Agate Genesis: A Continuing Enigma
Abstract
:1. Introduction
2. Scientific Contributions over the Years 1770–1980
2.1. 1770–1900
2.2. 1900–1945
- (1)
- Some samples of agates are found with a hollow space. This demonstrates that the vesicle is not always filled with a gel;
- (2)
- The vesicular infill occurs by the layering of the first generation and can be accompanied by metasomatic substitution of crystals, which have been previously precipitated;
- (3)
- The hypothesis does not explain why, in the same sample, colourless banded chalcedony varies with the pigmented chalcedony;
- (4)
- The role of pigmentation is not clear with (a) well-formed amethyst crystal centres and (b) brown pigments found in various zones with the disappearance of strong pigment zones;
- (5)
- In artificial preparations, the deposits are torn and split while in nature this phenomenon is rare.
2.3. 1945–1955
2.4. 1955–1982
3. Scientific Contributions over the Years 1980–2020
3.1. Genesis Contributions in the Early Years
3.2. Chalcedony from Silica Glass
3.3. Agate Formation Temperature
- (1)
- Loosely bound water molecules are lost at <200 °C.
- (2)
- Tightly bound water and various forms of silanol water are lost up to 800 °C.
- (3)
- The maximum mass loss is reached at 850 °C.
3.4. The Discovery of Moganite
3.5. Cation and Silica Loss from Basalt Host and Their Potential Role in Agate Formation
3.6. Age of Agate and Host
3.7. The Role of the Infiltration Canal
3.8. The Wall-Contact Layer
→ granular quartz
3.9. Agate under the Scanning Electron Microscope
3.10. Hydrocarbon Inclusions in Agate
4. Discussion
- (a)
- What is the formation temperature?
- (b)
- What is the source of the silica?
- (c)
- What is the nature of the silica deposit?
chalcedony/moganite → granular quartz
5. Summary
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Analysis of Rock Samples | Water Analysis from the Rock | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Hole | Depth | SiO2 | Fe2O3 | Al2O3 | MgO | Na2O | H2O | SiO2 | Fe3+ | Al3+ | Mg2+ | Na+ | pH |
No | m | (wt%) | (ppm) | ||||||||||
1 | 0.6 | 5.7 | 40.2 | 25.6 | 0.65 | 0.04 | 18.6 | 2.9 | 0.00 | 0.11 | 1.9 | 11 | 4.6 |
6 | 9.5 | 21.5 | 30.7 | 25.1 | 1.0 | 0.06 | 14.6 | 2.5 | 0.00 | 0.12 | 1.5 | 8.5 | 4.7 |
8 | ⁻ | 45.0 | 4.3 | 11.8 | 12.0 | 3.1 | 3.1 | 42 | 0.00 | 0.06 | 11 | 21 | 7.6 |
Agate Source | Country | Host Rock Type | Age of Host * (Ma) | Fe3+ | Al3+ (ppm) | Mg2+ | Na+ |
---|---|---|---|---|---|---|---|
Chihuahua | Mexico | Andesite Agate | 38 - | 6695 215 ** | nd 925 ** | 5460 151 ** | 25,000 320 ** |
Rio Grande do Sol | Brazil | Basalt Agate | 135 - | 14,700 137 | nd 54 | nd 10 | 19,000 140 |
Montrose | Scotland | Andesite Agate | 412 - | 33,400 70 | nd 456 | nd 15 | 23,000 230 |
Ardownie Quarry | Scotland | Andesite Agate | 412 - | 37,300 36 | nd 232 | nd 18 | 27,000 210 |
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Moxon, T.; Palyanova, G. Agate Genesis: A Continuing Enigma. Minerals 2020, 10, 953. https://doi.org/10.3390/min10110953
Moxon T, Palyanova G. Agate Genesis: A Continuing Enigma. Minerals. 2020; 10(11):953. https://doi.org/10.3390/min10110953
Chicago/Turabian StyleMoxon, Terry, and Galina Palyanova. 2020. "Agate Genesis: A Continuing Enigma" Minerals 10, no. 11: 953. https://doi.org/10.3390/min10110953