Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Catalyst Preparation
2.3. Catalyst Characterization
2.4. Catalytic Tests
3. Results and Discussion
3.1. Catalyst Characterization
3.1.1. X-ray Diffraction
3.1.2. Transmitted Electron Microscopy
3.1.3. Temperature-Programmed Pd Hydride Decomposition
3.2. Catalytic Hydrogenation of DPA
3.2.1. Effect of Reduction Temperature on the Activity of PdIn Catalysts
3.2.2. Selectivity to Olefin Formation
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Catalyst | r1 | r2 | r1/r2 |
---|---|---|---|
mmol/(gcat min) | |||
Pd | 4.39 | 0.621 | 7.1 |
PdIn-200 | 4.02 | 0.194 | 20.7 |
PdIn-300 | 1.40 | 0.040 | 35.0 |
PdIn-400 | 0.46 | 0.0103 | 44.7 |
PdIn-500 | 0.42 | 0.0088 | 47.7 |
PdIn-600 | 0.45 | 0.0095 | 47.4 |
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Mashkovsky, I.S.; Markov, P.V.; Bragina, G.O.; Baeva, G.N.; Rassolov, A.V.; Yakushev, I.A.; Vargaftik, M.N.; Stakheev, A.Y. Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation. Nanomaterials 2018, 8, 769. https://doi.org/10.3390/nano8100769
Mashkovsky IS, Markov PV, Bragina GO, Baeva GN, Rassolov AV, Yakushev IA, Vargaftik MN, Stakheev AY. Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation. Nanomaterials. 2018; 8(10):769. https://doi.org/10.3390/nano8100769
Chicago/Turabian StyleMashkovsky, Igor S., Pavel V. Markov, Galina O. Bragina, Galina N. Baeva, Alexander V. Rassolov, Ilya A. Yakushev, Michael N. Vargaftik, and Alexander Yu. Stakheev. 2018. "Highly-Ordered PdIn Intermetallic Nanostructures Obtained from Heterobimetallic Acetate Complex: Formation and Catalytic Properties in Diphenylacetylene Hydrogenation" Nanomaterials 8, no. 10: 769. https://doi.org/10.3390/nano8100769