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Article

Wide-Temperature Characteristics of Additively PBF-LB/M Processed Material Ti6Al4V

1
Department of Technical Studies, College of Polytechnics Jihlava, Tolsteho 16, 586 01 Jihlava, Czech Republic
2
Institute of Theoretical and Applied Mechanics of the Czech Academy of Sciences, Prosecká 809/76, 190 00 Praha, Czech Republic
*
Author to whom correspondence should be addressed.
Metals 2024, 14(7), 781; https://doi.org/10.3390/met14070781
Submission received: 15 April 2024 / Revised: 22 June 2024 / Accepted: 28 June 2024 / Published: 2 July 2024

Abstract

:
Titanium-based alloys are a widely applicable engineering material with high strength, low weight, non-magnetic, and corrosion resistance. At the same time, resistance to low temperatures is declared, which offers the material’s applicability for, e.g., aircraft or ship technology. Additive technologies are part of the industrial spectrum of material processing, especially the Laser Powder Bed Fusion of Metals method for metal alloys, which creates a layered structure of the resulting body. The topology of the internal structure, in relation to the temperature history of the functional environment, influences thermal expansion and the associated functional characteristics. Knowledge of the thermal expansion of printed strength and non-strength functional components and accessories is essential for future applications, especially in environments with high repeatable temperature changes, such as the aerospace industry. This paper presents the results of testing the expansion, mechanical, microstructural, and mineralogical characteristics of Ti6Al4V over the temperature range of −70 to 60 °C using a combination of instrumental techniques such as X-ray diffraction and nanoindentation. It was found that the topological orientations of the printed samples directly influenced the tested properties, e.g., the coefficient of thermal expansion in the direction perpendicular to the printed layers showed approximately 12% lower value compared to the other directions. Due to the progression of the application of the manufacturing method and its applicability within selected industries, the research provides results in a new area, which is supported by the relevant research.

Graphical Abstract

1. Introduction

Titanium and its alloys represent materials for various applications in mechanically stressed structures exposed to specific environmental conditions [1]. At the same time, it has a low specific weight compared to steel [2]. Typical areas of application of titanium alloys are, for example, aerospace or marine engineering [3,4]. The paramagnetic nature of these materials makes it particularly suitable for use in instrumentation applications such as electron microscopy [5]. Another specific sector using titanium alloys is the field of body implants [6,7,8]. An essential factor in applying titanium alloys over a wide temperature range, typically e.g., in the aerospace sector [9], is the dilatation characteristics. As a result of heating or cooling by the external environment, the component changes its shape and especially its dimensional characteristics [10]. For example, the declared value of the thermal expansion coefficient for Ti6Al4V alloy is approximately 8.5 × 10−6 K−1 [11]. The quantity value represents the change in unit length dimension when heated or cooled by one temperature degree. Over a wide temperature range, a significant dimensional change may occur, and the proper function of the component itself or an assembly, including other constituents, may be compromised. The resulting thermal deformation and dimensional changes can lead to deformation stresses and force effects [12]. Possible differences in thermal expansion characteristics in different directions, e.g., in orthotropic materials, may result in deformation in multiple directions due to different expansion characteristics [13]. In comparison with steel, for example, the relevant titanium alloy shows approximately half the value of the expansion parameter. In the case of aluminum alloys, it is approximately one-third the value.
In comparison with polymeric materials, it is a quarter. Ti-based alloys are more expensive compared to steel materials. The alternative to Ti alloys is usually stainless steel, but these do not include the same specific attributes, notably low weight [14]. A significant difference in mechanical characteristics is the modulus of elasticity, which is lower in titanium than steel; the components deform more quickly in the elastic deformation region. The consequence of the low modulus of elasticity is poorer machinability, mainly because of the easy deformation due to cutting forces during the machining process.
A progressive production technology applicable to the processing of titanium alloys is the additive manufacturing method of Laser Powder Bed Fusion of Metals (PBF-LB/M) [15,16]. The melting and bonding to the formed body takes place in layers [17]. The tool path and how the material is joined create a layered structure. The influence of the laser scanning speed is an important factor in the resulting microstructure of the Ti6Al4V alloy [18]. Phase transformation also occurs during PBF-LB/M processing; there are several studies in the literature documenting this [19,20,21]. The morphology of the primary alpha phase is similar to the lamellar microstructure of the alpha phase in conventionally processed Ti6Al4V alloy [22]. This fact is therefore an argument in favor of the use of this technology for commercial applications.
This paper presents the results of the effect of topological layered material structure on the dilatation behavior of Ti6Al4V alloy. Thermal expansion and related factors are considered. The aim is to determine the dilatation behavior depending on the respective printing topology and to derive general dilatation characteristics for 3D-printed titanium solids. An optodigital non-contact method is used to measure the deformation during temperature variation in the range from −70 to +60 °C. The obtained results can be applied to analytical and numerical computational procedures applicable during the design of components made by additive manufacturing from Ti6Al4V material and used in functional dimensional chains of thermally stressed assemblies.

2. Materials and Methods

Samples made using the additive PBF-LB/M method from Ti6Al4V material were used to measure dilatation and surface and structural characteristics. The parameters of the manufacturing method and the declared characteristics of the samples are given in Table 1.
The geometrical parameters of the test sample bodies, including the markers for the optodigital strain sensing, are shown in Figure 1. The print topologies, representing the layered structure concerning the reference geometry of the test body samples, are shown also in Figure 1. A representation of the solids of the corresponding topology relative to the reference coordinate system of the production facility are shown in Figure 1. The layered structure is characteristic of the PBF-LB/M additive manufacturing method, and the influence of the layers is the subject of the test results presented. The manufacturing method is chosen based on the declaration of the layout of the production equipment and the usual parameters recommended to achieve the optimal structural mechanical characteristics. Based on the results presented, producing the relevant components using the usual declared methods is assumed for application use. The shape and dimensions of the test samples are chosen to ensure a sufficient volume of material comparable to the expected volumes of the real components, for which the declared manufacturing method is applied. At the same time, their dimensions are adapted to the optimum parameters of the available measuring equipment. The aim is to set up the samples for measurement reliably and to capture the position of the reference features with an optodigital measuring device.
PBF-LB/M is an additive method based on the local sintering of powdered metal with a laser beam. The samples for testing the thermal behaviour, with the parameters shown in Table 1 and Figure 1 and Figure 2, are produced on a Renishaw AM250 (Renishaw, Wotton-under-Edge, UK). The 3D printing parameters are shown in Table 2. This standard 3D printing method is recommended for producing functional parts.
Technological characteristics for producing samples can be found in Table 2. Using the PBF-LB/M method, they represent the commonly available production equipment parameters.
The data in Table 2 represent the mean values of the parameters achieved by the available range, specific to the equipment used to produce the test samples. All samples are produced with the same parameters. The results of the broad temperature parameters are based on samples produced by a specific technology and any technical application. Samples produced by the PBF-LB/M additive method have shape, dimensional, and object characteristics adapted to the test method. The samples are clamped in the flat jaws of the test system so that degrees of freedom are taken in all directions, either by fixation or by measuring the relevant characteristic. The samples are not up-prepared for testing by any of the post-processing methods. The sampler recommends that the scanning speed be used to achieve acceptable productivity while maintaining the declared mechanical characteristics of the products. The positioning speed represents the auxiliary movements of the device during printing, repositioning the beam to the starting position to start the formation of each layer. The repositioning speed does not affect the product’s quality characteristics, but it does affect the productivity of the print.
The bill of materials declares the material structure of the supplier-prepared samples. For the practical application of the research results for real design solutions, it is assumed that the components are manufactured by the supplier using the declared method, or that the technological parameters can be requested from the supplier if the product is manufactured on different equipment. The presented research results are for reference. Since the manufacturing methods offer a wide range of parameters, variations cannot be excluded. The powder compositions for producing samples with mechanical properties according to Table 1 and technological parameters according to Table 2 are presented in Table 3.
The measurements are performed on three variants of mutually perpendicular printing topologies. Topologies A, B, and C represent a 90° rotation of the layer direction within the identical printing plane lying in the technological plane XY of the production facility. Topology B represents the orientation of the print planes perpendicular to the Z-axis.
The temperature environment for testing and controlling the temperature progression is generated by a Eurotherm 3119 chamber (Instron, Norwood, MA, USA). Low temperatures are achieved using liquid nitrogen retained for temperature control in a Wesington PV-120 Dewar (Wesington, Houghton-le-Spring, GB). A combination of nitrogen cooling and electric heating controls and stabilizes the temperature at a specific value. The temperature generation in the chamber is performed within a control system, ensuring a uniform distribution of the temperature field around the sample and an appropriate temperature value, measured using a temperature sensor located in the flow environment of the temperature medium. A separate independent temperature sensor simultaneously performs temperature control in the immediate vicinity of the sample. The temperature progression is controlled in the temperature range 20 °C, −70 °C, +60 °C, 20 °C. Cooling and heating are controlled with a bidirectional gradient of ±5 °C·min−1. The temperature waveform is graphically shown in the graph in Figure 2.
The mechanical tests are performed on an Instron Electropuls 10000 (Instron, Norwood, MA, USA), which can generate combined loads in the direction of the piston axis and rotation around the piston axis. Torsional characteristics are not tested. Only the axial axis stabilizing force is used to set up the sample and create the test conditions. Consistent external conditions and test stability are achieved by generating a constant moderate compressive load of 1 kPa. The deformation measurement due to thermal loading is performed using an Instron video extensometer (Instron, Norwood, MA, USA). Based on capturing and evaluating the position of the geometric pattern in the form of a thick dot of a distinctive contrasting color, the change in the position of the geometric center of the pattern is evaluated. The extensometer allows simultaneous sensing of the position of points in two mutually perpendicular directions. The positions of the displaced points due to thermal deformation in two mutually perpendicular directions are recorded in the declared thermal points within one temperature curve. At the beginning of each measurement, the initial separation distances of the corresponding pairs of points are evaluated. The relative deformation concerning the initial positions of the points is then determined from the initial distances. The dilation experimental measurement parameters are listed in Table 4.
The measurement is non-contact, and the extensometer is outside the temperature chamber. The principle of strain measurement is achieved via the video extensometer. The control of the measurement process and the control of the Instron Electropuls 10000 test rig is performed via the Instron Console V9 control software (Instron, Norwood, MA, USA). The temperature profile and test method are controlled through Bluehill Universal V3 software (Instron, Norwood, MA, USA). Calibration and control of strain values are performed via the Instron Video extensometer control software as part of Bluehill Universal V3 (Instron, Norwood, MA, USA). The accuracy and determination of measurement uncertainty are defined through statistical methods and calibration results of the used gauges. The sample standard deviation of the arithmetic mean of the measured values for each test set determines the type A uncertainty. The type B uncertainty is determined from the calibration sheet of the gauge used. The parameters given for the results represent the expanded uncertainty of the measurement with an expansion factor of 2, which, for a normal distribution, gives a coverage probability of about 95%.
Each test is performed on ten different samples of each topology, A, B, and C, to eliminate the possible factor of material changes at each declared temperature cycle.
X-ray Fluorescence (XRF) analysis was carried out on samples A, B, and C type structures using a Prospector 3 instrument (Elvatech, Kyiv, Ukraine) with an energy range of 0–10 keV. Each sample was measured three times, and the results were taken as the mean.
Samples were tested by X-ray diffraction (XRD) using settings reported in [20] using Bruker D8 Advance instrument (Bruker, Fremont, CA, USA).
The surface mechanical properties of a 3D printed Ti6Al4V alloy were also investigated using a Hysitron TL 750 (Bruker, Fremont, CA, USA) nanoindenter with SPM capability with using the same settings as [25]. The test method consisted of the trapezoidal load function shown in Figure 3. Samples were tested before and after thermal-mechanical loading (TML) in two planes to the axis of each sample topology: A—perpendicular to the print axis and B—parallel to the print axis. Samples were tested in two planes to the axis of each sample topology: A—parallel to the print axis and B—perpendicular to the print axis.
Microstructure observation on individual samples was carried out using Videomicroscopes Hirox KH 7700 (Hirox, Limonest, FRA) with polarized light. A modified procedure based on [26] was chosen for etching, i.e., using a modified Keller solution: HNO3:HCl: CrO3 (5:3:2) original form (leads to etching in the form of white lines on grain boundaries, without breaking the surface) 5:3:2 mL to 190 mL H2O, reinforced form (leads to grain boundary etching) 50:30:20 mL to 100 mL H2O. In both cases, repeated etching was performed in the 5–10 min range per batch. Rinsing was conducted in H2O, and drying was sped up with ethanol. Samples were tested in two planes to the axis of each sample topology: A—parallel to the print axis and B—perpendicular to the print axis.

3. Results and Discussion

The microstructures of the samples before and after thermal-mechanical loading are shown in Figure 4, where on the left are the samples before thermal-mechanical loading and on the right after loading [27,28,29].
The microstructure of samples prior to TLM consists of α and β phases grains oriented according to the production process (3D printing). Mechanical properties obtained from the nanoindentation test clearly show the difference between parallel and perpendicular orientation, as seen in Table 4. However, it is different for the post-TLM samples. Since the same etching method and agent were used to prepare microscopy samples, the reason must be in the material and treatment.
There are still α and β phases grains, but not many visible oriented structures are caused by the production process (3D printing). Mechanical properties obtained from nanoindentation are isotropic in the parallel and perpendicular orientation (compared to the samples pre-TLM, also in Table 4).
Differences between structure and nanomechanical properties of samples pre- and post-TLM would be expected for PBF-LB/M treatment, which is more or less a classic powder metallurgy “sintering process“. The thermal cycling in TLM is only between −70 °C and 40 °C, and the structure should be compact, homogeneous, and mostly stable. Both the structure and mechanical properties of the material had changed. If such an observation is correct then the conclusion is that providing a relatively homogeneous microstructure at a suitable low temperature and pressure for TLM treatment is possible.
These results should be used as a starting point for additional research to prove the results and to further study mechanical behavior and microstructure as a function of time/number of cycles. It should be noted that the combination of thermal and mechanical stress is a source of defects in the structure [27,28,29,30]. What looks like defects in Figure 4 post-TLM (b, d, and f sections) were not originally present on the cross-section surface during polishing. It is a result of the etching of the structure. Rather, these are spaces where etched-out grains had been. Since the etching attacks mainly the inter-crystalline and inter-granular interfaces, some of these interfaces have increased energy levels and thus lower chemical stability. Since the etchant does not create these energetic instabilities but renders them visible, the source of this particular behavior must be in the TLM process.
Elemental composition has been verified for all sample types and is the declared composition for alloys designated Ti6Al4V [31]. The results are shown in Table 5, and the comparison of individual measurements is shown in Figure 5.
Figure 6a,b show the collected XRD patterns of measured samples before and after thermal-mechanical loading, respectively. The detected sharp Bragg’s peaks were found to belong to hexagonal closed-packet α/α′ Ti phases [32,33]. These phases substantially overlap due to their similar structures and lattice parameters, as already evidenced in [34,35]. The β-Ti phase, with its typical peak at around 39.5° [32], was not detected in measured patterns. Looking closely at patterns collected before thermal-mechanical loading, the only difference seems to be in the intensity of the peak characterizing (002) crystal plane: only in sample C was this peak higher than the peak of the (100) crystal plane.
On the contrary, peaks of crystal planes (100) and (002) were detected to have similar intensities in samples A and C and only in sample B the peak of the (002) plane was detected to be higher than the peak of (100) plane after thermal-mechanical loading. In addition, a broad peak of low intensity appeared at around 37.8° (highlighted in grey rectangular in Figure 6b) in samples after thermal-mechanical loading. All these findings suggest that the orientation of printing and thermal-mechanical loading may also affect the crystalline structure of Ti6Al4V alloy.
In terms of surface properties, the samples show different characteristics concerning the orientation of the print, with surface mechanics being an important parameter [7]. The nanoindentation results for all samples are shown in Table 6. The influence of thermal-mechanical loading was also evaluated. Samples in the parallel plane showed a higher hardness (H) around 5.7−6.3 GPa compared to the results of 4.3−5.0 GPa for the perpendicular section. Within orientation, the samples showed no variation and were comparable. A similar trend can be seen in the Young’s modulus (E) results. After thermal-mechanical loading, there was a decrease in hardness values, mainly for the parallel cut samples. Other data were comparable. A sample of the typical indentation applied to the material can be seen in Figure 7.
The results of measuring the expansion characteristics for the individual print topologies indexed A, B, and C according to the declaration are given in Table 7 and Table 8. Table 7 and Table 8 show the results of axial and transverse deformations at the extreme temperature points, respectively, range. The thermal expansion coefficient for each topology and temperature waveform is determined using linear regression. From the results, the influence of the printing layers on the thermal expansion is evident, especially in the direction perpendicular to each layer.
The corresponding dilatation curves for the individual print topologies are shown in Figure 8 and Figure 9. The results for deformations in the axial and transverse directions are shown separately.
The presented results show the influence of the printing layers on the dilatation in the perpendicular direction. Along the press layers, the values in both perpendicular directions are close to the declared value of 8.5 × 10−6 K−1. The measured values corresponding to 8.6 × 10−6 K−1 agree with other declarations of the thermal expansion coefficient for Ti6Al4V. A significant finding is the thermal expansion coefficient in the direction perpendicular to the printing layers, where a reduction to a value corresponding to 7.6 × 10−6 K−1 occurs. This factor is particularly significant in the case of the design of an additively manufactured component subjected to temperature variations during its operation, where precise dimensions in specific directions are crucial, and their variation due to the wide temperature range may exceed tolerance limits, resulting in incorrect function, or completely disabling the intended function [36,37].
The similarity of the coefficient values for samples A and C and the dissimilarity of the coefficient value for sample B in the measured temperature ranges for axial and transverse dilatation can be observed. The anisotropy of the layered material structure is reflected here by slightly different values of the thermal expansion coefficient over the entire measured temperature spectrum. This factor is particularly evident when measured in the longitudinal direction, where sample B presents a layer perpendicular to the measured axis. The differences in dilation values measured in the direction perpendicular to the longitudinal axis are even more pronounced. A significantly lower Thermal Expansion value is found in the direction perpendicular to the printing layers, associatively confirming the printing layers’ influence on the dilatation characteristics.
The dilatation characteristics for this material are available only in general terms, usually for the basic variant of Ti6Al4V, regardless of the production method and technological processing. At the same time, an interval is given, usually (8.5–9.1) × 10−6 K−1, as listed, e.g., in [23,24]. In the temperature range, it directly impacts functionality. In particular, the variant of pattern B, representing layering in the longest direction of the body, shows relatively low values or significantly lower values of the declared intervals. Based on the results obtained, which are at or below the lower limit of the generally declared values, it is possible to consider the influence of the material processing method on the resistance in terms of thermal expansion, which is an advantage for the technical applicability of the material. In addition to aerospace applications, the issue of thermal expansion is a significant problem in the field of body implants. The likely influence of the processing method is also evident for other materials applied in additive manufacturing of PBF-LB/M, e.g., Al10SiMg, as discussed in, e.g., [25]. Here, the values are lower for different print topologies, as in this text. Testing was performed using electromechanical sensors, thus eliminating any systematic error in the method. In addition to the direct effect on the mechanical behavior of the components over a wide temperature range, the values found are essential for developing manufacturing and assembly technical documentation of components for use in relevant industries using the appropriate additive method. A specific feature of additive methods is the relative ease with which free forms can be produced. The emerging approaches of minimum dimensioning can be used for complex components, combining freeform and exact shape features simultaneously, where most dimensions are contained within the relevant surface shape tolerance. The size of the tolerance field corresponds to the possibilities of the manufacturing methods. Mechanical temperature behavior is a functional attribute for using components over a wide temperature range, and the relevant tolerance must be considered and declared.
For the declaration of the relevant parameters, the effect of the manufacturing method on the thermal expansion can be based on a positive trend in terms of the effect on the overall surface tolerance concerning the three mutually perpendicular component bases, as shown, for example, in Figure 10. This tolerance is universal and can also be considered in the relevant perpendicular directions to determine the relevant component of the tolerance of the exact dimensions.
The accuracy of the measurement is expressed by an expanded combined standard uncertainty consisting of two components. Type A uncertainty represents the standard deviation of the arithmetic mean. Type B uncertainty represents the metrological characteristics of the measuring equipment used, here an Instron video extensometer (Instron, Norwood, MA, USA) with the appropriate control software Instron Video extensometer control software as part of Bluehill Universal V3 (Instron, Norwood, MA, USA). The declared accuracy class of the measuring device is 0.5, representing 0.5% of the recorded value. For the relevant measuring range values, the value based on the accredited calibration performed represents 0.44% of the recorded value. The combined measurement uncertainty, including statistical evaluation of repeated measurements and metrological characteristics of the equipment, is expanded by a factor of 2 to cover a 95.4% probability interval of correct result. The accuracy of the measured, recorded, and evaluated values is always better than 1% of the evaluated record, with the most significant uncertainty being 0.98%.

4. Conclusions

The structural characteristics of additively manufactured components are characterized by differences concerning an equivalent material whose blank is prepared by conventional casting or forming methods. The distinctive layer structure creates the prerequisites for the specific directional characteristics of the conventionally isotropic material. The presented results report the behavior of Ti6Al4V alloy prepared by the additive PBF-LB/M method, where the resulting structure is formed by sintering the metal powder in layers using a laser beam. The advantage of the additive method is the fast production preparation based on the existence of a digital 3D model created in CAD tools. Due to the industry standard of using CAD tools, the digital model is either full or partial. Conventional design processes are based on tabular standard parameters of the mechanical behavior of materials. Knowledge of the differences in additively prepared materials for designing key functional components is essential to guarantee proper functionality. The possibility of influencing the directional characteristics in the context of the functional dimensions of the component is another advantage of additive technologies, where the orientation of the component during manufacturing has minimal constraints from a technological point of view. Thus, the manufacturing process can be adapted to the accuracy requirements due to the directionally different behavior. The product’s primary position concerning the production equipment’s coordinate system is represented by the platform in the XY plane and the construction of the levels in the Z-axis direction. The smaller Thermal Expansion Coefficient in the direction perpendicular to the print layers can play a significant role in determining accurate dimensions in the appropriate direction of the thermally stressed component.

Author Contributions

Conceptualization, K.D.; Methodology, K.D. and J.D.; Validation, L.Z.; Formal analysis, K.D., D.M., L.Z. and R.S.; Investigation, K.D., J.D. and L.Z.; Data curation, K.D.; Writing—original draft preparation, K.D.; Writing—review and editing, J.D. and L.Z.; Visualization, K.D., R.S. and D.M.; Supervision, K.D.; Project administration, K.D. All authors have read and agreed to the published version of the manuscript.

Funding

This research was supported by the College of Polytechnics Jihlava, under Grant no. INT/2023/0007 ”Research on dilation characteristics of 3D DMLS printed products”, The Czech Science Foundation (GACR) 24-11505S ” Structurally controlled wave propagation in multi-material 3D printed bodies” and by the Czech Academy of Sciences, Institute of Theoretical and Applied Mechanics (RVO 68378297).

Data Availability Statement

The original contributions presented in the study are included in the article, further inquiries can be directed to the corresponding author/s.

Conflicts of Interest

The authors declare no conflicts of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript; or in the decision to publish the results.

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Figure 1. Samples parameters with markers, dimensions in mm, and manufacturing coordinate system. Orientation of printing layers relative to the working coordinate system of the body production equipment. A, B, C are significants.
Figure 1. Samples parameters with markers, dimensions in mm, and manufacturing coordinate system. Orientation of printing layers relative to the working coordinate system of the body production equipment. A, B, C are significants.
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Figure 2. Experimental measurement temperature time course.
Figure 2. Experimental measurement temperature time course.
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Figure 3. Graph of the load function used during the test.
Figure 3. Graph of the load function used during the test.
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Figure 4. Images of samples after etching, where (a)—sample A, (b)—sample A_TML, (c)—sample B, (d)—sample B_TML, (e)—sample C, (f)—sample C_TML.
Figure 4. Images of samples after etching, where (a)—sample A, (b)—sample A_TML, (c)—sample B, (d)—sample B_TML, (e)—sample C, (f)—sample C_TML.
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Figure 5. XRF patterns for all samples (Hg signal collected due to discharged lamp of used XRF instrument).
Figure 5. XRF patterns for all samples (Hg signal collected due to discharged lamp of used XRF instrument).
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Figure 6. The collected XRD patterns of Ti6Al4V alloy of samples before (a) and after thermal-mechanical loading (b) with indexed crystal planes of α/α′ Ti phases peaks.
Figure 6. The collected XRD patterns of Ti6Al4V alloy of samples before (a) and after thermal-mechanical loading (b) with indexed crystal planes of α/α′ Ti phases peaks.
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Figure 7. Example of indent applied to materials.
Figure 7. Example of indent applied to materials.
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Figure 8. Course of Axial dilation in the measured temperature range, 27 points were recorded for each measurement.
Figure 8. Course of Axial dilation in the measured temperature range, 27 points were recorded for each measurement.
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Figure 9. The course of transverse dilation is in the measured temperature range; 27 points were recorded for each measurement.
Figure 9. The course of transverse dilation is in the measured temperature range; 27 points were recorded for each measurement.
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Figure 10. Incorporation of the results into the tolerance requirements for the surface shape of a free-form body produced by the PBF-LB/M method. Technological bases for which the dilation characteristics of 3D printed bodies are evaluated. A, B, C correspond to the directions of the vectors for determining dimensional tolerances due to dilation.
Figure 10. Incorporation of the results into the tolerance requirements for the surface shape of a free-form body produced by the PBF-LB/M method. Technological bases for which the dilation characteristics of 3D printed bodies are evaluated. A, B, C correspond to the directions of the vectors for determining dimensional tolerances due to dilation.
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Table 1. Initial general Ti6Al4V material characteristics [23].
Table 1. Initial general Ti6Al4V material characteristics [23].
ParametersValues
Density4.42 g·cm3
Thermal conductivity6–8 W·mK
Melting range1635–1665 °C
Tensile strength (XY)1089 ± 7 MPa
Tensile strength (Z)1085 ± 12 MPa
Yield strength (XY)1007 ± 5 MPa
Yield strength (Z)985 ± 23 MPa
Young’s modulus (XY)129 ± 7 GPa
Young’s modulus (Z)126 ± 15 GPa
Thermal expansion coefficient, declared 0–100 °C8.5 × 10−6 K−1
Table 2. Declared technological production characteristics for PBF-LB/M print [23,24].
Table 2. Declared technological production characteristics for PBF-LB/M print [23,24].
ParametersValues
Production speed5 cm3/h
Scanning speed2000 mm·s−1
Positioning speed7000 mm·s−1
Layer thickness30 μm
Laser power200 W
Average input grain size30 ± 15 µm
Table 3. Composition of powder [23].
Table 3. Composition of powder [23].
ElementWeight (wt.%)
TitaniumBalance according to composition below
Aluminum5.5 to 6.5
Vanadium3.5 to 4.5
Iron≤0.25
Oxygen≤0.13
Carbon≤0.08
Nitrogen≤0.05
Hydrogen≤0.012
Yttrium≤0.005
Residuals≤0.1 each, ≤0.4 total
Table 4. Dilation experimental measurement parameters.
Table 4. Dilation experimental measurement parameters.
ParametersValues
Start of measurement20 °C
1st part of Temp. cycle20 °C − 70 °C
2nd part of Temp. cycle−70 °C ± 60 °C
3rd part of Temp. cycle+60 °C ± 20 °C
Temperature rate −max. −5 °C/min
Temperature rate +max. +5 °C/min
Controlled Preloadmax. 1 kPa
Clamping methodFlat jaws
Table 5. XRF results.
Table 5. XRF results.
SampleContents of the Elements (%)
TiAlVFeNiSb
A88.7 ± 0.87 ± 74.31 ± 0.110.166 ± 0.0130.018 ± 0.006<0.03
B88.1 ± 0.97 ± 74.15 ± 0.110.229 ± 0.014<0.030.03 ± 0.03
C86.6 ± 0.99 ± 74.07 ± 0.110.212 ± 0.0140.003 ± 0.005<0.03
Table 6. Nanoindentation characteristics results.
Table 6. Nanoindentation characteristics results.
SampleSample OrientationBefore Thermal-Mechanical LoadingAfter Thermal-Mechanical Loading
H (GPa)E (GPa)H (GPa)E (GPa)
Aparallel5.73 ± 0.35122.46 ± 4.164.85 ± 0.53126.09 ± 8.17
B6.17 ± 0.43132.22 ± 6.634.97 ± 0.58130.05 ± 8.97
C6.32 ± 0.52134.63 ± 5.935.13 ± 0.63130.94 ± 9.42
Aperpendicular4.24 ± 0.39101.73 ± 6.264.26 ± 0.7094.52 ± 9.06
B4.74 ± 0.55112.07 ± 7.884.76 ± 0.91113.99 ± 11.11
C4.96 ± 0.53117.84 ± 7.864.56 ± 0.99122.27 ± 14.39
Table 7. Results of axial and transverse dilation characteristics.
Table 7. Results of axial and transverse dilation characteristics.
SamplesTransverse Dilation (%)Axial Dilation (%)
Maximal Deformation
+60 °C
Negative Deformation
−70 °C
Maximal Deformation
+60 °C
Negative Deformation
−70 °C
A0.044 ± 0.003−0.073 ± 0.0030.036 ± 0.003−0.074 ± 0.002
B0.037 ± 0.003−0.079 ± 0.0030.035 ± 0.003−0.064 ± 0.002
C0.034 ± 0.003−0.063 ± 0.0030.014 ± 0.003−0.092 ± 0.030
Table 8. Results of axial and transverse thermal expansion coefficients.
Table 8. Results of axial and transverse thermal expansion coefficients.
SamplesTransverseAxial
Thermal Expansion
Coefficient −60/+60
K−1
Thermal Expansion
Coefficient −60/+60
K−1
A8.6 × 10−68.7 × 10−6
B8.6 × 10−67.6 × 10−6
C7.7 × 10−68.7 × 10−6
The standard deviation is part of the expanded measurement uncertainty, covering the probability interval of the correct result of 95.4%. The expanded combined measurement uncertainty includes the standard deviation and the metrological characteristics of the equipment used. The extended measurement uncertainty in the entire range is less than 1%, precisely 0.98%.
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Dvorak, K.; Dvorakova, J.; Majtas, D.; Sevcik, R.; Zarybnicka, L. Wide-Temperature Characteristics of Additively PBF-LB/M Processed Material Ti6Al4V. Metals 2024, 14, 781. https://doi.org/10.3390/met14070781

AMA Style

Dvorak K, Dvorakova J, Majtas D, Sevcik R, Zarybnicka L. Wide-Temperature Characteristics of Additively PBF-LB/M Processed Material Ti6Al4V. Metals. 2024; 14(7):781. https://doi.org/10.3390/met14070781

Chicago/Turabian Style

Dvorak, Karel, Jana Dvorakova, Dusan Majtas, Radek Sevcik, and Lucie Zarybnicka. 2024. "Wide-Temperature Characteristics of Additively PBF-LB/M Processed Material Ti6Al4V" Metals 14, no. 7: 781. https://doi.org/10.3390/met14070781

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