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Evaluating CHIRPS and ERA5 for Long-Term Runoff Modelling with SWAT in Alpine Headwaters
Characterizing Hot-Water Consumption at Household and End-Use Levels Based on Smart-Meter Data
Making Sense of Unsustainable Realities: Hydropower and the Sustainable Development Goals
Sediment Transport Constraints for Restoration of the Ebro Delta
Comparative Analysis of Livestock Wastewater Reuse Under Summer and Winter Conditions at a Scale-Down Microalgae Culture

Journal Description

Water

Water is a peer-reviewed, open access journal on water science and technology, including the ecology and management of water resources, and is published semimonthly online by MDPI. Water collaborates with the Stockholm International Water Institute (SIWI). In addition, the American Institute of Hydrology (AIH), The Polish Limnological Society (PLS) and Japanese Society of Physical Hydrology (JSPH) are affiliated with Water and their members receive a discount on the article processing charges.

Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
High Visibility: indexed within Scopus, SCIE (Web of Science), Ei Compendex, GEOBASE, GeoRef, PubAg, AGRIS, CAPlus / SciFinder, Inspec, and other databases.
Journal Rank: JCR - Q2 (Water Resources) / CiteScore - Q1 (Aquatic Science)
Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 19.1 days after submission; acceptance to publication is undertaken in 2.6 days (median values for papers published in this journal in the first half of 2025).
Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in any MDPI journal, in appreciation of the work done.
Companion journals for Water include: GeoHazards.
Journal Clusters of Water Resources: Water, Journal of Marine Science and Engineering, Hydrology, Resources, Oceans, Limnological Review, Coasts.

Impact Factor: 3.0 (2024); 5-Year Impact Factor: 3.3 (2024)

Imprint Information Journal Flyer Open Access ISSN: 2073-4441

Latest Articles

18 pages, 1012 KiB

Open AccessArticle

Sustainable Greywater Treatment in Jordan: The Role of Constructed Wetlands as Nature-Based Solutions

by Ahmed M. N. Masoud, Amani Alfarra, Alham W. Al-Shurafat and Sabrina Sorlini

Water 2025, 17(16), 2497; https://doi.org/10.3390/w17162497 - 21 Aug 2025

Water scarcity in Jordan is intensifying, creating an urgent need for innovative approaches to maximize the use of nonconventional water resources, such as greywater treatment and reuse. This study presents a detailed analysis of the suitability of nature-based solutions (NbSs) for greywater treatment, [...] Read more.

Water scarcity in Jordan is intensifying, creating an urgent need for innovative approaches to maximize the use of nonconventional water resources, such as greywater treatment and reuse. This study presents a detailed analysis of the suitability of nature-based solutions (NbSs) for greywater treatment, with a focus on the application of horizontal flow constructed wetlands (HFCWs). Two systems were implemented to treat greywater generated from mosques located in Az-Zarqa Governorate, a dry region in Jordan. Following several months of operation, monitoring, and evaluation, the systems demonstrated high removal efficiencies: turbidity (>87%), total suspended solids (TSS) (>96%), chemical oxygen demand (COD) (>91%), and five-day biological oxygen demand (BOD₅) (>85%). The eight-square-meter HFCW units successfully produced one cubic meter of treated greywater per day, meeting Jordanian standards for reclaimed greywater (JS 1776:2013) for use in irrigating food crops, including those consumed raw. The system achieved a 70% reduction in water consumption compared to the same period in the year prior to its implementation. These results demonstrate the potential of constructed wetlands (CWs) as effective, low-cost, and sustainable NbSs for decentralized greywater treatment and reuse in water-scarce regions. Full article

(This article belongs to the Special Issue Impacts of Climate Change & Human Activities on Wetland Ecosystems)

21 pages, 16313 KiB

Open AccessArticle

An Interpretable Deep Learning Framework for River Water Quality Prediction—A Case Study of the Poyang Lake Basin

by Ying Yuan, Chunjin Zhou, Jingwen Wu, Fuliang Deng, Wei Liu, Mei Sun and Lanhui Li

Water 2025, 17(16), 2496; https://doi.org/10.3390/w17162496 - 21 Aug 2025

Accurate prediction of water quality involves early identification of future pollutant concentrations and water quality indicators, which is an important prerequisite for optimizing water environment management. Although deep learning algorithms have demonstrated considerable potential in predicting water quality parameters, their broader adoption remains [...] Read more.

Accurate prediction of water quality involves early identification of future pollutant concentrations and water quality indicators, which is an important prerequisite for optimizing water environment management. Although deep learning algorithms have demonstrated considerable potential in predicting water quality parameters, their broader adoption remains hindered by limited interpretability. This study proposes an interpretable deep learning framework integrating an artificial neural network (ANN) model with Shapley additive explanations (SHAP) analysis to predict spatiotemporal variations in water quality and identify key influencing factors. A case study was conducted in the Poyang Lake Basin, utilizing multi-dimensional datasets encompassing topographic, meteorological, socioeconomic, and land use variables. Results indicated that the ANN model exhibited strong predictive performance for dissolved oxygen (DO), total nitrogen (TN), total phosphorus (TP), permanganate index (CODMn), ammonia nitrogen (NH₃N), and turbidity (Turb), achieving R² values ranging from 0.47 to 0.77. Incorporating land use and socioeconomic factors enhanced prediction accuracy by 37.8–246.7% compared to models using only meteorological data. SHAP analysis revealed differences in the dominant factors influencing various water quality parameters. Specifically, cropland area, forest cover, air temperature, and slope in each sub-basin were identified as the most important variables affecting water quality parameters in the case area. These findings provide scientific support for the intelligent management of the regional water environment. Full article

(This article belongs to the Section Water Quality and Contamination)

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18 pages, 1216 KiB

Open AccessArticle

Ultrasonic-Cavitation-Enhanced Biodegradation of Ciprofloxacin: Mechanisms and Efficiency

by Qianheng Wen, Qiwei Peng, ThuThi Pham and Xiwei He

Water 2025, 17(16), 2495; https://doi.org/10.3390/w17162495 - 21 Aug 2025

Ciprofloxacin (CIP), a persistent fluoroquinolone antibiotic, poses serious environmental concerns due to its low biodegradability and widespread presence in aquatic ecosystems. This study investigates the synergistic application of low-frequency ultrasonic cavitation and biological treatment to enhance CIP removal efficiency. Experiments have shown that [...] Read more.

Ciprofloxacin (CIP), a persistent fluoroquinolone antibiotic, poses serious environmental concerns due to its low biodegradability and widespread presence in aquatic ecosystems. This study investigates the synergistic application of low-frequency ultrasonic cavitation and biological treatment to enhance CIP removal efficiency. Experiments have shown that under the optimal biological treatment conditions (6 g/L sludge concentration, pH 8), single biological treatment for 48 h can only remove 41.9% CIP and 24.9% total organic carbon (TOC). Ultrasonic pretreatment was conducted under varying frequencies and pH conditions to determine optimal cavitation parameters, while biodegradation performance was evaluated at different sludge concentrations and pH levels. Results indicated that in 10 mg/L CIP wastewater under alkaline conditions (pH 9.0), CIP and TOC removal efficiencies reached 58.9% and 35.2%, respectively, within 30 min using 15 kHz ultrasound irradiation. When ultrasonic pretreatment was followed by biological treatment, overall removal rates increased to 96.3% for CIP and 90.4% for TOC, significantly outperforming either method alone. LC-MS analysis identified several degradation intermediates during ultrasonic pretreatment, revealing key transformation pathways such as piperazine ring cleavage, hydroxylation, and defluorination. Furthermore, toxicity evaluation using the T.E.S.T. model confirmed a substantial reduction in ecological risk after ultrasonic treatment. Overall, the combined ultrasonic–biological process offers a cost-effective and environmentally sustainable strategy for the efficient removal of fluoroquinolone antibiotics from wastewater. Full article

(This article belongs to the Special Issue Application of Microbial Technology in Wastewater Treatment)

23 pages, 1035 KiB

Open AccessReview

Recent Advances in Organic Pollutant Removal Technologies for High-Salinity Wastewater

by Jun Dai, Yun Gao, Kinjal J. Shah and Yongjun Sun

Water 2025, 17(16), 2494; https://doi.org/10.3390/w17162494 - 21 Aug 2025

Industrial processes like farming, food processing, petroleum refinery, and leather manufacturing produce a lot of high-salinity wastewater. This wastewater presents serious environmental risks, such as soil degradation, eutrophication, and water salinization, if it is released without adequate treatment. The sources and features of [...] Read more.

Industrial processes like farming, food processing, petroleum refinery, and leather manufacturing produce a lot of high-salinity wastewater. This wastewater presents serious environmental risks, such as soil degradation, eutrophication, and water salinization, if it is released without adequate treatment. The sources and features of high-salinity wastewater are outlined in this review, along with the main methods for removing organic pollutants, such as physicochemical, biological, and combined treatment approaches. Membrane separation, coagulation–flocculation, and advanced oxidation processes are the primary physicochemical techniques. Anaerobic and aerobic technologies are the two categories into which biological treatments fall. Physicochemical–biological combinations and the fusion of several physicochemical techniques are examples of integrated technologies. In order to achieve sustainable and effective treatment and resource recovery of high-salinity wastewater, this review compares the effectiveness and drawbacks of each method and recommends that future research concentrate on the development of salt-tolerant catalysts, anti-fouling membrane materials, halophilic microbial consortia, and optimized hybrid treatment systems. Full article

(This article belongs to the Special Issue Advanced Wastewater Treatment Technologies with the Potential to Achieve Resource Recycling)

21 pages, 8981 KiB

Open AccessArticle

The Influence of the Sediment and Water Transported by the Yellow River on the Subaqueous Delta Without Water and Sediment Regulation

by Junyao Song, Bowen Li, Kaifei He and Xuerong Cui

Water 2025, 17(16), 2493; https://doi.org/10.3390/w17162493 - 21 Aug 2025

Globally, sediment transport from rivers and the morphological evolution of deltas are strongly shaped by human activities. The Yellow River Delta is a typical representative of this. In this paper, Delft 3D v4.01.00 software was used to simulate the sediment diffusion in the [...] Read more.

Globally, sediment transport from rivers and the morphological evolution of deltas are strongly shaped by human activities. The Yellow River Delta is a typical representative of this. In this paper, Delft 3D v4.01.00 software was used to simulate the sediment diffusion in the subaqueous delta of the Yellow River in 2017 so as to explore the influence of the sediment and water transported by the Yellow River on the subaqueous delta without water and sediment regulation. The results reveal the occurrence of a low–high–low suspended sediment concentration distribution from the coastlines to the far shore. The main accumulation areas shifted from the coasts of Bohai Bay and Laizhou Bay in the dry season to the estuary in the wet season. The sediments entering the sea formed deposition zones along the coastline, and erosion zones were formed outside these deposition zones, with a maximum depth of about 5 m. In 2017, the impact of the sediment inflow into the Yellow River on its subaqueous delta generally resulted in the erosion being greater than the sedimentation, and the erosion/deposition volume in 2017 was −1.28 × 10⁸ m³, and the estimated critical value of the sediment inflow balance was 2.13 × 10⁸ tons. Full article

(This article belongs to the Section Water Erosion and Sediment Transport)

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23 pages, 2478 KiB

Open AccessArticle

Creep Tests and Fractional Creep Damage Model of Saturated Frozen Sandstone

by Yao Wei and Hui Peng

Water 2025, 17(16), 2492; https://doi.org/10.3390/w17162492 - 21 Aug 2025

The rock strata traversed by frozen shafts in coal mines located in western regions are predominantly composed of weakly cemented, water-rich sandstones of the Cretaceous system. Investigating the rheological damage behavior of saturated sandstone under frozen conditions is essential for evaluating the safety [...] Read more.

The rock strata traversed by frozen shafts in coal mines located in western regions are predominantly composed of weakly cemented, water-rich sandstones of the Cretaceous system. Investigating the rheological damage behavior of saturated sandstone under frozen conditions is essential for evaluating the safety and stability of these frozen shafts. To explore the damage evolution and creep characteristics of Cretaceous sandstone under the coupled influence of low temperature and in situ stress, a series of triaxial creep tests were conducted at a constant temperature of −10 °C, under varying confining pressures (0, 2, 4, and 6 MPa). Simultaneously, acoustic emission (AE) energy monitoring was employed to characterize the damage behavior of saturated frozen sandstone under stepwise loading conditions. Based on the experimental findings, a fractional-order creep constitutive model incorporating damage evolution was developed to capture the time-dependent deformation behavior. The sensitivity of model parameters to temperature and confining pressure was also analyzed. The main findings are as follows: (1) Creep deformation progressively increases with higher confining pressure, and nonlinear accelerated creep is observed during the final loading stage. (2) A fractional-order nonlinear creep model accounting for the coupled effects of low temperature, stress, and damage was successfully established based on the test data. (3) Model parameters were identified using the least squares fitting method across different temperature and pressure conditions. The predicted curves closely match the experimental results, validating the accuracy and applicability of the proposed model. These findings provide a theoretical foundation for understanding deformation mechanisms and ensuring the structural integrity of frozen shafts in Cretaceous sandstone formations of western coal mines. Full article

(This article belongs to the Special Issue Freeze–Thaw Dynamics and Water Pathways: Vulnerability of Infrastructures and Disasters in Mines in Cold Regions)

16 pages, 2080 KiB

Open AccessArticle

Methane Emissions from Wetlands on the Tibetan Plateau over the Past 40 Years

by Tingting Sun, Zehua Jia, Yiming Zhang, Mengxin Ying, Mengxin Shen and Guanting Lyu

Water 2025, 17(16), 2491; https://doi.org/10.3390/w17162491 - 21 Aug 2025

Methane (CH₄) emissions from the wetlands of the Tibetan Plateau (TP) remain poorly quantified, particularly regarding their historical dynamics, spatial heterogeneity, and response to climate change. This study provides the high-resolution, observation-driven reconstruction of TP wetland CH₄ emissions over the [...] Read more.

Methane (CH₄) emissions from the wetlands of the Tibetan Plateau (TP) remain poorly quantified, particularly regarding their historical dynamics, spatial heterogeneity, and response to climate change. This study provides the high-resolution, observation-driven reconstruction of TP wetland CH₄ emissions over the past four decades, integrating a machine learning model with 108 flux measurements from 67 sites. This unique combination of field-based data and fine-scale mapping enables unprecedented accuracy in quantifying both emission intensity and long-term trends. We show that current TP wetlands emit 5.87 ± 1.43 g CH₄ m⁻² yr⁻¹, totaling 97.3 Gg CH₄ yr⁻¹, equivalent to 7.8% of East Asia’s annual wetland emissions. Despite a climate-driven increase in per-unit-area CH₄ fluxes, a 19.8% (8432.9 km²) loss of wetland area since the 1980s has reduced total emissions by 15%, counteracting the enhancement from warming and moisture increases. Our comparative analysis demonstrates that existing land surface models (LSMs) substantially underestimate TP wetland CH₄ emissions, largely due to the inadequate representation of TP wetlands and their dynamics. Projections under future climate scenarios indicate a potential 8.5–21.2% increase in emissions by 2100, underscoring the importance of integrating high-quality, region-specific observational datasets into Earth system models. By bridging the gap between field observations and large-scale modeling, this work advances understanding of alpine wetland–climate feedback, and provides a robust foundation for improving regional carbon budget assessments in one of the most climate-sensitive regions on Earth. Full article

(This article belongs to the Section Water and Climate Change)

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37 pages, 3197 KiB

Open AccessReview

Current State of Research on the Three-Dimensional Particle Electrode System for Treating Organic Pollutants from Wastewater Streams: Particle Electrode, Degradation Mechanism, and Synergy Effects

by Guene L. Razack, Jiayi Wang, Xian Zhao, Worou Chabi Noel, Hanjun Sun, Jiwei Pang, Jie Ding, Wenshuo Wang, Xiaoyin Yang, Chenhao Cui, Yani Zang, Yuqian Wang, Geng Luo, Nanqi Ren and Shanshan Yang

Water 2025, 17(16), 2490; https://doi.org/10.3390/w17162490 - 21 Aug 2025

As the demand for effective wastewater treatment continues to rise, the application of three-dimensional (3D) electrochemical particle electrodes for the removal of organic compounds from industrial wastewater has emerged as a promising solution. This approach offers significant advantages, including high treatment efficiency, operational [...] Read more.

As the demand for effective wastewater treatment continues to rise, the application of three-dimensional (3D) electrochemical particle electrodes for the removal of organic compounds from industrial wastewater has emerged as a promising solution. This approach offers significant advantages, including high treatment efficiency, operational flexibility, high current efficiency, low energy consumption, and the ability to degrade non-biodegradable organic pollutants, ultimately mineralizing them. This review provides a comprehensive and systematic exploration of the research and development of particle electrodes for use in 3D electrochemical reactors in wastewater treatment. The pivotal role of particle electrodes in removing organic contaminants from wastewater was highlighted, with most materials used as particle electrodes characterized by a specific surface area and well-defined porous structure, both of which were thoroughly discussed. Through the synergistic mechanism of adsorption, the particle electrode aids in the breakdown of organic contaminants, demonstrating the 3D particle electrode’s effectiveness in facilitating multiple oxidation mechanisms for organic wastewater treatment. Furthermore, this review categorized various particle electrode types used in 3D electrochemical wastewater treatment based on their primary components or carriers and the presence or absence of catalysts. Finally, the current status and prospects for the development and enhancement of 3D electrode particles were presented. This review offers valuable insights into the application of the 3D electrode process for environmental water treatment. Full article

(This article belongs to the Section Wastewater Treatment and Reuse)

25 pages, 3665 KiB

Open AccessArticle

Quantifying the Comprehensive Water Resources and Environment Carrying Capacity in Wuhan City Based on the “Human-Water-City” Framework

by Huiyuan Liu, Yi Dong, Jun Xia, Guoqing Wang and Jun Ma

Water 2025, 17(16), 2489; https://doi.org/10.3390/w17162489 - 21 Aug 2025

In recent years, China’s rapid economic growth and urbanization have heightened the conflict between economic development and resource sustainability, leading to severe urban water challenges, including scarcity and environmental degradation. This study proposes a quantitative model that integrates the “Human-Water-City” (HWC) feedback mechanisms [...] Read more.

In recent years, China’s rapid economic growth and urbanization have heightened the conflict between economic development and resource sustainability, leading to severe urban water challenges, including scarcity and environmental degradation. This study proposes a quantitative model that integrates the “Human-Water-City” (HWC) feedback mechanisms to assess and measure urban comprehensive water resources and environmental carrying capacity (CWRECC), aimed at addressing urban water sustainability challenges. The CWRECC integrates water quantity and quality dimensions following the principles of the “Cannikin Law”—selecting the lower envelope between water resources and water environment carrying capacities, which emphasizes the importance of weaknesses in enhancing the overall system. The maximum sustainable population and Gross Domestic Product (GDP) under the CWRECC constraints can be obtained using this quantitative method. A case study was conducted in Wuhan City. The results show that Wuhan has abundant water resources. From 2013 to 2020, if only considering the water quantity aspect, the water resources carrying capacity could support a population ranging from 22.63 to 61.17 million and a GDP between 1946.6 and 7988.9 billion yuan, maintaining a sustainable state throughout the period. However, when considering both water quantity and quality, the CWRECC revealed an overloaded state in 2013, 2014, 2018, and 2019, primarily attributable to significant water environmental issues. In 2013, 2014, 2018, and 2019, the quantified CWRECC could sustain populations of 9.88 million, 10.01 million, 10.33 million, and 10.57 million people, and support a GDP of 849.5 billion, 976.5 billion, 1402.9 billion, and 1538.9 billion yuan, respectively. Both the population and GDP capacities fell short of the actual recorded values for those years. The findings demonstrate that Wuhan needs to make greater efforts in water environmental protection to sustain the harmonious development within the HWC. This empirical study highlights the model’s potential to provide a scientific foundation for urban water resources management and environmental protection strategies. Full article

(This article belongs to the Section Water Use and Scarcity)

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22 pages, 1130 KiB

Open AccessReview

Spectroscopy-Based Methods for Water Quality Assessment: A Comprehensive Review and Potential Applications in Livestock Farming

by Aikaterini-Artemis Agiomavriti, Thomas Bartzanas, Nikos Chorianopoulos and Athanasios I. Gelasakis

Water 2025, 17(16), 2488; https://doi.org/10.3390/w17162488 - 21 Aug 2025

Water quality monitoring and evaluation are essential across multiple sectors, including public health, environmental protection, agriculture and livestock management, industrial processes, and broader sustainability efforts. Conventional water analysis techniques, although accurate, are often constrained by their labor-intensive nature, extended processing times, and limited [...] Read more.

Water quality monitoring and evaluation are essential across multiple sectors, including public health, environmental protection, agriculture and livestock management, industrial processes, and broader sustainability efforts. Conventional water analysis techniques, although accurate, are often constrained by their labor-intensive nature, extended processing times, and limited applicability for in situ, real-time monitoring. In recent years, spectroscopy-based methods have gained prominence as alternatives for water quality assessment, particularly when combined with chemometric analyses and advanced technological systems. This review provides an overview of the current advancements of spectroscopy-based water monitoring, with a focus on spectroscopy techniques operating within ultraviolet–visible (UV–Vis) and infrared (IR) spectral regions, which are currently applied for the assessment of a broad range of physicochemical and biological parameters relevant to livestock water management, including chemical oxygen demand (COD), dissolved organic carbon (DOC), nitrates, microbial contamination, and heavy metal ions. The findings highlight the growing utility of spectroscopy as a reliable tool in water quality assessment (e.g., COD detection with R² = 0.86 and nitrate detection with R² = 0.95 compared to traditional methods) and underpin the need for continued research into scalable, sensor-integrated solutions tailored for use in livestock farming environments. Full article

(This article belongs to the Section Water Quality and Contamination)

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29 pages, 37535 KiB

Open AccessArticle

Evolution of the Hydrological Regime at the Outlet of West Dongting Lake Since 1955

by Shuai Yuan, Changbo Jiang, Yuan Ma and Shanshan Li

Water 2025, 17(16), 2487; https://doi.org/10.3390/w17162487 - 21 Aug 2025

To quantitatively evaluate the hydrological regime dynamics in West Dongting Lake over the past seven decades, this study utilizes daily average water level series (1955–2024) from key control stations (Nanzui and Xiaohezui) to analyze variations in water level and discharge through change-point detection [...] Read more.

To quantitatively evaluate the hydrological regime dynamics in West Dongting Lake over the past seven decades, this study utilizes daily average water level series (1955–2024) from key control stations (Nanzui and Xiaohezui) to analyze variations in water level and discharge through change-point detection methods, adopting the water level difference between Xiaohezui and Nanzui as a pivotal indicator of hydrological changes; the IHA–RVA framework is then applied to comprehensively assess the degree of alteration in hydrological indicators before and after identifying change points, demonstrating the following: (1) declining trends in water level/discharge at both stations—primarily attributable to reduced inflows from the Songzi and Hudu Rivers—underwent abrupt shifts in 1983 and 2003, while the water level difference displayed an increasing trend with a change point in 1991; (2) the overall degree of hydrologic alteration (DHA) was moderate, with enhanced variability during T2 (2003–2024) relative to T1 (1983–2003), notably for discharge at Nanzui and water level at Xiaohezui; (3) reduced discharge in the Songzi and Hudu Rivers primarily drives the decreased outflow from West Dongting Lake. In the Li and Yuan basins during period T1, anthropogenic factors dominated runoff alterations. During T2, anthropogenic contributions accounted for 76.27% and 48.67% of runoff changes, respectively, resulting in reduced runoff volumes under equivalent precipitation inputs. (4) Under fixed water level differences, a significant positive correlation exists between discharges at Xiaohezui and Nanzui stations. Greater discharge flows downstream through the flow channel adjacent to NZ at West Dongting Lake’s outlet. Collectively, these findings establish a technical foundation for assessing the impact of hydrological regimes and aquatic ecological security in Dongting Lake, thereby advancing sustainable water resource utilization across the basin. Full article

(This article belongs to the Special Issue Global Water Risks Across Shared River Corridors in Transboundary Basins)

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18 pages, 56966 KiB

Open AccessArticle

Changes in Water-Industry Load on River Water Resources in the Volga–Kama and Angara–Yenisei Reservoir Catchments Under Contemporary Global Warming

by Aleksandr G. Georgiadi, Elena A. Barabanova, Irina P. Milyukova, Pavel Y. Groisman and Alexej N. Narykov

Water 2025, 17(16), 2486; https://doi.org/10.3390/w17162486 - 21 Aug 2025

Changes in river runoff resources, volumes of water intake from surface water sources, and discharge of wastewater into them under contemporary global warming in the basins of the Volga–Kama and Angara–Yenisei reservoirs were analyzed by comparison with the base period, characterized by colder [...] Read more.

Changes in river runoff resources, volumes of water intake from surface water sources, and discharge of wastewater into them under contemporary global warming in the basins of the Volga–Kama and Angara–Yenisei reservoirs were analyzed by comparison with the base period, characterized by colder climatic conditions and the largest volumes of water intake and wastewater discharge. The water stress index (WSI) and the index of reciprocal dilution of polluted wastewater (RDI) were examined to reveal features of the change in the water-industry load on river runoff resources in reservoir basins during the period of contemporary global warming (compared to the previous base period) as a result of climate change combined with changes in the volumes of water intake and discharge of polluted wastewater. Both indices were calculated relative to the annual free flow for years of average river flow and the flow of low-water years. The dilution factor was estimated relative to the annual total flow. 1. The basins of the Volga–Kama reservoirs are characterized by a higher level of water-industry load, which is especially noticeable in the significantly lower RDI. 2. When calculating the dilution factor relative to the annual total flow, the level of water-industry load turns out to be much lower both in the base period and in the period of contemporary global warming. 3. At the same time, under global warming conditions, the dilution level of polluted wastewater in the basins of all reservoirs exceeds the minimum required level. Full article

(This article belongs to the Special Issue Reservoir Control Operation and Water Resources Management, 2nd Edition)

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22 pages, 856 KiB

Open AccessArticle

Farmers’ Safe Behavior of Using Wastewater for Irrigation: The Case of Northeast Iran

by Sasan Esfandiari Bahraseman, Ali Firozzare, Arash Durandish, Hiva Khalili Mararndi, Christine Fürst, Rando Värnik, Iulia Ajtai and Hossein Azadi

Water 2025, 17(16), 2485; https://doi.org/10.3390/w17162485 - 21 Aug 2025

In countries facing physical water shortages, the safe use of treated wastewater can increase agricultural yields. However, farmers’ willingness to reuse water in agriculture is very low. Therefore, the purpose of this study is to determine the factors that influence 217,215 Iranian farmers [...] Read more.

In countries facing physical water shortages, the safe use of treated wastewater can increase agricultural yields. However, farmers’ willingness to reuse water in agriculture is very low. Therefore, the purpose of this study is to determine the factors that influence 217,215 Iranian farmers who use treated wastewater to adopt safe irrigation practices. This study, which developed the Theory of Planned Behavior (TPB) by including risk perception (RP) and knowledge factors, is a groundbreaking endeavor in the field of the safe use of treated wastewater at the farm level in Iran and around the world. The final model analysis was conducted based on structural equation modeling (SEM). The findings reveal that attitudes, perceived behavioral control (PBC), RP, and knowledge significantly influence farmers’ behaviors regarding safe wastewater use, while subjective norms did not impact intentions. The subjective norm in this study includes the perceived social pressure by farmers (through family, friends, the farming community, and local authorities) to perform or not perform safe behavior in using treated wastewater for irrigation. Notably, PBC was the most important component in the original TPB model, because intention has a beneficial impact on behavior. In the extended model, knowledge and risk perception emerged as critical elements. Therefore, intervention policies should prioritize enhancing farmers’ knowledge, risk perception, and perceived behavioral control to promote safe treated wastewater usage. This study offers valuable insights for developing countries in agricultural practices. Full article

(This article belongs to the Section Water, Agriculture and Aquaculture)

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28 pages, 5969 KiB

Open AccessArticle

Geospatial Analysis of Chloride Hot Spots and Groundwater Vulnerability in Southern Ontario, Canada

by Ceilidh Mackie, Rachel Lackey and Jana Levison

Water 2025, 17(16), 2484; https://doi.org/10.3390/w17162484 - 21 Aug 2025

Elevated chloride (Cl⁻) concentrations in surface water and groundwater are an increasing concern in cold region urban environments, largely due to long-term road salt application. This study investigates the Cl⁻ distribution across southern Ontario, Canada, using geospatial methods to identify [...] Read more.

Elevated chloride (Cl⁻) concentrations in surface water and groundwater are an increasing concern in cold region urban environments, largely due to long-term road salt application. This study investigates the Cl⁻ distribution across southern Ontario, Canada, using geospatial methods to identify contamination hot spots and assess groundwater vulnerability at both regional and watershed scales. Chloride data from 2001 to 2010 and 2011 to 2020 were compiled from public sources and interpolated using inverse distance weighting. A regional-scale vulnerability index was developed using slope (SL), surficial geology (SG), and land use (LU) (SL-SG-LU), and compared it to a more detailed DRASTIC-LU index within the Credit River watershed. Results show that Cl⁻ hot spots are concentrated in urbanized areas, including the Greater Toronto Area and Golden Horseshoe, with some rural zones also exhibiting elevated concentrations. Vulnerability mapping corresponded well with the observed Cl⁻ patterns and highlighted areas at risk for groundwater discharge to surface waters. While the DRASTIC-LU method offered finer resolution, the simplified SL-SG-LU index effectively captured broad vulnerability trends and is suitable for data-limited regions. This work provides a transferable framework for identifying Cl⁻ risk areas and supports long-term monitoring and management strategies in cold climate watersheds. Full article

(This article belongs to the Special Issue Advances in Hydrogeological Investigations: Field Monitoring, GIS, AI, Remote Sensing, Geophysical Techniques, and Hydrochemical Analysis)

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20 pages, 1368 KiB

Open AccessArticle

Assessment of the Surface Water Quality of Ibrahim River (Lebanon): A Spatio-Temporal Analysis

by Sandra Chidiac, Paula El Najjar, Amine Kassouf, Naïm Ouaini, Youssef El Rayess and Desiree El Azzi

Water 2025, 17(16), 2483; https://doi.org/10.3390/w17162483 - 21 Aug 2025

Monitoring surface water quality offers a clear understanding of its parameters over time and space. The Ibrahim River, one of the main rivers in Lebanon, was monitored over one hydrological year, from March 2021 to April 2022. Samples were collected from seven stations [...] Read more.

Monitoring surface water quality offers a clear understanding of its parameters over time and space. The Ibrahim River, one of the main rivers in Lebanon, was monitored over one hydrological year, from March 2021 to April 2022. Samples were collected from seven stations in the watershed, once every two weeks. A total of 504 samples were then analyzed for pH, conductivity, turbidity, total dissolved solids, dissolved oxygen, biochemical oxygen demand, dissolved nitrate, dissolved potassium, dissolved chloride, total alkalinity, fecal coliforms, and total coliforms. Principal Component Analysis (PCA) was able to highlight two principal components (PCs), representing spatial and temporal variations, identifying areas of pollution and the influence of flow on water quality. The adapted Water Quality Index (WQI) confirmed the PCA trend with an overall average for the entire watershed of 83.70 ± 4.97, indicating a “good” water quality. Full article

(This article belongs to the Section Water Quality and Contamination)

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20 pages, 3960 KiB

Open AccessArticle

Laboratory-Scale Biochar-Aerated Constructed Wetlands for Low C/N Wastewater: Standardization and Legal Cooperation from a Watershed Restoration Perspective

by Mengbing Li, Sili Tan, Jiajun Huang, Qianhui Chen and Guanlong Yu

Water 2025, 17(16), 2482; https://doi.org/10.3390/w17162482 - 21 Aug 2025

To address the problems of eutrophication exacerbation in water bodies caused by low carbon-to-nitrogen ratio (C/N) wastewater and the limited nitrogen removal efficiency of conventional constructed wetlands, this study proposes the use of biochar (Corncob biochar YBC, Walnut shell biochar HBC, and [...] Read more.

To address the problems of eutrophication exacerbation in water bodies caused by low carbon-to-nitrogen ratio (C/N) wastewater and the limited nitrogen removal efficiency of conventional constructed wetlands, this study proposes the use of biochar (Corncob biochar YBC, Walnut shell biochar HBC, and Manure biochar FBC) coupled with intermittent aeration technology to enhance nitrogen removal in constructed wetlands. Through the construction of vertical flow wetland systems, hydraulic retention time (HRT = 1–3 d) and influent C/N ratios (1, 3, 5) were regulated, before being combined with material characterization (FTIR/XPS) and microbial analysis (16S rRNA) to reveal the synergistic nitrogen removal mechanisms. HBC achieved efficient NH₄⁺-N adsorption (32.44 mg/L, Langmuir R² = 0.990) through its high porosity (containing Si-O bonds) and acidic functional groups. Under optimal operating conditions (HRT = 3 d, C/N = 5), the CW-HBC system achieved removal efficiencies of 97.8%, 98.8%, and 79.6% for NH₄⁺-N, TN, and COD, respectively. The addition of biochar shifted the dominant bacterial phylum toward Actinobacteriota (29.79%), with its slow-release carbon source (TOC = 18.5 mg/g) alleviating carbon limitation. Mechanistically, HBC synergistically optimized nitrogen removal pathways through “adsorption-biofilm (bacterial enrichment)-microzone oxygen regulation (pore oxygen gradient).” Based on technical validation, a dual-track institutionalization pathway of “standards-legislation” is proposed: incorporating biochar physicochemical parameters and aeration strategies into multi-level water environment technical standards; converting common mechanisms (such as Si-O adsorption) into legal requirements through legislative amendments; and innovating legislative techniques to balance precision and universality. This study provides an efficient technical solution for low C/N wastewater treatment while constructing an innovative framework for the synergy between technical specifications and legislation, supporting the improvement of watershed ecological restoration systems. Full article

(This article belongs to the Section Wastewater Treatment and Reuse)

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26 pages, 2389 KiB

Open AccessArticle

Application of a Heuristic Model (PSO—Particle Swarm Optimization) for Optimizing Surface Water Allocation in the Machángara River Basin, Ecuador

by Jaime Veintimilla-Reyes, Berenice Guerrero, Daniel Maldonado-Segarra and Raúl Ortíz-Gaona

Water 2025, 17(16), 2481; https://doi.org/10.3390/w17162481 - 21 Aug 2025

Efficient surface water allocation in reservoir-equipped basins is essential for balancing competing demands within the Water–Energy–Food (WEF) nexus. This study investigated the applicability of Particle Swarm Optimization (PSO) for optimizing water distribution in the Machángara River Basin, Ecuador; a complex, constraint-rich hydrological system. [...] Read more.

Efficient surface water allocation in reservoir-equipped basins is essential for balancing competing demands within the Water–Energy–Food (WEF) nexus. This study investigated the applicability of Particle Swarm Optimization (PSO) for optimizing water distribution in the Machángara River Basin, Ecuador; a complex, constraint-rich hydrological system. Implemented via the Pymoo package in Python, the PSO model was evaluated across calibration, validation, and execution phases, and benchmarked against exact methods, including Linear Programming (LP) and Mixed Integer Linear Programming (MILP). The results revealed that standard PSO struggled to satisfy equality constraints and yielded suboptimal solutions, with elevated penalty costs. Despite incorporating MILP-inspired encoding and repair functions, the algorithm failed to identify feasible solutions that met operational requirements. The execution phase, which includes reservoir construction decisions, resulted in a total penalty exceeding EUR 164.95 billion, with no improvement observed from adding reservoirs. Comparative analysis confirmed that LP and MILP outperformed PSO in constraint compliance and penalty minimization. Nonetheless, the study contributes a reproducible implementation framework and a comprehensive benchmarking strategy, including synthetic test functions, performance metrics, and diagnostic visualizations. These tools can facilitate systematic evaluation of PSO’s behavior in high-dimensional, nonlinear environments and provide a foundation for future hybrid or adaptive heuristic models. The findings underscore the limitations of standard PSO in hydrological optimization but also highlight its potential when enhanced through hybridization. Future research should explore PSO variants that integrate exact solvers, adaptive control mechanisms, or cooperative search strategies to improve feasibility and convergence. This work advances the methodological understanding of metaheuristics in environmental resource management and supports the development of robust optimization tools under the WEF-nexus paradigm. Full article

(This article belongs to the Section Water Resources Management, Policy and Governance)

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18 pages, 9431 KiB

Open AccessArticle

Modeling Hydraulic Transient Process in Long-Distance Water Transfer Systems Using a MUSCL-Type FVM Approach

by Yifei Li and Jijian Lian

Water 2025, 17(16), 2480; https://doi.org/10.3390/w17162480 - 20 Aug 2025

To gain deeper insights into the influence of pipe parameters on water hammer properties and achieve the accurate simulation of the hydraulic transient process in pipeline systems, the Finite Volume Method (FVM) is adopted. The solution scheme, incorporating a second-order MUSCL-type reconstruction, is [...] Read more.

To gain deeper insights into the influence of pipe parameters on water hammer properties and achieve the accurate simulation of the hydraulic transient process in pipeline systems, the Finite Volume Method (FVM) is adopted. The solution scheme, incorporating a second-order MUSCL-type reconstruction, is derived, and the numerical solution process is detailed. For enhanced accuracy, the unsteady friction term is included in the numerical solution of the governing water hammer equations. The method is validated through a comparison with experimental data and the verification of mesh and Courant number independence, confirming both its efficiency and accuracy. The calculation error of the peak water head is less than 5%. Finally, an engineering case is studied to investigate valve arrangement and operation. Optimization yields the optimal valve position and operating parameters. This analysis provides valuable reference for pipeline system design. Full article

(This article belongs to the Section Hydraulics and Hydrodynamics)

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29 pages, 6596 KiB

Open AccessArticle

A Practical Model Framework for Describing the Flow of Nitrogen and Phosphorus in a Cascade Reservoir Watershed

by Han Ding, Long Han, Zeli Li, Tong Han, Wei Jiang, Gelin Kang and Qiulian Wang

Water 2025, 17(16), 2479; https://doi.org/10.3390/w17162479 - 20 Aug 2025

The construction of cascade reservoir systems (CRSs) is increasing globally, providing reliable energy and water resources for human social development, while also having significant impacts on the watershed water environment, particularly in terms of nitrogen and phosphorus distribution in the rivers and lakes [...] Read more.

The construction of cascade reservoir systems (CRSs) is increasing globally, providing reliable energy and water resources for human social development, while also having significant impacts on the watershed water environment, particularly in terms of nitrogen and phosphorus distribution in the rivers and lakes of these areas. Watershed management authorities urgently need model tools that can comprehensively analyze the sources of nitrogen and phosphorus in CRSs and the nitrogen and phosphorus cycling in lakes and reservoirs. Therefore, this study establishes a model framework that includes a watershed nutrient load model and a hierarchical reservoir nutrient cycling model, validating and analyzing this framework in the Water Diversion Basin from the Luanhe River to Tianjin (WDBLT) in North China, which yields nitrogen and phosphorus substance flows over different time scales. The conclusions show that banning cage culture and curbing point sources improved reservoir water quality, and the internal TP flux serves as a key environmental indicator. This model framework is scientifically sound, easy to operate, and does not require high data demands, demonstrating high practical value for similar water environmental management in CRS. Full article

(This article belongs to the Section Hydraulics and Hydrodynamics)

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26 pages, 3791 KiB

Open AccessReview

A Review of Modification of Carbon-Based Materials Based on Defect Engineering in Capacitive Deionization

by Yubo Zhao, Rupeng Liu, Jinfeng Fang, Feiyong Chen and Silu Huo

Water 2025, 17(16), 2478; https://doi.org/10.3390/w17162478 - 20 Aug 2025

Capacitive deionization (CDI) is a novel water treatment technology based on the principle of double-electric-layer adsorption, which stores ions in the solution on the surface of electrodes by applying a low potential difference to achieve desalination. CDI has the advantages of low operating [...] Read more.

Capacitive deionization (CDI) is a novel water treatment technology based on the principle of double-electric-layer adsorption, which stores ions in the solution on the surface of electrodes by applying a low potential difference to achieve desalination. CDI has the advantages of low operating voltage (<1.2 V), small equipment footprint, low energy consumption, low cost and environmental friendliness. The performance of CDI is heavily dependent on the electrode materials. Carbon-based materials are widely used in CDI systems because of the large specific surface areas, lower price, and remarkable stability. To improve the CDI performance, extensive research efforts have been made for the modification of carbon-based materials. Defects in carbon-based materials play an important role in electrochemical processes and the introduction of defects is an important method to modify carbon-based materials. However, there is a lack of systematic summary of modification of carbon-based materials through introducing defects in CDI system. Therefore, this study makes the first attempt to review the modification of carbon-based materials of CDI based on defect engineering. The mechanism of enhancing CDI performance of carbon-based materials with the induction of different defects is analyzed and the future research prospects are proposed. Full article

(This article belongs to the Special Issue Application of Electrochemical Technology for Water and Wastewater Treatment)

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