Abstract
For each fundamental and widely used ordinary second-order linear homogeneous differential equation of mathematical physics, we derive a family of associated differential equations that share the same “degenerate” canonical form. These equations can be solved easily if the original equation is known to possess analytic solutions, otherwise their properties and the properties of their solutions are de facto known as they are comparable to those already deduced for the fundamental equation. We analyze several particular cases of new families related to some of the famous differential equations applied to physical problems, and the degenerate eigenstates of the radial Schrödinger equation for the hydrogen atom in N dimensions.
Keywords:
ordinary differential equations; analytical methods; mathematical models; Riccati equation; radial Schrödinger equation; transformations MSC:
34A25; 34A30
1. Introduction
The ordinary second-order linear homogeneous (OSLH) differential equations of mathematical physics have the general form [1,2,3,4]
where primes denote derivatives with respect to the independent variable x and and are functions of x. Equation (1) can be transformed to the canonical form [5,6,7,8]
where
and then the solutions are given by
Equation (2) is degenerate in the sense that it can also be obtained from another equation of the form
in which the functions and c obey the condition that
and then the solutions of Equation (5) are given by
Therefore, the original transformation is not uniquely invertible as there exist an infinite number of function pairs (b, c) that result in the same coefficient in Equation (2). The solutions and of the two differential equations still differ in their exponential factors, but the function is the same in Equations (4) and (7) and generally ascribes similar qualitative properties to the solutions.
The degeneracy of the canonical form (2) effectively provides a new method of solution or at least of investigation of an enormous number of potentially useful OSLH differential equations. In what follows, we determine some of these families of associated equations that may prove to be of current or future interest in applied mathematics and in physics applications. In Section 2, we describe the general theory and some notable special cases derived from degenerate canonical forms. In Section 3 and Section 4, we analyze specific examples of such families with closely related properties and solutions. In particular, we revisit 15 fundamental OSLH equations of mathematical physics listed in [3] and the degeneracies of the radial Schrödinger equation across spatial dimensions. In Section 5, we summarize and discuss our results.
2. Exploiting the Degeneracy of the Canonical Form
We consider Equations (1) and (5) with and/or leading to the same canonical form (2) with coefficient . Ibragimov [5] calls the invariant function and the associated equations equivalent by function (his Theorem 3.3.2, page 112) in the Lie symmetry group of second-order linear equations [6], but he does not pursue the classification further, as we do. We assume that the solutions (or at least their properties) are known for Equation (1) and we determine all other OSLH equations of the form (5) that are closely related due to the appearance of the same function in their solutions (7). Combining Equations (3) and (6), we find that
The coefficients and are known functions of x, whereas and are generally unknown functions to be determined. If , then also, in which case there is no family of associated equations. If , then is only a particular solution of Equation (8). We examine this case in Section 2.1, two special cases with in Section 2.2, and the general case for arbitrary and in Section 2.3 below.
Written as a Riccati equation for , Equation (8) takes the form
where is known by virtue of Equation (3). A given and the general solution of the Riccati equation determine together a family of coefficients for the associated Equation (5); some examples of important differential equations from mathematical physics with are analyzed in Section 3 below. Furthermore, two chosen functions and such that they satisfy Equation (9) identically (i.e., ) produce additional (and generally more complicated) members of the same family; a physically interesting problem from multidimensional quantum mechanics is analyzed in Section 4 below.
2.1. The Case for When
When the Riccati Equation (9) is solved to obtain , a particular solution is needed [7,8]. In the case with , we already know that . In this case:
Theorem 1.
The general solution of Equation (9) is given by
where is the general solution of the linear differential equation
Proof.
See Procedure 2 in page 392 of [8]. □
This result appears to be important for physics applications using equations of the form (1) with predetermined coefficients and . It shows that when the new term is added to the coefficient of the first derivative (Equation (10)), the complexity of the mathematical problem does not increase at all; and the new problem remains just as mathematically tractable as the original problem since the two equations share the exact same canonical form (Equation (2)).
2.2. Additional Riccati Cases with Particular Solutions
(a) For and , where K is a constant, the Riccati Equation (9) takes the form
for which is a particular solution. Then Equation (10) is the general solution, where is the general solution of the linear equation
Example 1.
In the special case with , the method generates a family of damped harmonic oscillators (associated with the basic equation [5]) whose simplest member has constant coefficients and in Equation (5).
(b) For and , where K is a constant, the Riccati Equation (9) takes the form
for which is a particular solution. Then Equation (10) is again the general solution, where is the general solution of the linear equation
Example 2.
In the special case with , then , and the known function is shifted vertically in order to produce the family of associated coefficients, i.e., and , in Equation (5).
Example 3.
On the other hand, for and for , the method generates a family of Cauchy–Euler equations (associated with [5]) whose simplest member has coefficients and in Equation (5), where .
By comparing the associated families in Examples 1 and 3 above, we see how complexity is being built up into the coefficients of the general OSLH form (5), starting merely from the simplest possible OSLH equation ; but without causing any serious difficulties to the investigations of properties or solutions of the associated equations (see also related examples in [5], pages 112 and 114).
2.3. The General Case for and
2.3.1. Solving a Riccati Equation
For arbitrary coefficients and (not related to b and , respectively), Equation (8) or (9) can be written as a Riccati equation without a linear b-term, viz.
where
is a function of x with no particular dependencies among the functions involved or any special symmetries. This function does not appear explicitly in the calculations that follow, but it does affect the determination of the sought-after particular solution. The general solution of Equation (16) from Theorem 1 is
where is a particular solution and is the general solution of the linear equation
2.3.2. Solving a Canonical Equation
If a particular solution cannot be found, then there is one more transformation that one can try ([8], Section 86, page 392):
Theorem 2.
Proof.
See Procedure 1 in page 392 of [8]. □
It is important that this coefficient will finally contain only one arbitrary constant, just as the solution (18). The two integration constants in the solution of Equation (20) will always combine into one constant in Equation (21), thus the solutions (18) and (21) are equivalent, as shown following Example 4.
Example 4.
An example of such a reduction to one arbitrary constant is provided by the simplest case with . In this case, is a linear function of x, i.e., , where and are the integration constants, and then Equation (21) gives
where . Thus, Equation (21) produces a function that depends on only one arbitrary constant C.
In the general case, , where and are two nontrivial linearly-indepenent particular solutions of Equation (20). Then Equation (21) gives
where, again, . In this case as well, the determined coefficient depends on only one arbitrary constant C.
Example 5.
A simple choice that results in complicated associated equations is and . Then, from Equation (17), and Equation (16) gives , a Riccati equation for which a particular solution cannot be readily found. Thus, we turn to Equation (20) which takes the form of Airy’s differential equation with particular solutions and , where and are the Airy functions [3]; and the general solution of is then given by Equation (23), where C is an arbitrary constant. For , the principal solution is , which is much more involved as compared to the initial choice of .
3. Families of Associated Differential Equations with
We analyze several examples of families of associated OSLH differential equations of the form (5) that are closely related to well-known and widely used equations of mathematical physics that take the form of Equation (1). In this section, we limit ourselves to families with
hence the methodology of Section 2.1 is applicable. The new differential equations have significantly more complicated coefficients due to the addition of nontrivial terms (see Equation (10)) for which is determined by solving the first-order linear differential Equation (11).
In physics applications of the standard form (1), the term usually represents damping due to friction or other resisting forces [7,9], unless it was created by the specific choice of a curvilinear coordinate system [4], as for example the inertial term in the cylindrical Bessel differential equation [4,10]. The new coefficient then generally represents a significantly more sophisticated model of resistance to motion that surprisingly has a similar effect on the dynamics of the physical system as the original simpler damping coefficient (see Table 1 for a summary). The similarity is not precise however because the solutions (4) and (7) also contain differing exponential factors. The differences in the exponential factors, , are also summarized in Table 1.
3.1. Canonical Equations of Physics with
There are quite a few OSLH equations of mathematical physics that lack a first derivative term ( in Equation (1)) [3,4] and their properties and solutions depend only on the single remaining coefficient . For such equations, we find that the associated Equation (5) admit nonzero terms of the form that complicate their appearances but not their studies. For and , Equation (11) reduces to and Equation (10) provides a nonzero coefficient of the form (22) (since from Equation (17)), viz.
where C is an arbitrary constant. This is not a trivial result. The principal () particular solution is ubiquitous in physical models [1,4,9] and the degeneracy of the canonical form was first discovered in this case: transformations of equations with to their canonical forms would eliminate the -terms from , thus leading to in such models (Equation (3) with ; see also Section 6.2 in [4]).
3.2. Damped Harmonic Oscillator
The damped harmonic oscillator [7] is described by Equation (1) with and . A family of associated differential equations is obtained from Equations (10) and (11). We find that the family members with have coefficients of the form
where C is an arbitrary constant. The result can also be written in terms of hyperbolic functions (Appendix 2 in [11]). It may be surprising that such a complicated damping coefficient can be introduced to the harmonic oscillator, yet the problem remains analytically solvable. We have seen analogous “harmless” complications in the past (hyperbolic tangents in ; Equations (56) and (59) in [4]) when we solved analytically the CDOS differential equation [11,12].
3.3. Cauchy–Euler Equation
The Cauchy–Euler equation [2,7] is described by Equation (1) with and , where and are constants. We find that its family members with have
where C is an arbitrary constant. As with the Bessel differential equation [10], the term in the case does not represent damping if x is a cylindrical radial coordinate [4]. This must be the case for the new term as well, because b and lead to the same canonical form with , which implies that for ; thus, the solutions are oscillatory in for any positive value of the constant (see [4] for details).
Example 6.
The cases with and are also notable and consistent with the results obtained in Section 3.1 above and in Section 3.9 below, respectively:
- (a)
- For (i.e., ), then , a renowned coefficient [1,4,9].
- (b)
- For (i.e., ), then , a coefficient that includes the special forms (for ) and (for ).
It is important to note here that both Cauchy–Euler special cases with and include the ubiquitous result that .
3.4. Bessel Equations
The Bessel equation of order n [10,13] is described by Equation (1) with and , where n is a constant. We find that its family members with have
where C is an arbitrary constant. In this case too, the new coefficient does not represent damping in a cylindrical coordinate frame (see also equation (77) in [4]).
The modified Bessel equation of order n [10,13] also has , but it differs in the form of . Members of this family are described by the same coefficient as that in Equation (28) and they are distinguished from the corresponding Bessel family members only because of their “modified” coefficient .
3.5. Legendre Equations
The Legendre () and associated Legendre () equations [13] are described by Equation (1) with and , where and ℓ, m are constants. We find that their family members with have
where C is an arbitrary constant other than zero. The condition eliminates a singularity at where .
3.6. Chebyshev Equation
The Chebyshev equation [13] is described by Equation (1) with and , where and n is a constant. We find that its family members with have
where C is an arbitrary constant other than zero. The condition eliminates a singularity at where . The Chebyshev equation and the associated differential equations can all be solved analytically by a transformation to their degenerate canonical form [4,11].
3.7. Hermite Equations
The Hermite differential equation [13] for the so-called polynomials in physics applications is described by Equation (1) with and , where is an integer. We find that its family members with have
where is an arbitrary constant and is Dawson’s integral [3,14].
In probability applications, the Hermite differential equation for the so-called polynomials is written with and an integer [3]. In this case, we find that family members with have
where, again, is an arbitrary constant and is Dawson’s integral [3,14]. In both of the above coefficients, the condition that eliminates the singularity at introduced by .
3.8. Laguerre Equations
The Laguerre equation [13] is described by Equation (1) with and , where and is a constant. We find that its family members with have
where C is an arbitrary constant and is the exponential integral [3,11].
The associated Laguerre equation [13] is described by Equation (1) with and , where and are real constants. Here we take to be a negative integer so that the coefficients will be real (on the other hand, leads back to Equation (33)). We find that family members with have
where C is an arbitrary constant and is the upper incomplete Gamma function [3]. We note that the coefficient in Equation (34) is not a real function of if is taken to be a real number other than a negative integer or zero.
3.9. Radial Schrödinger Equation in Three Dimensions
The radial Schrödinger equation for the hydrogen atom [1,2,3,15,16,17] is described by Equation (1) with and , where is a spherical radial coordinate and the integers and are the principal and secondary quantum numbers, respectively. It is often written in alternative forms such as in Kummer’s form of the confluent hypergeometric equation (Section 67 in [15]) with and ; and as Whittaker’s differential equation (Section 16.1 in [1]) with , , and . All three equations share the same canonical form (2) with [16].
For , the above forms produce three distinct families of associated differential equations having coefficients (Equation (10))
and
respectively, where C is an arbitrary constant and is the upper incomplete Gamma function [3]. The coefficient (35) with is ubiquitous in mathematical physics [1,4,9]. On the other hand, we find that, as in Equation (34) above with integer , the coefficient (36) here is not a real function of since in the Gamma function for all quantum numbers . Finally, in Equation (37) (derived from the original ) corresponds to the associated coefficient (26) of a damped harmonic oscillator derived from an original constant damping of .
4. Radial Schrödinger Equations in N Dimensions
Here we consider the eigenvalue problem posed by the radial Schrödinger equation in N dimensions with quantum numbers and and radial scale . The fundamental N-dimensional equation [17] takes the form (1) with and , where V is the potential and is the discrete spectrum of the eigenvalues with radial quantum numbers such that .
The corresponding eigenfunctions , , as , and they have radial nodes, not counting the boundary node at . For and , where is a constant, and with the proper normalization of variables, the main differential equation in [17] reduces to the spherical form discussed at the top of Section 3.9 above and in [16] for the hydrogen atom. In this transformation, the eigenvalues (usually denoted by ) are absorbed by the scaling (Section 67 in [15]) and they can be obtained from in atomic units (Section 3.9.1 in [18]) or, more commonly, from in electron-volts, where . (We note that, in the metric system of units [19], 13.6 eV = J.)
Our interest in this differential equation stems from the comparison theorems of Hall and Katatbeh [17] who showed that the eigenvalues and the corresponding eigenstates with the same number of radial nodes are related across different dimensions because the associated differential equations share effectively the same canonical form. Using our formulation, we recover and extend their Theorem 2 that quantifies the degeneracies between eigenvalues across dimensions N and (and within the 1-dimensional case itself) for the same potential function and with quantum numbers and , respectively. We note that, although is taken to be the same in degenerate eigenstates, their principal quantum numbers may still differ since n depends also on ℓ [15], viz.
On the other hand, it is the number of radial nodes that determines the number of oscillations in the corresponding eigenfunctions, causing thus the appearance of similar qualitative characteristics in the degenerate eigenstates [16].
4.1. The Case with
Degeneracy occurs between these eigenstates with discrete eigenvalues and the families of the corresponding eigenstates in M dimensions with eigenvalues and canonical coefficients
in which the secondary quantum number is [17]. The condition then results in two intersecting sets of degenerate solutions with eigenvalues : (i) and (ii) . Set (ii) is finite (since requires that and requires that ) and its elements are also contained in set (i), except for one particular solution: for and . This solution indicates that in three-dimensional and in one-dimensional spaces, the corresponding coefficients and result in the same canonical form for . This occurs because the s-orbitals effectively respond to the same radial potential in one and three dimensions. The same property does not extend to the s-orbitals in two dimensions because the electron sees a different effective potential, , when we restrict its motion to be on a plane (Equation (39) with and ).
We note that Equations (39) and (40) allow for more sets of solutions with and/or for . These sets are finite and their solutions are included in the fundamental set (i). We conclude that in the N-dimensional radial Schrödinger equation, given an eigenstate with eigenvalue for potential , the degenerate eigenstates with are described by the conditions
where the integers , , and (because using for s-orbitals in the first condition leads to a tautology).
4.2. The Case with
For , the inferred equation
can be rewritten in the convenient form
which has three nontrivial solution sets with degenerate eigenvalues in the case : (iii) for , (where ); (iv) for , (where ); and (v) and (which is identical to the second condition in Equation (41) obtained in Section 4.1). Sets (iii) and (iv) are equivalent, thus the degenerate eigenstates with , , and are described by the condition
that associates the ()-orbitals in 1 dimension with the corresponding ℓ-orbitals in three dimensions and the same number of radial nodes.
Equation (42) also has a solution set (vi) for : In one dimension, we find that , which gives the degeneracy condition
This condition shows that the s- and p-orbitals are degenerate in one dimension, if they have the same number of radial nodes (i.e., if their principal quantum numbers differ by 1). Finally, combining Equations (44) and (45) and with , we infer the second condition in Equation (41) which also results from set (v) above.
4.3. The General Case for Any Function
For the same potential function , the degeneracy condition in the general case takes the form
which can be recast as a quadratic equation for in terms of , viz.
that has two sets of solutions: (I) and (II) .
The two sets are intesecting and the combinations are even integers in all solutions, just as in the subsets of solutions with studied in Section 4.1. Similarly here, set (II) is finite and small in size since its solutions are valid only for and . Sets (I) and (II) include all special cases found in Section 4.1 and Section 4.2 above:
5. Summary and Discussion
For OSLH differential equations of the form (1), we have determined entire families of associated differential Equation (5) of the same form, but with generally different coefficients and/or , that exhibit comparable qualitative properties in their solutions. All such equations belonging to the same family share the same canonical form (see Equations (2) and (6)) and their general solutions differ only by the introduction of exponential factors in Equations (4) and (7), such as those listed in the entries of the summarizing Table 1. Given an original well-studied and widely used differential equation, the methods for determining associated equations with comparable qualitative properties were described in Section 2, and several examples known from physics applications were analyzed in Section 3 (; see also Table 1) and Section 4 (generally and in Hilbert spaces with different spatial dimensions).
Although one may generally create arbitrarily complicated differential equations (as in Section 2.2 and Section 2.3), we focused here on the “tip of the iceberg,” that is, on the multidimensional radial Schrödinger equations of quantum mechanics (Section 4), as well as on other physically-important OSLH differential equations (Section 3) in which the y-coefficients of Equations (1) and (5) remain the same (Equation (24)) within each family of associated equations. In the latter case, the transformations of coefficients that we carried out are not iterative: If the derived function is used in place of the original , then the new derived function is equivalent to the input , that is, repeated transformations produce the sequence and only one general solution .
Example 7.
For instance, in the canonical case with (Section 3.1):
and similarly in the Bessel case with (Section 3.4):
where C and are arbitrary constants.
This property arises from the method of solution of the Riccati Equation (9). For any choice of the arbitrary constant , becomes a particular solution and if it is used in place of in Equation (11), then this equation will produce the same general solution (10) for that will contain yet another arbitrary constant which absorbs both and the new integration constant . In particular, in the two cases of Example 7, we have and , respectively.
The results listed in Table 1 indicate that as , and then the listed entries are not applicable; as , these exponential factors tend to 1. On the other hand, for , the principal solutions are described mostly by elementary functions and by three notable special functions (Dawson’s integral , the exponential integral , and the upper incomplete Gamma function ; their standard definitions are given in [3] and in the notes to Table 1). Because of their appearance in the corresponding families of associated differential equations, these special functions have just grown somewhat in importance to mathematical physics. Of the three special functions appearing in Table 1, and (for and an even integer) contain singular points other than the familiar in the coefficients of the (associated) Laguerre equation for (Equations (33) and (34), respectively, in Section 3.8). In particular, the only root of is and it lies in the domain of the Laguerre equation; and the root of is and it lies in the domain of the associated Laguerre equation; similarly, the real roots of for are , respectively.
The coefficients derived from Equation (10) for and listed in Table 1 (one has to add up the two b-entries in each case) generally describe damping of motion due to friction ([20], Section 3.4, page 172), or air resistance ([20], Section 2.3, page 93), or other dissipative processes (e.g., [21], Section 17.9, page 603) in physics applications (unless the term is inertial created by the curvature of the coordinate system; see [4]). At present, there is no general theory of friction or such resisting forces [22]. Then, these new functions would potentially represent more complicated and more sophisticated models of resisting forces acting on the corresponding dynamical systems. Despite their intimidating look at first sight (owing to the overly complicated terms), the associated differential equations of the various families are quite easily mathematically tractable, provided that the original models involving simpler damping terms of the form in Equation (1) are already well-studied and their qualitative properties are fully understood.
Author Contributions
Conceptualization, D.M.C.; methodology, D.M.C. and Q.D.K.; formal analysis and investigation, D.M.C., E.K., and Q.D.K.; writing—original draft preparation, D.M.C.; writing—review and editing, E.K. and Q.D.K. All authors have read and agreed to the published version of the manuscript.
Funding
This research received no external funding.
Data Availability Statement
All data generated in this study are included in this published article.
Acknowledgments
During this research project, D.M.C. was supported by the University of Massachusetts Lowell, E.K. was supported by Colorado State University, and Q.D.K. was supported by the Jordan University of Science and Technology.
Conflicts of Interest
The authors declare no conflict of interest.
Abbreviations
The following abbreviations are used in this manuscript:
| OSLH | Ordinary Second-order Linear Homogeneous |
| CDOS | Chuaqui, Duren, Osgood, Stowe (Ref. [12]) |
| , | Airy Functions (Ref. [3]) |
| Dawson’s Integral (Refs. [3,14]) | |
| Exponential Integral (Refs. [3,11]) | |
| Upper Incomplete Gamma Function (Ref. [3]) |
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