Batik Effluent Treatment and Decolorization—A Review
Abstract
:1. Introduction
2. Production of Batik
Dyes | Chemical Structure | Molecular Weight (g/mol) | Maximum Absorption Wavelength (nm) |
---|---|---|---|
Direct dyes (Direct Black 38) | 760.8 | 520 | |
Indigo dyes (Vat blue 1) | 262.26 | 610 | |
Naphthol dyes (Acid Orange 20) | 350.3 | 488 |
Dyes | Chemical Structure | Molecular Weight (g/mol) | Maximum Absorption Wavelength (nm) |
---|---|---|---|
Vinyl sulfone (Reactive Red 239) | 1050.37 | 555 | |
Procion MX (Reactive Red 3) | 774.05 | 532 | |
Remazol (Reactive Blue 19) | 626.5 | 592 |
3. Characteristics of Batik Effluent
No. | Parameter | Unit | Standard | |
---|---|---|---|---|
A | B | |||
1. | Temperature | °C | 40 | 40 |
2. | pH Value | - | 6.0–9.0 | 5.5–9.0 |
3. | BOD at 20 °C | mg/L | 20 | 50 |
4. | Suspended Solids | mg/L | 50 | 100 |
5. | Mercury | mg/L | 0.005 | 0.05 |
6. | Cadmium | mg/L | 0.01 | 0.02 |
7. | Chromium, Hexavalent | mg/L | 0.05 | 0.05 |
8. | Chromium, Trivalent | mg/L | 0.20 | 1.0 |
9. | Arsenic | mg/L | 0.05 | 0.10 |
10. | Cyanide | mg/L | 0.05 | 0.10 |
11. | Lead | mg/L | 0.10 | 0.5 |
12. | Copper | mg/L | 0.20 | 1.0 |
13. | Manganese | mg/L | 0.20 | 1.0 |
14. | Nickel | mg/L | 0.20 | 1.0 |
15. | Tin | mg/L | 0.20 | 1.0 |
16. | Zinc | mg/L | 2.0 | 2.0 |
17. | Boron | mg/L | 1.0 | 4.0 |
18. | Iron (Fe) | mg/L | 1.0 | 5.0 |
19. | Silver | mg/L | 0.1 | 1.0 |
20. | Aluminum | mg/L | 10 | 15 |
21. | Selenium | mg/L | 0.02 | 0.5 |
22. | Barium | mg/L | 1.0 | 2.0 |
23. | Fluoride | mg/L | 2.0 | 5.0 |
24. | Formaldehyde | mg/L | 1.0 | 2.0 |
25. | Phenol | mg/L | 0.001 | 1.0 |
26. | Free Chlorine | mg/L | 1.0 | 2.0 |
27. | Sulfide | mg/L | 0.50 | 0.50 |
28. | Oil and Grease | mg/L | 1.0 | 10 |
29. | Ammoniacal Nitrogen | mg/L | 10 | 20 |
30. | Color | ADMI * | 100 | 200 |
4. Discharge Standards for Industrial Effluents
5. Wastewater Treatment Techniques
5.1. Membrane Filtration
5.1.1. Reverse Osmosis (RO)
5.1.2. Nanofiltration (NF)
5.1.3. Ultrafiltration (UF)
5.1.4. Microfiltration (MF)
5.2. Coagulation-Flocculation Treatment
5.3. Adsorption
5.4. Fenton Reaction
5.5. Ozonation
5.6. Biological Treatment
5.6.1. Activated Sludge System
5.6.2. Trickling Filters
5.6.3. Upflow Anaerobic Sludge Blanket (UASB)
5.6.4. Enzymatic Treatment
5.7. Electrical-Assisted Treatment
6. Summary of the Advantages and Disadvantages of Physical Chemical and Biological Methods
7. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Parameter | Batik Effluent 1 | Textile Effluent 2 | Permitted Value 3 |
---|---|---|---|
pH | 7.65–12.5 | 5.5–10.5 | 5.5–9.0 |
Dissolved Oxygen (DO) (mg/L) | 1.7–2.25 | - | 3 |
BOD5 (mg/L) | 340 | 80–6000 | 50 |
COD (mg/L) 4 | 1600–4090 | 150–30,000 | 250 |
TSS (mg/L) | 305 | 15–8000 | 100 |
Turbidity (NTU) | 217 | - | - |
Trade/Industry | Unit | Standard A | Standard B |
---|---|---|---|
| mg/L mg/L mg/L | 80 80 80 | 350 250 300 |
| mg/L | 80 | 250 |
| mg/L | 400 | 400 |
| mg/L | 80 | 200 |
Treatment Methods | Method Description | Dye Removal Performance | Advantages | Disadvantages | References |
---|---|---|---|---|---|
Fenton reagent | Decompose contaminants using strong oxidizing agents and iron ions as catalyst | 81.35–97.8% |
|
| [83,125] |
Ozonation | Dissolving ozone in wastewater that acts as a strong oxidizing agent | 95–100% |
|
| [87,126] |
Membrane filtration | Utilizes pore sizes and pressure to separate contaminants in wastewater |
|
|
| [33,39,59,127,128,129] |
Coagulation | Adding coagulant as aggregation aid to increase the sedimentation rate of contaminants | 58–100% |
|
| [63,130] |
Activated sludge | Utilizes sludge-like bacteria colony to degrade contaminants with aid of aeration | 89–95% |
|
| [99] |
Trickling filter | Spraying wastewater over a filter bed that contains microorganism film on its surface | 72–99.8% |
|
| [103,104] |
Physical/Chemical Method | Method Description | Advantages | Disadvantages |
---|---|---|---|
Photochemical | This process involves the use of a photochemical oxidant, such as hydrogen peroxide or ozone, which is activated by UV or visible light to produce reactive oxygen species (ROS). | No sludge production | Formation of by-products |
NaOCl | NaOCl is a strong oxidizing agent that can react with the chromophoric groups of dyes to break down their chemical structure and remove them from the water. | Initiates and accelerates azo-bond cleavage | Release of aromatic amine |
Cucurbituril | Cucurbituril is a macrocyclic molecule with a hydrophobic cavity that can selectively bind to and trap guest molecules, including dyes. | Good sorption capacity for various dyes | High cost |
Electrochemical destruction | The process relies on the application of an electric current to the contaminated water, which initiates a series of oxidation and reduction reactions that ultimately result in the destruction of the dye molecules. | Breakdown compounds are non-hazardous | High cost of electricity |
Peat | Wastewater is pumped through a bed containing peat that allows for dye adsorption. | Good adsorbent due to the cellular structure | Specific surface area for adsorption is lower than activated carbon |
Wood chips | The adsorption of dye molecules onto the surface of wood chips, that act as a natural adsorbent material. | Good sorption capacity for acid dyes | Requires long retention times |
Silica gels | Silica gel is a synthetic, amorphous form of silicon dioxide with a high surface area and surface reactivity, making it an efficient adsorbent for various pollutants. | Effective for basic dye removal | Side reaction prevents commercial application |
Ion exchange | The process relies on the selective affinity of ion exchange resins for specific ions or molecules. | Regeneration; no adsorbent loss | Not effective for all dyes |
Irradiation | The process relies on the ability of certain wavelengths of radiation to initiate a series of chemical reactions that ultimately result in the degradation and destruction of the dye molecules. | Effective oxidation at lab scale | Requires a lot of dissolved oxygen |
Microorganism | Method Description | Advantages | Disadvantages |
---|---|---|---|
Bacteria (aerobic) | The process relies on the ability of aerobic bacteria to break down and convert the organic pollutants into carbon dioxide, water, and other harmless byproducts. |
|
|
Bacteria (anaerobic) | The process relies on the ability of anaerobic bacteria to use alternative electron acceptors, such as nitrate, sulfates, or carbon dioxide to metabolize organic pollutants. |
|
|
Fungi | The process relies on the ability of fungi to secrete enzymes that can degrade organic pollutants, including dyes and pesticides. |
|
|
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Zakaria, N.; Rohani, R.; Wan Mohtar, W.H.M.; Purwadi, R.; Sumampouw, G.A.; Indarto, A. Batik Effluent Treatment and Decolorization—A Review. Water 2023, 15, 1339. https://doi.org/10.3390/w15071339
Zakaria N, Rohani R, Wan Mohtar WHM, Purwadi R, Sumampouw GA, Indarto A. Batik Effluent Treatment and Decolorization—A Review. Water. 2023; 15(7):1339. https://doi.org/10.3390/w15071339
Chicago/Turabian StyleZakaria, Nuriah, Rosiah Rohani, Wan Hanna Melini Wan Mohtar, Ronny Purwadi, Giovanni Arneldi Sumampouw, and Antonius Indarto. 2023. "Batik Effluent Treatment and Decolorization—A Review" Water 15, no. 7: 1339. https://doi.org/10.3390/w15071339
APA StyleZakaria, N., Rohani, R., Wan Mohtar, W. H. M., Purwadi, R., Sumampouw, G. A., & Indarto, A. (2023). Batik Effluent Treatment and Decolorization—A Review. Water, 15(7), 1339. https://doi.org/10.3390/w15071339