Synthesis and Characterization of Novel NiW–CeO2 Composite Coating with Enhanced Corrosion and Wear Resistance
Abstract
:1. Introduction
2. Methodology
2.1. Electrolyte Components
2.2. Substrate Preparation
2.3. Electrodeposition Setup
2.4. Optimization of PRC Waveform
2.5. Characterization of Deposits
3. Results and Discussion
3.1. Corrosion Analysis
3.1.1. Cyclic Potentiodynamic Polarization (CPP)
3.1.2. Potentiodynamic Polarization (PP)
3.2. SEM/EDS Analysis
3.2.1. DC and PRC Deposited Ni
3.2.2. DC and PRC Deposited Ni–W
3.2.3. DC and PRC Deposited NiW–CeO2 Composite
3.3. Tribological Analysis (Coefficient of Friction and Wear Rate)
3.4. XRD Analysis (Effect of Heat Treatment on Crystallite Sizes of PRC deposited Ni, NiW and NiW–CeO2)
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Name of Chemicals | Concentration |
---|---|
Nickel sulfate | 29.5–30 (g·L−1) |
Sodium tungstate | 58–60 (g·L−1) |
Citric acid | 63–67 (g·L−1) |
Ammonia | 58 (mL·L−1) |
Sulfuric acid | as needed |
Propargyl–oxo–propane–2,3–dihydroxy (POPDH) | 0.9–1 (g·L−1) |
DuPont™ Capstone® Fluoro–surfactant FS–63 | 1.8–2 (g·L−1) |
Sodium saccharin | 0.5–1 (g·L−1) |
Experimental Parameters | |
pH | 7.8–8.0 |
Temperature | 58–61 °C |
Duration of electrodeposition | 30 min |
Ingredients | Concentrations (wt%) |
---|---|
NaCl | 58.49 |
Na2SO4 | 9.75 |
CaCl2 | 2.765 |
KCl | 1.645 |
NaHCO3 | 0.477 |
KBr | 0.238 |
H3BO3 | 0.071 |
SrCl2.6H2O | 0.095 |
NaF | 0.007 |
MgCl2 | 26.46 |
Coatings | Peak Position of (111) [°2Th] | FWHM [°2Th] | Crystallite Size [Å] |
---|---|---|---|
PRC–Ni (as–deposited) | 44.712 | 0.443 | 197 |
PRC–Ni (heat–treated at 350 °C) | 44.810 | 0.315 | 280 |
PRC–Ni (heat–treated at 500 °C) | 44.651 | 0.079 | 1210 |
PRC–NiW (as–deposited) | 44.220 | 0.630 | 138 |
PRC–NiW (heat–treated at 350 °C) | 44.319 | 0.433 | 202 |
PRC–NiW (heat–treated at 500 °C) | 44.130 | 0.386 | 222 |
PRC–NiW–CeO2 (as–deposited) | 44.261 | 0.779 | 110 |
PRC–NiW–CeO2 (heat–treated at 350 °C) | 44.075 | 0.692 | 124 |
PRC–NiW–CeO2 (heat–treated at 500 °C) | 44.214 | 0.543 | 158 |
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Dadvand, M.; Savadogo, O. Synthesis and Characterization of Novel NiW–CeO2 Composite Coating with Enhanced Corrosion and Wear Resistance. Coatings 2022, 12, 878. https://doi.org/10.3390/coatings12070878
Dadvand M, Savadogo O. Synthesis and Characterization of Novel NiW–CeO2 Composite Coating with Enhanced Corrosion and Wear Resistance. Coatings. 2022; 12(7):878. https://doi.org/10.3390/coatings12070878
Chicago/Turabian StyleDadvand, Mina, and Oumarou Savadogo. 2022. "Synthesis and Characterization of Novel NiW–CeO2 Composite Coating with Enhanced Corrosion and Wear Resistance" Coatings 12, no. 7: 878. https://doi.org/10.3390/coatings12070878