Correlation of Dielectric Properties and Vibrational Spectra of Composite PVDF/Salt Fibers
Abstract
:1. Introduction
2. Materials and Methods
2.1. Sample Preparation
2.2. Sample Experimental Characterization
2.3. Computational Methods
2.4. Electrical Characterization
3. Results
3.1. Sample Morphology
3.2. Sample Composition
3.3. DFT Analyses
3.4. Dielectric Properties
4. Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Hydrated Salts | (kcal/mol) | (kcal/mol) | (kcal/mol) |
---|---|---|---|
Mg(NO3)2·6H2O | 1.88 | −96.20 | −312.90 |
Ca(NO3)2·4H2O | −1.26 | −70.10 | −315.49 |
Zn(NO3)2·6H2O | −1.88 | −86.88 | −313.085 |
PVDF/Salt Complexes | (kcal/mol) | (kcal/mol) | (kcal/mol) |
---|---|---|---|
α-PVDF/Mg(NO3)2·6H2O | 8.16 | −5.54 | −14.03 |
α-PVDF/Ca(NO3)2·4H2O | −0.62 | −10.48 | −11.05 |
α-PVDF/Zn(NO3)2·6H2O | −1.26 | −9.11 | −12.59 |
β-PVDF/Mg(NO3)2·6H2O | 9.41 | −10.59 | −18.42 |
β-PVDF/Ca(NO3)2·4H2O | −2.51 | −21.55 | −20.31 |
β-PVDF/Zn(NO3)2·6H2O | 7.53 | −9.20 | −18.66 |
γ-PVDF/Mg(NO3)2·6H2O | −2.51 | −15.85 | −11.56 |
γ-PVDF/Ca(NO3)2·4H2O | 0.62 | −10.46 | −12.48 |
γ-PVDF/Zn(NO3)2·6H2O | −2.51 | −17.22 | −16.85 |
Material | Pressure | Voltage | Current | Reference |
---|---|---|---|---|
PVDF + (Zn(NO3)2·6H2O) | 22.7 kPa | 0.4 V | 57 nA | This study |
PVDF + (Ca(NO3)2·4H2O) | 22.7 kPa | 0.41 V | 58 nA | This study |
PVDF + (Mg(NO3)2·6H2O) | 22.7 kPa | 0.48 V | 120 nA | This study |
PVDF + ZnO | ∼1.13 kPa | 0.51 ± 0.12 V | ∼190 nA | [23] |
PVDF + MXene | 200 kPa | 3.15 V | 134 nA | [24] |
PVDF + NiO | 9.81 Pa | 5.5 V | 1830 nA | [25] |
PVDF + CsPbBr3 | 100 MPa | 120 V | 35 µA | [26] |
PVDF + Cu@AgNP | 7.3 MPa | 0.147 V | 0.42 nA | [27] |
PVDF + cellulose nanocrystal | 15 kPa | 0.146 mV | 0.009 nA | [28] |
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Dallaev, R.; Sarkar, R.; Selimov, D.; Papež, N.; Kočková, P.; Schubert, R.; Častková, K.; Orudzhev, F.; Ramazanov, S.; Holcman, V. Correlation of Dielectric Properties and Vibrational Spectra of Composite PVDF/Salt Fibers. Polymers 2024, 16, 2412. https://doi.org/10.3390/polym16172412
Dallaev R, Sarkar R, Selimov D, Papež N, Kočková P, Schubert R, Častková K, Orudzhev F, Ramazanov S, Holcman V. Correlation of Dielectric Properties and Vibrational Spectra of Composite PVDF/Salt Fibers. Polymers. 2024; 16(17):2412. https://doi.org/10.3390/polym16172412
Chicago/Turabian StyleDallaev, Rashid, Ranjini Sarkar, Daud Selimov, Nikola Papež, Pavla Kočková, Richard Schubert, Klara Častková, Farid Orudzhev, Shikhgasan Ramazanov, and Vladimír Holcman. 2024. "Correlation of Dielectric Properties and Vibrational Spectra of Composite PVDF/Salt Fibers" Polymers 16, no. 17: 2412. https://doi.org/10.3390/polym16172412