Effect of Pt Addition on the Oxidation and Corrosion Resistance of Al0.25CoCrFeNi High-Entropy Alloy
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Microstructure and Phase Composition
3.2. High-Temperature Oxidation
3.3. Corrosion Resistance Test
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Alloy | Al | Co | Cr | Fe | Ni | Pt | ΔSmix, J∙mole−1∙K−1 |
---|---|---|---|---|---|---|---|
Al0.25CoCrFeNi | 5.86 | 23.47 | 23.88 | 23.21 | 23.58 | – | 1.53R |
Al0.25CoCrFeNiPt0.1 | 5.64 | 22.93 | 23.10 | 22.96 | 23.05 | 2.32 | 1.60R |
Alloy | kp | Alloy | kp |
---|---|---|---|
Al0.25CoCrFeNi | 22 × 10−13 | Al0.2Co1.5CrFeNi1.5Ti0.3Nb0.05 [19] | 78.5 × 10−13 |
Al0.25CoCrFeNiPt0.1 | 5.62 × 10−13 | Al0.5CoCrFeNi [33] | 8.91 × 10−13 |
Al0.6CrFeCoNi [16] | 11.8 × 10−13 | FeCoNiCrAl [36] | 4.9 × 10−13 |
Al0.2Co1.5CrFeNi1.5Ti0.3 [19] | 280 × 10−13 | AISI 304L [37] | 23 × 10−13 |
Alloy | Al | Co | Cr | Fe | Ni | Pt | O | |
---|---|---|---|---|---|---|---|---|
Al0.25CoCrFeNi | Av | 8.99 | 4.54 | 23.92 | 4.30 | 4.75 | – | 53.50 |
LC | 23.86 | 3.20 | 13.88 | 3.15 | 3.11 | – | 52.80 | |
RC | 0.06 | 5.18 | 31.36 | 4.37 | 5.52 | – | 53.51 | |
Al0.25CoCrFeNiPt0.1 | Av | 14.11 | 4.21 | 19.19 | 4.17 | 3.37 | 0.21 | 54.74 |
LC | 22.71 | 4.17 | 11.25 | 4.30 | 3.38 | 0.27 | 53.92 | |
RC | 1.02 | 3.83 | 33.03 | 3.37 | 2.93 | 0.08 | 55.74 |
Alloy | Ecorr, V | Icorr, μA/cm2 | Rp, kΩcm2 | Ipas, μA/cm2 | ΔE | Eb, V |
---|---|---|---|---|---|---|
Al0.25CoCrFeNi | −0.132 ± 0.003 | 6.67 ± 0.05 | 1.12 ± 0.03 | 417 | 1.262 | 1.195 |
Al0.25CoCrFeNiPt0.1 | −0.018 ± 0.002 | 3.93 ± 0.02 | 6.79 ± 0.05 | 356 | 1.222 | 1.218 |
Al0.25CoCrFeNiCu [22] | −0.164 ± 0.002 | 607 ± 3 | 0.088 ±0.001 | 271 | 0.077 | – |
Al0.5CoCrFeNiTi0.5 [23] | −0.400 | 320 | – | 24.8 | 0.650 | 0.980 |
FeCoNiCrCu0.5Al0.5 [25] | −0.112 | 4.190 | – | 3000 | 0.550 | – |
AlCoCrFeNiSi0.1 [27] | −0.453 | 304.20 | – | 19.35 | 1.350 | 0.925 |
SS 304 [27] | −0.438 | 105.12 | – | 4.47 | 1.261 | 0.925 |
Al0.5CoCrFeNiCu0.25 [28] | −0.112 ± 0.002 | 3.52 ± 0.02 | 7.81 ± 0.05 | 21.5 | 0.967 | – |
Al0.5CoCrFeNiCu0.25Ag0.1 [28] | −0.143 ± 0.002 | 5.21 ± 0.05 | 8.47 ± 0.05 | 28.8 | 1.282 | – |
Al0.25CoCrFeNi [42] | −0.095 | 16.7 | – | 7.1 | 1.080 | – |
SS 304 [42] | −0.185 | 45.3 | – | 19.1 | 0.750 | – |
Co1.5CrFeNi1.5Ti0.5 [43] | −0.092 | 30 | – | 9 | 1.130 | 1.089 |
Co1.5CrFeNi1.5Ti0.5Mo0.1 [43] | −0.071 | 78 | – | 9 | 1.112 | 1.089 |
AlCoCuFeNiCr [44] | −0.075 | 5.09 | 14.450 | – | 0.650 | – |
AlCoCuFeNiCrTi [44] | −0.256 | 39.59 | 1.558 | – | 0.940 | – |
Al0.3CrFe1.5MnNi0.5 [45] | −0.194 | 2390 | – | 73.9 | 1.176 | – |
Alloy | Al | Co | Cr | Fe | Ni | Pt | O | S | |
---|---|---|---|---|---|---|---|---|---|
Al0.25CoCrFeNi | Av | 5.66 | 21.88 | 23.17 | 21.54 | 22.03 | – | 5.64 | 0.08 |
Al0.25CoCrFeNiPt0.1 | Av | 4.10 | 19.91 | 21.45 | 19.56 | 19.50 | 5.60 | 8.94 | 0.94 |
A | 2.40 | 19.68 | 24.64 | 18.11 | 19.36 | 2.62 | 12.08 | 1.11 | |
B | 4.53 | 20.45 | 20.72 | 20.56 | 20.64 | 6.91 | 5.77 | 0.42 |
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Samoilova, O.; Pratskova, S.; Suleymanova, I.; Shaburova, N.; Ostovari Moghaddam, A.; Trofimov, E. Effect of Pt Addition on the Oxidation and Corrosion Resistance of Al0.25CoCrFeNi High-Entropy Alloy. Metals 2023, 13, 1709. https://doi.org/10.3390/met13101709
Samoilova O, Pratskova S, Suleymanova I, Shaburova N, Ostovari Moghaddam A, Trofimov E. Effect of Pt Addition on the Oxidation and Corrosion Resistance of Al0.25CoCrFeNi High-Entropy Alloy. Metals. 2023; 13(10):1709. https://doi.org/10.3390/met13101709
Chicago/Turabian StyleSamoilova, Olga, Svetlana Pratskova, Ilsiya Suleymanova, Nataliya Shaburova, Ahmad Ostovari Moghaddam, and Evgeny Trofimov. 2023. "Effect of Pt Addition on the Oxidation and Corrosion Resistance of Al0.25CoCrFeNi High-Entropy Alloy" Metals 13, no. 10: 1709. https://doi.org/10.3390/met13101709