Antimicrobial Coatings Based on a Photoreactive (Meth)acrylate Syrup and Ferulic Acid—The Effectiveness against Staphylococcus epidermidis
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of the (Meth)acrylate Syrup
2.3. Preparation of the Varnish Compositions and Coatings
2.4. Characterization of the (Meth)acrylate Syrup
2.5. Kinetic Studies of the UV Curing Process of the Varnish Compositions
2.6. Structural Characteristics of the UV-Cured Varnish Coatings
2.7. Mechanical and Optical Characteristics of the UV-Cured Varnish Coatings
2.8. Antibacterial Properties of the UV-Cured Varnish Coatings
3. Results and Discussion
3.1. The Physicochemical Properties of the (Meth)acrylate Syrup and Copolymer
3.2. Kinetic Studies of UV Curing of the Varnish Composition
3.3. Structural Characterization of UV-Cured Varnish Coatings
3.4. Mechanical and Optical Properties of the UV-Cured Varnish Coatings
3.5. Antimicrobial Properties of the UV-Cured Varnish Coatings
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
References
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(Meth)acrylate Syrup | Monomers [wt. parts] | APO [wt. part] | |||
---|---|---|---|---|---|
BA | MMA | HEA | STY | ||
MAS | 40 | 35 | 15 | 10 | 0.75 |
Varnish Symbol | Components [wt. parts] | |||
---|---|---|---|---|
MAS | PETIA | HAP | FA | |
CV-1/0 | 100 | 15 | 1 | 0 |
CV-1/0.3 | 0.3 | |||
CV-1/0.6 | 0.6 | |||
CV-1/0.9 | 0.9 | |||
CV-3/0 | 3 | 0 | ||
CV-3/0.3 | 0.3 | |||
CV-3/0.6 | 0.6 | |||
CV-3/0.9 | 0.9 | |||
CV-5/0 | 5 | 0 | ||
CV-5/0.3 | 0.3 | |||
CV-5/0.6 | 0.6 | |||
CV-5/0.9 | 0.9 |
Syrup | Copolymer | |||
---|---|---|---|---|
SC (%) | ƞ [Pa·s] | Mn [g/mol] | Mw [g/mol] | PDI [a.u.] |
51 | 4.6 | 15,000 | 56,000 | 3.7 |
HAP (wt. part) | 1 | 3 | 5 | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
FA (wt. part) | 0 | 0.3 | 0.6 | 0.9 | 0 | 0.3 | 0.6 | 0.9 | 0 | 0.3 | 0.6 | 0.9 |
Conversion (%) | 78 | 74 | 77 | 81 | 72 | 71 | 72 | 75 | 67 | 68 | 70 | 70 |
tRpmax (s) | 2.8 | 6.1 | 5.7 | 9.4 | 2.1 | 4.0 | 5.5 | 7.0 | 1.8 | 3.8 | 5.6 | 6.0 |
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Kowalczyk, A.; Kraśkiewicz, A.; Markowska-Szczupak, A.; Kowalczyk, K. Antimicrobial Coatings Based on a Photoreactive (Meth)acrylate Syrup and Ferulic Acid—The Effectiveness against Staphylococcus epidermidis. Polymers 2024, 16, 2452. https://doi.org/10.3390/polym16172452
Kowalczyk A, Kraśkiewicz A, Markowska-Szczupak A, Kowalczyk K. Antimicrobial Coatings Based on a Photoreactive (Meth)acrylate Syrup and Ferulic Acid—The Effectiveness against Staphylococcus epidermidis. Polymers. 2024; 16(17):2452. https://doi.org/10.3390/polym16172452
Chicago/Turabian StyleKowalczyk, Agnieszka, Agata Kraśkiewicz, Agata Markowska-Szczupak, and Krzysztof Kowalczyk. 2024. "Antimicrobial Coatings Based on a Photoreactive (Meth)acrylate Syrup and Ferulic Acid—The Effectiveness against Staphylococcus epidermidis" Polymers 16, no. 17: 2452. https://doi.org/10.3390/polym16172452