A Revised Method of Surface Water Quality Evaluation Based on Background Values and Its Application to Samples Collected in Heilongjiang Province, China
Abstract
:1. Introduction
2. Materials and Methods
2.1. Study Area
2.2. Sampling Sites and Data Collection
2.3. Water Quality Assessment
2.4. Statistical Analysis
2.5. Iterative 2σ-Technique
3. Results and Discussion
3.1. Water Quality Analysis
3.2. Characteristic Analysis of Failed Variables
3.3. Geochemical Background Value
3.4. Evaluation Method Considering Background Values
4. Conclusions
- (1)
- Based on research conducted between 2011 and 2016, the key background pollutants (COD, CODMn, NH3-N) were identified for river source water environment function zones in Heilongjiang Province.
- (2)
- Spatial and temporal variations of background pollutants were analysed, and the obtained relative seasonal averages (RMse,s,p) indicated that concentrations of background pollutants in surface water were higher in the wet season than in the dry season.
- (3)
- A three-step discriminant method was first proposed to identify the background area for determining pollutant background values.
- (4)
- Based on the iterative 2σ-technique, descriptive statistics and the range of water quality background values in the wet and dry seasons were calculated for the 22 source water reserves in 2017. In contrast to the evaluation results obtained by considering background values, those that ignored background values could not objectively reflect the effect of human activities on water quality.
Author Contributions
Funding
Conflicts of Interest
References
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Code | Reserve | Area (km2) | Proportion of Land Use Area (%) | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Farmland | Woodland | Grassland | Water | Town | Country Side | Industrial Construction Land | Unused Land | |||
A1 | Nanweng | 2262.3 | 98.4 | 1 | 0.2 | 0.4 | ||||
A2 | Nengjiang | 14,990.6 | 6.2 | 65.4 | 5 | 0.4 | 0.1 | 0.1 | 22.8 | |
A3 | Nanbei | 2516.5 | 29.1 | 65.3 | 5.3 | 0 | 0.2 | 0.1 | ||
A4 | Wuyuer | 227.32 | 42 | 33.1 | 7.2 | 0.6 | 17.1 | |||
A5 | Tongken | 81.99 | 14.9 | 80.3 | 0.6 | 0 | 4.2 | |||
A6 | Tangwang | 5122.5 | 1.5 | 91.8 | 4.8 | 0.3 | 0.5 | 0.6 | 0.1 | 0.4 |
A7 | Wuytong | 1703.3 | 6.3 | 84.3 | 0.5 | 0.4 | 0.1 | 8.4 | ||
A8 | Heli | 145.5 | 3.4 | 76.2 | 19.8 | 0.3 | 0.2 | 0.1 | ||
A9 | Yichun | 218.7 | 0.5 | 92.6 | 0.2 | 0.3 | 0.2 | 6.2 | ||
A10 | Hulan | 470.7 | 5.6 | 91.8 | 0.9 | 0.2 | 0.7 | 0.8 | ||
A11 | Bielahong | 3710.8 | 70 | 3.7 | 7.3 | 0.2 | 0.4 | 18.4 | ||
A12 | Anbang | 143.1 | 1.9 | 97.3 | 0.5 | 0.3 | ||||
A13 | Woken | 1303.1 | 32.3 | 55.7 | 2.9 | 0.7 | 8.4 | |||
A14 | Naoli | 1328.7 | 46.9 | 42.7 | 4.6 | 0.9 | 4.9 | |||
A15 | Qihulin | 134.4 | 1.9 | 96.4 | 1.3 | 0.1 | 0.3 | |||
A16 | Ashi | 1161.3 | 14.6 | 79.7 | 0.4 | 2.7 | 0.2 | 1 | 0.2 | 1.2 |
A17 | Mayi | 701.5 | 24.7 | 72 | 1.6 | 0.1 | 1.5 | 0.1 | ||
A18 | Mangmiu | 1628.3 | 12.9 | 82 | 4 | 0.1 | 0.9 | 0.1 | ||
A19 | Lalin | 927.6 | 6 | 91.3 | 0.8 | 1.3 | 0.5 | 0.1 | ||
A20 | Hailang | 1587.6 | 1.4 | 97.2 | 1.1 | 0.2 | 0.1 | |||
A21 | Xiaosuifen | 556.1 | 3.1 | 91.6 | 4.5 | 0.2 | 0.6 | |||
A22 | Muling | 463.6 | 4.1 | 88.5 | 5.9 | 1.3 | 0.2 |
Years | Variables | Failed Variables | F1 (%) | F2 (%) | F3 (%) | CCME WQI Values |
---|---|---|---|---|---|---|
2011 | 17 | 6 | 33.33 | 10.56 | 7.83 | 79.31 |
2012 | 17 | 5 | 27.78 | 11.08 | 14.90 | 80.71 |
2013 | 17 | 6 | 33.33 | 11.49 | 14.52 | 77.98 |
2014 | 17 | 5 | 27.78 | 11.41 | 15.21 | 80.57 |
2015 | 17 | 7 | 38.89 | 9.55 | 12.75 | 75.74 |
2016 | 17 | 7 | 38.89 | 11.14 | 13.83 | 75.32 |
Variable | Grouping of Variables | Total Number of Monitoring Data Entries (N) | Asymptotic Saliency (p) |
---|---|---|---|
COD | 2011–2016 | 988 | 0.083 |
CODMn | 988 | 0.093 | |
NH3-N | 984 | 0.008 | |
COD | A1–A22 | 988 | 0.00 |
CODMn | 988 | 0.00 | |
NH3-N | 984 | 0.00 |
Study Area | Single Index Recognition | Limiting Factor | Synthetic Index | Complete Background Area | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 2 | 4 | 3 | 5 | Single Index Recognition | 6 | 7 | 8 | Limiting Factor | Score | Synthetic Index | |||
A1 | Nanweng | I | I | I | I | I | 1 | 1 | √ | |||||
A2 | Nengjiang | I | II | I | I | II | 0.81 | 0.81 | √ | |||||
A3 | Nanbei | I | II | II | II | I | 0.75 | |||||||
A4 | Wuyuer | I | III | II | III | I | Poor background properties | 0.62 | ||||||
A5 | Tongken | I | II | I | II | I | 0.78 | |||||||
A6 | Tangwang | II | I | II | I | II | × | × | Veto power | 0.83 | 0.83 | |||
A7 | Wuytong | I | II | II | I | I | 0.83 | 0.83 | √ | |||||
A8 | Heli | I | I | I | I | I | 0.96 | 0.96 | √ | |||||
A9 | Yichun | I | I | I | I | I | 0.94 | 0.94 | √ | |||||
A10 | Hulan | I | I | II | I | I | 0.78 | √ | ||||||
A11 | Bielahong | I | III | II | III | I | Poor background properties | × | Veto power | 0.21 | ||||
A12 | Anbang | I | I | II | I | I | 0.87 | 0.87 | √ | |||||
A13 | Woken | I | III | II | III | I | Poor background properties | × | Veto power | 0.6 | ||||
A14 | Naoli | II | III | II | III | I | Poor background properties | 0.49 | ||||||
A15 | Qihulin | I | I | II | I | I | 0.91 | 0.91 | √ | |||||
A16 | Ashi | III | II | III | II | III | Poor background properties | × | × | Veto power | 0.53 | |||
A17 | Mayi | II | II | II | II | I | 0.54 | |||||||
A18 | Mangmiu | II | II | II | II | I | 0.72 | |||||||
A19 | Lalin | II | I | II | I | I | × | Veto power | 0.81 | 0.81 | ||||
A20 | Hailang | I | I | II | I | I | 0.92 | 0.92 | √ | |||||
A21 | Xiaosuifen | II | I | II | I | I | 0.86 | 0.86 | √ | |||||
A22 | Muling | I | I | I | I | I | × | Veto power | 0.89 | 0.89 |
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Duan, M.; Du, X.; Peng, W.; Zhang, S.; Yan, L. A Revised Method of Surface Water Quality Evaluation Based on Background Values and Its Application to Samples Collected in Heilongjiang Province, China. Water 2019, 11, 1057. https://doi.org/10.3390/w11051057
Duan M, Du X, Peng W, Zhang S, Yan L. A Revised Method of Surface Water Quality Evaluation Based on Background Values and Its Application to Samples Collected in Heilongjiang Province, China. Water. 2019; 11(5):1057. https://doi.org/10.3390/w11051057
Chicago/Turabian StyleDuan, Maoqing, Xia Du, Wenqi Peng, Shijie Zhang, and Linqing Yan. 2019. "A Revised Method of Surface Water Quality Evaluation Based on Background Values and Its Application to Samples Collected in Heilongjiang Province, China" Water 11, no. 5: 1057. https://doi.org/10.3390/w11051057
APA StyleDuan, M., Du, X., Peng, W., Zhang, S., & Yan, L. (2019). A Revised Method of Surface Water Quality Evaluation Based on Background Values and Its Application to Samples Collected in Heilongjiang Province, China. Water, 11(5), 1057. https://doi.org/10.3390/w11051057