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Article

Corrosion of Steels in Liquid Bismuth–Lithium Alloy

by
Aleksander V. Abramov
1,*,
Ruslan R. Alimgulov
2,
Anastasia I. Trubcheninova
2,
Vladimir A. Volkovich
2 and
Ilya B. Polovov
2
1
Department of Physical and Chemical Methods of Analysis, Ural Federal University, 620062 Ekaterinburg, Russia
2
Department of Rare Metals and Nanomaterials, Ural Federal University, 620062 Ekaterinburg, Russia
*
Author to whom correspondence should be addressed.
Metals 2024, 14(11), 1215; https://doi.org/10.3390/met14111215
Submission received: 26 September 2024 / Revised: 16 October 2024 / Accepted: 21 October 2024 / Published: 25 October 2024
(This article belongs to the Section Corrosion and Protection)

Abstract

The corrosion resistance of several types of steel (AISI 410, 321, 316L, 904L) was determined in a liquid Bi-Li (5 mol.%) alloy (BLA) medium at 650 °C combining gravimetric analysis of steel samples and chemical analysis of corrosion products’ content accumulating in the BLA phase. Energy dispersive X-ray spectrometry, scanning electron microscopy, X-ray fluorescence and inductively coupled plasma–atomic emission spectrometry analysis were employed for characterizing steel structure and alloy composition. AISI 321, 316L and 904L nickel-containing corrosion-resistant steels underwent severe corrosion in BLA, and their corrosion rates depended on the nickel content in the material. AISI 410 steel exhibited the lowest corrosion rate of all the materials investigated, and this type of steel can be considered as a reasonable structural material for work in BLA environments. The corrosion rates of AISI 410, 321, 316L and 904L steels in BLA at 650 °C were 77, 244, 252 and 280 µm/year, respectively. It was also found that chromium was etched more intensively than iron from the surface of steel samples.
Keywords: corrosion; bismuth; lithium; steel; chrome; iron corrosion; bismuth; lithium; steel; chrome; iron

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MDPI and ACS Style

Abramov, A.V.; Alimgulov, R.R.; Trubcheninova, A.I.; Volkovich, V.A.; Polovov, I.B. Corrosion of Steels in Liquid Bismuth–Lithium Alloy. Metals 2024, 14, 1215. https://doi.org/10.3390/met14111215

AMA Style

Abramov AV, Alimgulov RR, Trubcheninova AI, Volkovich VA, Polovov IB. Corrosion of Steels in Liquid Bismuth–Lithium Alloy. Metals. 2024; 14(11):1215. https://doi.org/10.3390/met14111215

Chicago/Turabian Style

Abramov, Aleksander V., Ruslan R. Alimgulov, Anastasia I. Trubcheninova, Vladimir A. Volkovich, and Ilya B. Polovov. 2024. "Corrosion of Steels in Liquid Bismuth–Lithium Alloy" Metals 14, no. 11: 1215. https://doi.org/10.3390/met14111215

APA Style

Abramov, A. V., Alimgulov, R. R., Trubcheninova, A. I., Volkovich, V. A., & Polovov, I. B. (2024). Corrosion of Steels in Liquid Bismuth–Lithium Alloy. Metals, 14(11), 1215. https://doi.org/10.3390/met14111215

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