Study. Polymers. 2023; 15(15):3299. https://doi.org/10.3390/polym15153299
Chicago/Turabian StyleAndropova, Ulyana S., Rinat R. Aysin, Olga A. Serenko, Tatyana O. Ershova, Anton A. Anisimov, and Vladimir N. Chernik. 2023. "Ladder Polyphenylsilsesquioxanes and Their Niobium–Siloxane Composite as Coating Materials: Spectroscopy and Atomic Oxygen Resistance Study" Polymers 15, no. 15: 3299. https://doi.org/10.3390/polym15153299