Ligands-Coordinated Zr-Based MOF for Wastewater Treatment
Abstract
:- We have regulated and synthesized different Zr-MOFs with distinct pore sizes by utilizing different lengths of organic ligands.
- The process and mechanisms of the adsorption of dye by Zr-MOFs with different apertures were studied through theoretical kinetic models and BET data analyses.
- The adsorption of the best state was achieved at 235 mg/g.
1. Introduction
2. Materials and Methods
2.1. Chemicals
2.2. Synthesis of UiO-66 and UiO-67
2.3. Characterization
2.4. Adsorption Experiment
3. Result and Discussion
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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C0 (ppm) | k2,ad (g/mg h) | qe (mg/g) | R2 |
---|---|---|---|
10 | 0.01803 | 56.21 | 0.99986 |
20 | 0.00954 | 104.57 | 0.99965 |
30 | 0.00729 | 132.40 | 0.99984 |
40 | 0.00589 | 161.99 | 0.99966 |
50 | 0.00525 | 189.54 | 0.99973 |
C0 (ppm) | k2,ad (g/mg h) | qe (mg/g) | R2 |
---|---|---|---|
10 | 0.01897 | 55.89 | 0.99949 |
20 | 0.00960 | 110.89 | 0.99952 |
30 | 0.00664 | 156.62 | 0.99977 |
40 | 0.00511 | 196.76 | 0.9998 |
50 | 0.00410 | 253.09 | 0.99994 |
UiO-66 (NLDFT) | UiO-66 (BJH) | UiO-67 (NLDFT) | UiO-67 (BJH) | |
---|---|---|---|---|
Surface Area (cm3/g) | 744 | 793 | 1139 | 1314 |
Pore Width (nm) | 1.410 | 30 | 2.114 | 30 |
Pore Volume (cc/g) | 0.413 | 0.093 | 0.649 | 0.146 |
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Zhan, X.-Q.; Tsai, F.-C.; Xie, L.; Zhang, K.-D.; Liu, H.-L.; Ma, N.; Shi, D.; Jiang, T. Ligands-Coordinated Zr-Based MOF for Wastewater Treatment. Nanomaterials 2018, 8, 655. https://doi.org/10.3390/nano8090655
Zhan X-Q, Tsai F-C, Xie L, Zhang K-D, Liu H-L, Ma N, Shi D, Jiang T. Ligands-Coordinated Zr-Based MOF for Wastewater Treatment. Nanomaterials. 2018; 8(9):655. https://doi.org/10.3390/nano8090655
Chicago/Turabian StyleZhan, Xue-Qing, Fang-Chang Tsai, Lei Xie, Ke-Deng Zhang, Huan-Li Liu, Ning Ma, Dean Shi, and Tao Jiang. 2018. "Ligands-Coordinated Zr-Based MOF for Wastewater Treatment" Nanomaterials 8, no. 9: 655. https://doi.org/10.3390/nano8090655