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Minerals, Volume 9, Issue 7

2019 July - 71 articles

Cover Story: Eudialyte deposits could provide a low-cost, low-impact source of rare earth elements (REE) and other critical metals. We investigated the late-magmatic alteration of eudialyte in the Ilímaussaq Complex, Greenland, which transformed magmatic eudialyte into a variety of pseudomorphic mineral assemblages. We demonstrate that eudialyte alteration is associated with a loss of 15%–30% REE, Nb, and Zr from the original crystal volume. While we infer that these elements are retained within the rock, the results indicate that they were readily mobilised in the hydrothermal environment. View this paper
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Articles (71)

  • Article
  • Open Access
21 Citations
6,249 Views
20 Pages

Selenium Minerals: Structural and Chemical Diversity and Complexity

  • Vladimir G. Krivovichev,
  • Sergey V. Krivovichev and
  • Marina V. Charykova

23 July 2019

Chemical diversity of minerals containing selenium as an essential element has been analyzed in terms of the concept of mineral systems and the information-based structural and chemical complexity parameters. The study employs data for 123 Se mineral...

  • Article
  • Open Access
4 Citations
4,643 Views
16 Pages

22 July 2019

The assessment of textural and compositional modifications of detrital sediments is required to reconstruct past source to sink dynamics. The Changjiang Delta is an ideal location to study the sedimentary environment from the Pliocene to Quaternary t...

  • Article
  • Open Access
5 Citations
4,612 Views
17 Pages

Modeling of REE and Fe Extraction from a Concentrate from Araxá (Brazil)

  • Marisa Nascimento,
  • Flávio Lemos,
  • Rogério Guimarães,
  • Clóvis Sousa and
  • Paulo Soares

21 July 2019

The study aimed to employ a comprehensive methodology for the acid processing of a rare earth element (REE) concentrate obtained from the ore from Araxá (MG-Brazil). The most important process variables have been identified and their levels de...

  • Article
  • Open Access
5 Citations
3,932 Views
12 Pages

Effect of Comminution Methods on Low-Rank Coal Bubble–Particle Attachment/Detachment: Implications for Flotation

  • Guoqiang Rong,
  • Yangchao Xia,
  • Youfei Zhang,
  • Fangyu Guo,
  • Dongyue Wang,
  • Rui Zhang,
  • Yaowen Xing and
  • Xiahui Gui

21 July 2019

The floatability of fine low-rank coal particles can be greatly influenced by their morphological characteristics, such as shape and surface roughness. In this study, the attachment efficiency and detachment amplitude of fine low-rank coal particles...

  • Article
  • Open Access
11 Citations
6,516 Views
21 Pages

Evaluation of the Sorption Potential of Mineral Materials Using Tetracycline as a Model Pollutant

  • Jaime Cuevas,
  • Nisael Dirocie,
  • Felipe Yunta,
  • Carlos García Delgado,
  • Daniel E. González Santamaría,
  • Ana Isabel Ruiz,
  • Raúl Fernández and
  • Enrique Eymar

21 July 2019

Tetracycline (TC) is among the most used antibiotics in animal feedstock in the EU. Antibiotics’ persistence as emerging pollutants in the environment is evidenced by their long half-life in residual organic-mineral sediments and waters. The ri...

  • Case Report
  • Open Access
46 Citations
7,462 Views
17 Pages

Environmental and Business Challenges Presented by Mining and Mineral Processing Waste in the Russian Federation

  • Marina A. Nevskaya,
  • Sergey G. Seleznev,
  • Vladimir A. Masloboev,
  • Elena M. Klyuchnikova and
  • Dmitriy V. Makarov

19 July 2019

Using Murmansk Region, one of Russia’s largest mining regions, as a case study, this paper examines the environmental safety challenges arising in the storage of mining and mineral processing waste (MMPW). It was found that MMPW causes environm...

  • Article
  • Open Access
8 Citations
5,899 Views
20 Pages

In Situ LA-ICP-MS Analysis of Minerals Hosted by Late Cenozoic Basaltic Rocks from Thailand

  • Long Yuan,
  • Quanshu Yan,
  • Xuefa Shi,
  • Haitao Zhang and
  • Xijun Liu

19 July 2019

Shortly after the cessation of seafloor spreading, intraplate magmatism affected large areas in the South China Sea (SCS) region. The origin and geodynamic setting of the post-spreading volcanism is still in debate, for many previous studies have foc...

  • Article
  • Open Access
18 Citations
8,849 Views
24 Pages

Invisible Gold in Pyrite from Epithermal, Banded-Iron-Formation-Hosted, and Sedimentary Gold Deposits: Evidence of Hydrothermal Influence

  • Yuichi Morishita,
  • Napoleon Q. Hammond,
  • Kazunori Momii,
  • Rimi Konagaya,
  • Yuji Sano,
  • Naoto Takahata and
  • Hirotomo Ueno

19 July 2019

“Invisible gold” in pyrite is defined as an Au solid solution of the pyrite lattice, sub-microscopic Au nanoparticles (NPs) in the pyrite, or other chemisorption complexes of Au. Because the relationship between the Au and As concentratio...

  • Feature Paper
  • Article
  • Open Access
30 Citations
7,767 Views
20 Pages

Application of Falcon Centrifuge as a Cleaner Alternative for Complex Tungsten Ore Processing

  • Yann. Foucaud,
  • Quentin Dehaine,
  • Lev. O. Filippov and
  • Inna V. Filippova

19 July 2019

Scheelite (CaWO4) is one of the main raw material for the production of tungsten. It is usually encountered in skarn deposits where it is commonly associated with other calcium minerals as fluorite, apatite, and calcium silicates. Worldwide, scheelit...

  • Article
  • Open Access
24 Citations
5,262 Views
14 Pages

Microstructure and Minerals Evolution of Iron Ore Sinter: Influence of SiO2 and Al2O3

  • Zhiyun Ji,
  • Yuanjie Zhao,
  • Min Gan,
  • Xiaohui Fan,
  • Xuling Chen and
  • Lin Hu

19 July 2019

SiO2 and Al2O3 are two important minerals that can affect the mechanical and metallurgical properties of sinter. This investigation systematically studied the influences of these minerals and revealed their functional mechanisms on sinter quality. Re...

  • Article
  • Open Access
76 Citations
6,133 Views
18 Pages

Novel Insights into the Hydroxylation Behaviors of α-Quartz (101) Surface and its Effects on the Adsorption of Sodium Oleate

  • Chenyang Zhang,
  • Zhijie Xu,
  • Yuehua Hu,
  • Jianyong He,
  • Mengjie Tian,
  • Jiahui Zhou,
  • Qiqi Zhou,
  • Shengda Chen,
  • Daixiong Chen and
  • Wei Sun
  • + 1 author

19 July 2019

A scientific and rigorous study on the adsorption behavior and molecular mechanism of collector sodium oleate (NaOL) on a Ca2+-activated hydroxylated α-quartz surface was performed through experiments and density functional theory (DFT) simulat...

  • Article
  • Open Access
15 Citations
10,572 Views
19 Pages

Automated Quantitative Mineralogy Optimized for Simultaneous Detection of (Precious/Critical) Rare Metals and Base Metals in A Production-Focused Environment

  • Mathis Warlo,
  • Christina Wanhainen,
  • Glenn Bark,
  • Alan R. Butcher,
  • Iris McElroy,
  • Dominique Brising and
  • Gavyn K. Rollinson

18 July 2019

Automated Scanning Electron Microscopy (ASEM) systems are applied in the mining industry to quantify the mineralogy of the ore feed and products. With society pushing towards sustainable mining, this quantification should be comprehensive and include...

  • Article
  • Open Access
17 Citations
4,150 Views
11 Pages

18 July 2019

We investigate the structural, vibrational, and electrical transport properties of nanocrystalline rutile and its high-pressure polymorphs by Raman spectroscopy, and AC complex impedance spectroscopy in conjunction with the high-resolution transmissi...

  • Article
  • Open Access
29 Citations
10,761 Views
22 Pages

Magmatic-Hydrothermal Processes Associated with Rare Earth Element Enrichment in the Kangankunde Carbonatite Complex, Malawi

  • Frances Chikanda,
  • Tsubasa Otake,
  • Yoko Ohtomo,
  • Akane Ito,
  • Takaomi D. Yokoyama and
  • Tsutomu Sato

18 July 2019

Carbonatites undergo various magmatic-hydrothermal processes during their evolution that are important for the enrichment of rare earth elements (REE). This geochemical, petrographic, and multi-isotope study on the Kangankunde carbonatite, the larges...

  • Article
  • Open Access
7 Citations
5,520 Views
27 Pages

18 July 2019

The Tongkuangyu copper deposit, North China Craton, is hosted in a volcano-sedimentary sequence (ca. 2.2 Ga) that metamorphosed to the lower amphibolite facies at ca. 1.9 Ga. Petrographic observations revealed various metamorphic fabrics (mineral ali...

  • Article
  • Open Access
12 Citations
5,159 Views
26 Pages

18 July 2019

Using a low temperature synthesis protocol, it was possible to obtain phase-pure synthetic aegirine (NaFeSi2O6) at temperatures as low as 130 °C, albeit only with rather long synthesis times of ~200 h; at 155 °C, a nano-crystallite shaped pha...

  • Article
  • Open Access
9 Citations
4,528 Views
15 Pages

17 July 2019

Deltaic areas and marginal seas are important archives that document information on regional tectonic movement, sea level rise, river evolution, and climate change. Here, sediment samples from boreholes of the Yangtze Delta and the modern Yangtze dra...

  • Article
  • Open Access
55 Citations
11,446 Views
42 Pages

Hydrogenetic, Diagenetic and Hydrothermal Processes Forming Ferromanganese Crusts in the Canary Island Seamounts and Their Influence in the Metal Recovery Rate with Hydrometallurgical Methods

  • Egidio Marino,
  • Francisco Javier González,
  • Thomas Kuhn,
  • Pedro Madureira,
  • Anna V. Wegorzewski,
  • Jose Mirao,
  • Teresa Medialdea,
  • Martin Oeser,
  • Catarina Miguel and
  • Rosario Lunar
  • + 2 authors

17 July 2019

Four pure hydrogenetic, mixed hydrogenetic-diagenetic and hydrogenetic-hydrothermal Fe-Mn Crusts from the Canary Islands Seamount Province have been studied by Micro X-Ray Diffraction, Raman and Fourier-transform infrared spectroscopy together with h...

  • Article
  • Open Access
12 Citations
7,223 Views
26 Pages

15 July 2019

The Lulehe sandstone in the Eboliang area is a major target for hydrocarbon exploration in the northern Qaidam Basin. Based on an integrated analysis including thin section analysis, scanning electron microscopy, X-ray diffraction, cathodoluminescenc...

  • Article
  • Open Access
16 Citations
5,868 Views
18 Pages

15 July 2019

Despite previous studies investigating selenium (Se) redox reactions in the presence of semiconducting minerals, Se redox reactions mediated by galena (PbS) are poorly understood. In this study, the redox chemistry of Se on galena is investigated ove...

  • Article
  • Open Access
5 Citations
4,957 Views
20 Pages

14 July 2019

Kornerupine ± prismatine is present in granulite-facies paragneiss at two locations in the Grenvillian New Jersey Highlands, occurring in an assemblage composed of quartz + biotite + K-feldspar + plagioclase + garnet + Fe-Ti oxides ± si...

  • Article
  • Open Access
8 Citations
5,115 Views
27 Pages

Insights into B-Mg-Metasomatism at the Ranger U Deposit (NT, Australia) and Comparison with Canadian Unconformity-Related U Deposits

  • Joséphine Gigon,
  • Roger G. Skirrow,
  • Matthieu Harlaux,
  • Antonin Richard,
  • Julien Mercadier,
  • Irvine R. Annesley and
  • Johan Villeneuve

14 July 2019

The Ranger deposit (Northern Territory, Australia) is one of the largest uranium deposits in the world. Uranium mineralisation occurs in crystalline basement rocks and is thought to belong to the unconformity-related category. In order to address the...

  • Article
  • Open Access
8 Citations
2,885 Views
10 Pages

14 July 2019

Energy input, an important factor affecting flocs properties and flotation performance, has rarely been studied in the field of diaspore flotation, which has severely limited our understanding of the flocculation flotation of fine diaspore. Therefore...

  • Article
  • Open Access
25 Citations
6,035 Views
29 Pages

Electron Donor Utilization and Secondary Mineral Formation during the Bioreduction of Lepidocrocite by Shewanella putrefaciens CN32

  • Edward J. O’Loughlin,
  • Christopher A. Gorski,
  • Theodore M. Flynn and
  • Michelle M. Scherer

14 July 2019

The bioreduction of Fe(III) oxides by dissimilatory iron reducing bacteria (DIRB) may result in the production of a suite of Fe(II)-bearing secondary minerals, including magnetite, siderite, vivianite, green rusts, and chukanovite; the formation of s...

  • Article
  • Open Access
22 Citations
6,995 Views
16 Pages

Experimental Study of Pyrite Oxidation at 100 °C: Implications for Deep Geological Radwaste Repository in Claystone

  • Héloïse Verron,
  • Jérôme Sterpenich,
  • Julien Bonnet,
  • Franck Bourdelle,
  • Régine Mosser-Ruck,
  • Catherine Lorgeoux,
  • Aurélien Randi and
  • Nicolas Michau

12 July 2019

The oxidation of pyrite is one of the near field processes of the chemical evolution of clay rock planned to host a deep geological radioactive waste repository during operation. Indeed, this process can lead to transitory acidic conditions in the me...

  • Article
  • Open Access
68 Citations
6,614 Views
18 Pages

Pyrite Morphology as an Indicator of Paleoredox Conditions and Shale Gas Content of the Longmaxi and Wufeng Shales in the Middle Yangtze Area, South China

  • Ziyi Liu,
  • Dongxia Chen,
  • Jinchuan Zhang,
  • Xiuxiang Lü,
  • Ziyi Wang,
  • Wenhao Liao,
  • Xuebin Shi,
  • Jin Tang and
  • Guangjie Xie

12 July 2019

Pyrite is the most common authigenic mineral preserved in many ancient sedimentary rocks. Pyrite also widely exists in the Longmaxi and Wufeng marine shales in the middle Yangtze area in South China. The Longmaxi and Wufeng shales were mainly discove...

  • Article
  • Open Access
22 Citations
12,152 Views
41 Pages

Factors Controlling Hydrothermal Nickel and Cobalt Mineralization—Some Suggestions from Historical Ore Deposits in Italy

  • Marilena Moroni,
  • Piergiorgio Rossetti,
  • Stefano Naitza,
  • Lorenzo Magnani,
  • Giovanni Ruggieri,
  • Andrea Aquino,
  • Paola Tartarotti,
  • Andrea Franklin,
  • Elena Ferrari and
  • Francesco Secchi
  • + 2 authors

12 July 2019

We compare three poorly known, historical Ni–Co-bearing hydrothermal deposits in different geological settings in Italy: The Ni–Co–As–Sb–Au-bearing Arburese vein system (SW Sardinia), the Co–Ni–As-rich Ussegl...

  • Article
  • Open Access
14 Citations
6,415 Views
47 Pages

12 July 2019

Significant selenium enrichment associated with selenides and previously unknown Ag-Pb-Sb, Ag-Sb and Pb-Sb sulfosalts has been discovered in hydrothermal ore veins in the Anthony of Padua mine near Poličany, Kutná Hora ore district, central Bo...

  • Article
  • Open Access
15 Citations
4,001 Views
15 Pages

11 July 2019

Sewage sludge ash (SSA) is considered to be a valuable secondary raw material for the production of phosphorous fertilisers. This method of recycling may also be a solution to the problem posed by the growing amount of this waste. An innovative suspe...

  • Editorial
  • Open Access
7 Citations
3,090 Views
4 Pages

11 July 2019

Securing reliable and continuous access to raw materials and extraction of metals are important priorities in almost all countries in order to meet industrial needs, enable high-tech applications, maintain quality of life, and guarantee millions of j...

  • Article
  • Open Access
7 Citations
3,377 Views
23 Pages

Experimental Modeling of Silicate and Carbonate Sulfidation under Lithospheric Mantle P,T-Parameters

  • Evgeniy Zdrokov,
  • Ivan Novoselov,
  • Yuliya Bataleva,
  • Yuri Borzdov and
  • Yuri Palyanov

11 July 2019

Interactions of mantle silicates with subducted carbonates, sulfides, and sulfur-rich fluids are experimentally simulated in the olivine-ankerite-sulfur and olivine-ankerite-pyrite systems using a multi-anvil high-pressure split-sphere apparatus at 6...

  • Article
  • Open Access
8 Citations
7,585 Views
15 Pages

11 July 2019

A practical method is presented to estimate rare earth element (REE) concentrations in a magmatic fluid phase in equilibrium with water-saturated granitic melts based on empirical fluid–melt partition coefficients of REE ( k P R E E )...

  • Article
  • Open Access
10 Citations
3,505 Views
16 Pages

Crystal Chemistry and Properties of Elpidite and Its Ag-Exchanged Forms

  • Natalia V. Zubkova,
  • Rositsa P. Nikolova,
  • Nikita V. Chukanov,
  • Vladislav V. Kostov-Kytin,
  • Igor V. Pekov,
  • Dmitry A. Varlamov,
  • Tatiana S. Larikova,
  • Olga N. Kazheva,
  • Nadezhda A. Chervonnaya and
  • Dmitry Yu. Pushcharovsky
  • + 1 author

10 July 2019

Elpidite from the Lovozero alkaline complex, Kola Peninsula, Russia, and Ag-exchanged forms of elpidite from two different localities (Lovozero and Khan Bogdo, Mongolia) were studied by means of single-crystal X-ray diffraction, electron microprobe a...

  • Article
  • Open Access
28 Citations
6,007 Views
13 Pages

Optimization of the Heap Leaching Process through Changes in Modes of Operation and Discrete Event Simulation

  • Manuel Saldaña,
  • Norman Toro,
  • Jonathan Castillo,
  • Pía Hernández and
  • Alessandro Navarra

10 July 2019

The importance of mine planning is often underestimated. Nonetheless, it is essential in achieving high performance by identifying the potential value of mineral resources and providing an optimal, practical, and realistic strategy for extraction, wh...

  • Article
  • Open Access
14 Citations
7,593 Views
23 Pages

Hydrothermal Alteration of Eudialyte-Hosted Critical Metal Deposits: Fluid Source and Implications for Deposit Grade

  • Mathijs A. J. van de Ven,
  • Anouk M. Borst,
  • Gareth R. Davies,
  • Emma J. Hunt and
  • Adrian A. Finch

10 July 2019

Eudialyte-hosted critical metal deposits potentially represent major sources of rare earth elements (REE), zirconium and niobium. Here, we study the chemical and isotopic composition of fresh and altered eudialyte in nepheline syenite from the Ilímau...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,659 Views
15 Pages

Chondrite Shock Metamorphism History Assessed by Non-Destructive Analyses on Ca-Phosphates and Feldspars in the Cangas de Onís Regolith Breccia

  • Alvaro Rubio-Ordóñez,
  • Olga García-Moreno,
  • Luis Miguel Rodríguez Terente,
  • Javier García-Guinea and
  • Laura Tormo

9 July 2019

The Cangas de Onís regolith breccia is an H5-H6 ordinary chondrite that fell to Earth in 1866. It is constituted by 60% H6-H5 clasts within an H5 clastic matrix. All clasts are affected by intense fissuration, with an intricate pattern filled by kama...

  • Article
  • Open Access
10 Citations
5,789 Views
28 Pages

9 July 2019

Skarn Sn-polymetallic deposits, located in the southern Great Khingan Range, can be divided into Sn–Fe and Sn–Pb–Zn deposits. By systematically studying the geochemical characteristics of source granitoid and deposits, the ore-formi...

  • Article
  • Open Access
3 Citations
3,323 Views
10 Pages

9 July 2019

Frequency distribution of zircon U–Pb ages has been commonly utilized to interpret the age of a magmatic event. Anomalies in age peaks are related to plate movement caused by mantle convection during the formation of supercontinents and contine...

  • Article
  • Open Access
9 Citations
4,611 Views
12 Pages

8 July 2019

In order to provide a good theoretical guidance for the development and utilization of weathered phosphorite resources, we investigated the geochemical and mineralogical characteristics of primary and weathered phosphorites. The analysis of trace ele...

  • Article
  • Open Access
13 Citations
4,418 Views
11 Pages

Silicate Melt Inclusions in Diamonds of Eclogite Paragenesis from Placers on the Northeastern Siberian Craton

  • Vladislav Shatsky,
  • Dmitry Zedgenizov,
  • Alexey Ragozin and
  • Viktoriya Kalinina

5 July 2019

New findings of silicate-melt inclusions in two alluvial diamonds (from the Kholomolokh placer, northeastern Siberian Platform) are reported. Both diamonds exhibit a high degree of N aggregation state (60–70% B) suggesting their long residence...

  • Review
  • Open Access
14 Citations
6,285 Views
16 Pages

5 July 2019

Microbes can mediate the precipitation of primary dolomite under surface conditions. Meanwhile, primary dolomite mediated by microbes often contains more Fe2+ than standard dolomite in modern microbial culture experiments. Ferroan dolomite and ankeri...

  • Article
  • Open Access
23 Citations
4,268 Views
21 Pages

5 July 2019

Mineral deposits concealed by thick cover sequences present special problems for geochemical exploration. A variety of penetrating geochemical methods have been developed in the last few decades to explore for buried deposits. The theoretical basis o...

  • Article
  • Open Access
11 Citations
5,940 Views
25 Pages

5 July 2019

Pyrometallurgical processing of ore from the Zeehan mineral field was performed intermittently between 1896 and 1948, primarily recovering Pb, Ag and Cu. While Zn recovery was attempted at the time, it was unsuccessful using the available technology....

  • Article
  • Open Access
9 Citations
4,763 Views
19 Pages

Constraining Mantle Heterogeneity beneath the South China Sea: A New Perspective on Magma Water Content

  • Wei Wang,
  • Fengyou Chu,
  • Xichang Wu,
  • Zhenggang Li,
  • Ling Chen,
  • Xiaohu Li,
  • Yuanzi Yan and
  • Jie Zhang

4 July 2019

The nature of upper mantle is important to understand the evolution of the South China Sea (SCS); thus, we need better constrains on its mantle heterogeneity. Magma water concentration is a good indicator, but few data have been reported. However, th...

  • Article
  • Open Access
48 Citations
9,152 Views
24 Pages

4 July 2019

The large-scale Maoping W–Sn deposit in the Gannan metallogenic belt of the eastern Nanling Range, South China, spatially associated with the Maoping granite pluton, hosts total ore reserves of 103,000 t WO3 and 50,000 t Sn. Two different types of mi...

  • Article
  • Open Access
9 Citations
8,761 Views
28 Pages

3 July 2019

The Postmasburg Manganese Field (PMF), Northern Cape Province, South Africa, once represented one of the largest sources of manganese ore worldwide. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of fe...

  • Article
  • Open Access
19 Citations
7,841 Views
22 Pages

Carbonate Precipitation in Mixed Cyanobacterial Biofilms Forming Freshwater Microbial Tufa

  • Dahédrey Payandi-Rolland,
  • Adeline Roche,
  • Emmanuelle Vennin,
  • Pieter T. Visscher,
  • Philippe Amiotte-Suchet,
  • Camille Thomas and
  • Irina A. Bundeleva

3 July 2019

Mixed cyanobacteria-dominated biofilms, enriched from a tributary of the Mérantaise (France) were used to conduct laboratory experiments in order to understand the relationship between the morphology of carbonate precipitates and the biologica...

  • Article
  • Open Access
18 Citations
5,308 Views
23 Pages

2 July 2019

We present a joint 2D inversion approach for magnetotelluric (MT) and gravity data with elastic-net regularization and cross-gradient constraints. We describe the main features of the approach and verify the inversion results against a synthetic mode...

  • Article
  • Open Access
8 Citations
3,207 Views
16 Pages

1 July 2019

In practical celestite flotation, iron contamination is commonly found on celestite surfaces. The effect of ferric ions on celestite flotation was assessed by a combination of ion release experiments, DFT calculation, X-ray photoelectron spectroscopy...

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Minerals - ISSN 2075-163X