Combining Water Quality Indices and Multivariate Modeling to Assess Surface Water Quality in the Northern Nile Delta, Egypt
Abstract
:1. Introduction
2. Material and Methods
2.1. Study Area
2.2. Sampling and Analyses
2.3. Indexing Approach
2.3.1. Drinking Water Quality Index (DWQI)
2.3.2. Pollution Indices (PIs)
Heavy Metal Pollution Index (HPI)
Heavy Metal Evaluation Index (HEI)
Contamination Index (CD)
Pollution Index (PI)
2.4. Data Analysis
3. Results
3.1. Physicochemical Data
3.2. Geochemical Facies and Controlling Mechanisms
3.3. Water Quality Indices
Relationships between the Drinking Water Quality Index and Pollution Indices
3.4. Multivariate Statistical Analysis
3.4.1. Principal Component Analysis
3.4.2. The Performance of Partial Least Square Regression Models and Stepwise Multiple Linear Regressions to Predict the Drinking Water Quality Index and Pollution Indices
4. Discussion
4.1. Physiochemical Parameters
4.2. Assessment of Water Quality Indices
4.3. Multivariate Statistical Analysis
4.3.1. Principal Component Analysis
4.3.2. Partial Least Square Regression Models and Stepwise Multiple Linear Regressions to Predict the Drinking Water Quality Index and Pollution Indices
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Parameter | Temperature | pH | EC | TDS | TH | K+ | Na+ | Mg2+ | Ca2+ | Cl− | SO42− | |
Minimum | 27.0 | 7.2 | 406.3 | 260.0 | 2.80 | 4.5 | 15.0 | 8.2 | 22.6 | 4.0 | 26.2 | |
Maximum | 33.7 | 8.7 | 790.6 | 506.0 | 236 | 11.2 | 55.0 | 25.0 | 64.6 | 55.0 | 104.1 | |
Mean | 28.3 | 8.0 | 562.0 | 359.7 | 183.25 | 7.4 | 32.5 | 17.0 | 39.6 | 28.8 | 52.1 | |
SD | 1.9 | 0.3 | 138.9 | 88.9 | 36.23 | 2.0 | 11.6 | 4.3 | 11.0 | 12.2 | 18.1 | |
Parameter | Alkalinity | NO3− | B | Cd | Cr | Cu | F | Fe | Mn | Ni | Pb | Zn |
Minimum | 118.0 | 0.800 | 0.02 | 0.0002 | 0.005 | 0.001 | 0.100 | 0.050 | 0.010 | 0.001 | 0.001 | 0.001 |
Maximum | 278.3 | 4.420 | 0.49 | 0.0330 | 0.340 | 0.030 | 0.700 | 1.200 | 0.450 | 0.050 | 31.00 | 0.220 |
Mean | 184.3 | 1.506 | 0.12 | 0.0060 | 0.061 | 0.009 | 0.265 | 0.225 | 0.105 | 0.017 | 0.605 | 0.025 |
SD | 44.6 | 0.582 | 0.11 | 0.0090 | 0.060 | 0.005 | 0.168 | 0.206 | 0.087 | 0.017 | 4.175 | 0.060 |
Parameter | Weight (wi) | WHO 2011 [46] | Relative Weight (Wi) |
---|---|---|---|
pH | 4 | 7.50 | 0.0548 |
EC | 4 | 1000 | 0.0548 |
TDS | 5 | 500 | 0.0685 |
TH | 2 | 300 | 0.0274 |
K+ | 2 | 10.0 | 0.0274 |
Na+ | 3 | 200 | 0.0411 |
Ca2+ | 2 | 75.0 | 0.0274 |
Mg2+ | 2 | 30.0 | 0.0274 |
Cl− | 1 | 250 | 0.0137 |
SO42− | 3 | 250 | 0.0411 |
Alkalinity | 3 | 120 | 0.0411 |
NO3− | 5 | 50.0 | 0.0685 |
B | 3 | 0.50 | 0.0411 |
Cd | 3 | 0.003 | 0.0411 |
Cr | 4 | 0.05 | 0.0548 |
Cu | 2 | 2.00 | 0.0274 |
F | 4 | 1.50 | 0.0548 |
Fe | 4 | 0.30 | 0.0548 |
Mn | 4 | 0.05 | 0.0548 |
Ni | 3 | 0.07 | 0.0411 |
Pb | 5 | 0.01 | 0.0685 |
Zn | 2 | 3.00 | 0.0274 |
∑wi = 73 | ∑Wi = 1 |
Heavy Metal | WHO 2011 [46] Si (mg/L) | MACi | Unit Weight Wi | Sub index Qi | Wi × Qi |
---|---|---|---|---|---|
B | 0.50 | 500 | 0.00404 | 4.00 | 0.016179516 |
Cd | 0.003 | 3.00 | 0.67415 | 6.66 | 4.494309883 |
Cr | 0.05 | 50.0 | 0.04045 | 10.00 | 0.404487889 |
Cu | 2.00 | 2000 | 0.00101 | 0.50 | 0.00050561 |
F | 1.50 | 1500 | 0.00135 | 20.00 | 0.026965859 |
Fe | 0.30 | 300 | 0.00674 | 100.0 | 0.674146482 |
Mn | 0.05 | 50.0 | 0.04045 | 20.00 | 0.808975779 |
Ni | 0.07 | 70.0 | 0.02889 | 2.85 | 0.082548549 |
Pb | 0.01 | 10.0 | 0.20224 | 100.0 | 20.22439447 |
Zn | 3.00 | 3000 | 0.00067 | 0.166 | 0.000112358 |
∑ (Wi) = 1 | ∑ (Wi × Qi) |
Class | PI Value | Effect |
---|---|---|
1 | <1 | No effect |
2 | 1–2 | Slightly affected |
3 | 2–3 | Moderately affected |
4 | 3–5 | Strongly affected |
5 | >5 | Seriously affected |
Water Quality Indices (WQIs) | Sample Range | Range | Water Class | Samples (%) | |||
---|---|---|---|---|---|---|---|
Minimum | Maximum | Mean | SD | ||||
Drinking water quality index (DWQI) | 36.72 | 136.73 | 66.99 | 21.25 | 0–25 | Excellent water | Nil |
26–50 | Good water | 33% (18 samples) | |||||
51–75 | Poor water | 58% (32 samples) | |||||
76–100 | Very poor water | 5% (3 samples) | |||||
>100 | Unsuitable | 4% (2 samples) | |||||
Heavy metal pollution index (HPI) | 26.28 | 222.51 | 68.24 | 42.42 | <100 | Low polluted | 87% (48 samples) |
>100 | High polluted | 13% (7 samples) | |||||
Heavy metal evaluation index (HEI) | 1.98 | 17.23 | 6.59 | 3.33 | <0.3 | Very pure | Nil |
0.3–1.0 | Pure | Nil | |||||
1.0–2.0 | Slightly affected | Nil | |||||
2.0–3.0 | Moderately affected | 4% (2 samples) | |||||
3.0–6.0 | Strongly affected | 49% (27 samples) | |||||
>6.0 | Seriously affected | 47% (26 samples) | |||||
Contamination index (CD) | −8.02 | 7.23 | −3.41 | 3.33 | >1 | Low | 91% (50 samples) |
1–3 | Medium | 2% (1 sample) | |||||
<3 | High | 7% (4 samples) |
Heavy Metal | PI | Class | Effect |
---|---|---|---|
B | 0.20 | I | No effect |
Cd | 0.15 | I | No effect |
Cr | 1.00 | II | Slightly affected |
Cu | 0.01 | I | No effect |
F | 0.24 | I | No effect |
Fe | 1.17 | II | Slightly affected |
Mn | 4.50 | IV | Strongly affected |
Ni | 0.36 | I | No effect |
Pb | 4.50 | IV | Strongly affected |
Zn | 0.00 | I | No effect |
Model No. | Influential Heavy Metals for DWQI | R2 | SE |
1 | Pb | 0.774 | 7.62614 |
2 | Pb, TDS | 0.921 | 4.54227 |
3 | Pb, TDS, Fe | 0.961 | 3.22618 |
4 | Pb, TDS, Fe, Cr | 0.985 | 2.02108 |
5 | Pb, TDS, Fe, Cr, Ni | 0.994 | 1.24464 |
6 | Pb, TDS, Fe, Cr, Ni, Mn | 0.998 | 0.68741 |
7 | Pb, TDS, Fe, Cr, Ni, Mn, Cd | 0.999 | 0.63303 |
8 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K | 0.999 | 0.59664 |
9 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg | 0.999 | 0.56404 |
10 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity | 0.999 | 0.51314 |
11 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F | 0.999 | 0.41374 |
12 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH | 1.000 | 0.2414 |
13 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4 | 1.000 | 0.17705 |
14 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH | 1.000 | 0.08731 |
15 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B | 1.000 | 0.06297 |
16 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B, NO3 | 1.000 | 0.05622 |
17 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B, NO3, Ca | 1.000 | 0.04346 |
18 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B, NO3, Ca, Na | 1.000 | 0.01118 |
19 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B, NO3, Ca, Na, Cl | 1.000 | 0.00487 |
20 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B, NO3, Ca, Na, Cl, Cu | 1.000 | 0.00074 |
21 | Pb, TDS, Fe, Cr, Ni, Mn, Cd, K, Mg, Alkalinity, F, TH, SO4, PH, B, NO3, Ca, Na, Cl, Cu, Zn | 1.000 | 0.00000 |
Model No. | Influential Heavy Metals for HPI | R2 | SE |
1 | Pb | 0.98 | 5.88732 |
2 | Pb, Cd | 0.998 | 1.90212 |
3 | Pb, Cd, Cr | 1.000 | 0.72319 |
4 | Pb, Cd, Cr, Ni | 1.000 | 0.38778 |
5 | Pb, Cd, Cr, Ni, Fe | 1.000 | 0.10818 |
6 | Pb, Cd, Cr, Ni, Fe, Mn | 1.000 | 0.01196 |
7 | Pb, Cd, Cr, Ni, Fe, Mn, F | 1.000 | 0.00125 |
8 | Pb, Cd, Cr, Ni, Fe, Mn, F, B | 1.000 | 0.00024 |
9 | Pb, Cd, Cr, Ni, Fe, Mn, F, B, Cu | 1.000 | 0.00001 |
10 | Pb, Cd, Cr, Ni, Fe, Mn, F, B, Cu, Zn | 1.000 | 0.00000 |
Model No. | Influential Heavy Metals for HEI | R2 | SE |
1 | Pb | 0.861 | 0.88209 |
2 | Pb, Fe | 0.929 | 0.63571 |
3 | Pb, Fe, Cr | 0.968 | 0.43119 |
4 | Pb, Fe, Cr, Ni | 0.989 | 0.25051 |
5 | Pb, Fe, Cr, Ni, Mn | 0.998 | 0.11135 |
6 | Pb, Fe, Cr, Ni, Mn, F | 0.999 | 0.08108 |
7 | Pb, Fe, Cr, Ni, Mn, F, Cd | 1.000 | 0.01419 |
8 | Pb, Fe, Cr, Ni, Mn, F, Cd, B | 1.000 | 0.00221 |
9 | Pb, Fe, Cr, Ni, Mn, F, Cd, B, Cu | 1.000 | 0.00027 |
10 | Pb, Fe, Cr, Ni, Mn, F, Cd, B, Cu, Zn | 1.000 | 0.00000 |
Model No. | Influential Heavy Metals For CD | R2 | SE |
1 | Pb | 0.861 | 0.88209 |
2 | Pb, Fe | 0.929 | 0.63571 |
3 | Pb, Fe, Cr | 0.968 | 0.43119 |
4 | Pb, Fe, Cr, Ni | 0.989 | 0.25051 |
5 | Pb, Fe, Cr, Ni, Mn | 0.998 | 0.11135 |
6 | Pb, Fe, Cr, Ni, Mn, F | 0.999 | 0.08108 |
7 | Pb, Fe, Cr, Ni, Mn, F, Cd | 1.000 | 0.01419 |
8 | Pb, Fe, Cr, Ni, Mn, F, Cd, B | 1.000 | 0.00221 |
9 | Pb, Fe, Cr, Ni, Mn, F, Cd, B, Cu | 1.000 | 0.00027 |
10 | Pb, Fe, Cr, Ni, Mn, F, Cd, B, Cu, Zn | 1.000 | 0.00000 |
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Gad, M.; Elsayed, S.; Moghanm, F.S.; Almarshadi, M.H.; Alshammari, A.S.; Khedher, K.M.; Eid, E.M.; Hussein, H. Combining Water Quality Indices and Multivariate Modeling to Assess Surface Water Quality in the Northern Nile Delta, Egypt. Water 2020, 12, 2142. https://doi.org/10.3390/w12082142
Gad M, Elsayed S, Moghanm FS, Almarshadi MH, Alshammari AS, Khedher KM, Eid EM, Hussein H. Combining Water Quality Indices and Multivariate Modeling to Assess Surface Water Quality in the Northern Nile Delta, Egypt. Water. 2020; 12(8):2142. https://doi.org/10.3390/w12082142
Chicago/Turabian StyleGad, Mohamed, Salah Elsayed, Farahat S. Moghanm, Mohammed H. Almarshadi, Abdullah S. Alshammari, Khaled M. Khedher, Ebrahem M. Eid, and Hend Hussein. 2020. "Combining Water Quality Indices and Multivariate Modeling to Assess Surface Water Quality in the Northern Nile Delta, Egypt" Water 12, no. 8: 2142. https://doi.org/10.3390/w12082142